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4-Methyl-3-nitroaniline

4-Methyl-3-nitroaniline structure

CAS No.: 119-32-4

Chemical Name:: 4-Methyl-3-nitroaniline

Synonyms: META NITRO PARA TOLUIDINE;FAST RED GL BASE;3-NITRO-4-METHYLANILINE;MNPT;Gl-amin;FAST RED GL;FAST RED G BASE;5-Nitro-4-toluidine;3-NITRO-P-TOLUIDINE;LABOTEST-BB LTBB000623

CBNumber:: CB2287373

Molecular Formula:: C7H8N2O2

Molecular Weight:: 152.15

MDL Number:: MFCD00007910

MOL File:: 119-32-4.mol

Last updated:2023-09-21 11:25:22

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4-Methyl-3-nitroaniline Properties

Melting point	74-77 °C(lit.)
Boiling point	169 °C (21 mmHg)
Density	1.312
vapor density	5.8
refractive index	1.6276 (estimate)
Flash point	157 °C
storage temp.	Store below +30°C.
solubility	<1g/l
pka	2.96±0.10(Predicted)
form	Powder
color	Ochre to orange or brown
BRN	638984
InChIKey	GDIIPKWHAQGCJF-UHFFFAOYSA-N
CAS DataBase Reference	119-32-4(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	SM8UZ1Q81F
NIST Chemistry Reference	Benzenamine, 4-methyl-3-nitro-(119-32-4)
EPA Substance Registry System	4-Methyl-3-nitroaniline (119-32-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS08,GHS09

Signal word

Danger

Hazard statements

H301+H311+H331-H373-H411

Precautionary statements

P273-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311-P314

Hazard Codes

T,N,Xi

Risk Statements

23/24/25-33-51/53

Safety Statements

28-36/37-45-61-28A

RIDADR

UN 2660 6.1/PG 3

WGK Germany

RTECS

XU8227250

Hazard Note

Irritant

TSCA

Yes

HazardClass

6.1

PackingGroup

III

HS Code

29214300

Toxicity

LD50 orl-rat: 6860 mg/kg 28ZPAK -,133,72

NFPA 704

	0
2		0

4-Methyl-3-nitroaniline price More Price(23)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	M59807	4-Methyl-3-nitroaniline 97%	119-32-4	25g	$46.9	2023-01-07	Buy
TCI Chemical	N0278	4-Methyl-3-nitroaniline	119-32-4	25g	$73	2024-03-01	Buy
Alfa Aesar	A12538	4-Methyl-3-nitroaniline, 98%	119-32-4	25g	$66.65	2024-03-01	Buy
Alfa Aesar	A12538	4-Methyl-3-nitroaniline, 98%	119-32-4	100g	$197.65	2024-03-01	Buy
Usbiological	N2680-02	3-Nitro-4-toluidine	119-32-4	5g	$425	2021-12-16	Buy

Product number	Packaging	Price	Buy
M59807	25g	$46.9	Buy
N0278	25g	$73	Buy
A12538	25g	$66.65	Buy
A12538	100g	$197.65	Buy
N2680-02	5g	$425	Buy

4-Methyl-3-nitroaniline Chemical Properties,Uses,Production

Description

4-Methyl-3-nitroaniline is one of the intermediates or products in the photochemical transformations (λ=254 nm) of 2,4-dinitrotoluene (2,4-DNT) in aqueous solutions containing the cationic surfactant cetyltrimethylammonium (CTA) and the anionic nucleophile borohydride (BH₄^-)[1].

Chemical Properties

Orange Crystalline Solid

Uses

4-Methyl-3-nitroaniline is a compound useful in organic synthesis. It is used to make pigments and dyes. It could also be used in Environmental Testing. It could be used as raw material to synthesized N-(4-methyl-3-nitrophenyl)-4-(4-methylpiperazin-1-ylmethyl)benzamide through acylation[2].

Definition

ChEBI: 4-Amino-2-nitrotoluene is a C-nitro compound.

Synthesis Reference(s)

Tetrahedron Letters, 30, p. 251, 1989 DOI: 10.1016/S0040-4039(00)95173-6

Reactivity Profile

4-Methyl-3-nitroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents (NTP, 1992).

Hazard

Toxic by ingestion.

Fire Hazard

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG, 2020)

Safety Profile

Poison by ingestion andintravenous routes. Combustible when exposed to heat orflame. To fight fire, use CO2, spray, foam. When heated todecomposition it emits toxic fumes of NOx.

Purification Methods

Crystallise the aniline from hot water (charcoal), then ethanol and dry it in a vacuum desiccator. [Beilstein 12 H 966.]

References

[1] Diehl C, et al. Surfactant-assisted UV-photolysis of nitroarenes. Chemosphere, 2002; 46: 553-560.
[2] Koroleva E, et al. Synthesis of new amides of the N -methylpiperazine series. Russian Journal of Organic Chemistry, 2011; 47: 1556–1563.

4-Methyl-3-nitroaniline synthesis

Synthesis of 4-Methyl-3-nitroaniline from p-Toluidine

4-Methyl-3-nitroaniline Preparation Products And Raw materials

Raw materials

Preparation Products

6-Methoxy-1H-indole-3-carboxylic acid 6-Bromoindole-3-carboxaldehyde Rhodamine 6G 2-Bromo-4-chlorotoluene 3-Fluoro-4-methylbenzoic acid

5-Fluoro-2-methylaniline 4-Fluoro-2-nitrobenzoic acid 4-Bromo-2-nitrotoluene 4-Bromo-2-chlorobenzoic acid 4-Methyl-3-nitrobenzene-1-sulfonyl chloride

2-Methyl-5-nitrophenol 2,4-Dihydro-5-methyl-4-[(4-methyl-3-nitrophenyl)azo]-2-phenyl-3H-pyrazol-3-one ASISCHEM N13873 Methyl-(4-Methyl-3-nitro-phenyl)-aMine 4'-METHYL-3'-NITROMETHANESULFONANILIDE

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4-Methyl-3-nitroaniline Suppliers

Global( 290)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Taizhou Suze Chemical Materials Co.,Ltd.	+86-0523-86392777 +86-19825580222	nick.miao@suzechem.com	China	23	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29884	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	sales@dolonchem.com	CHINA	2972	58
Shanghai Worldyang Chemical Co.,Ltd.	+86-021-56795779 +8613651600618	sales@worldyachem.com	China	1243	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22963	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58

Supplier	Advantage
Taizhou Suze Chemical Materials Co.,Ltd.	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Shanghai Worldyang Chemical Co.,Ltd.	58
Hubei xin bonus chemical co. LTD	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58

View Lastest Price from 4-Methyl-3-nitroaniline manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-11-22	4-Methyl-3-nitroaniline 119-32-4	US $0.00 / kg	1kg	99%	50 tons	Taizhou Suze Chemical Materials Co.,Ltd.
2022-02-22	4-Methyl-3-nitroaniline 119-32-4	US $0.00 / KG	1KG	98.3%	100 tons	Honest Joy Holdings Limited
2019-07-06	4-Methyl-3-nitroaniline 119-32-4	US $8.00 / kg	1kg	99%	10TON	Career Henan Chemical Co

4-Methyl-3-nitroaniline
119-32-4
US $0.00 / kg
99%
Taizhou Suze Chemical Materials Co.,Ltd.

4-Methyl-3-nitroaniline
119-32-4
US $0.00 / KG
98.3%
Honest Joy Holdings Limited

4-Methyl-3-nitroaniline
119-32-4
US $8.00 / kg
99%
Career Henan Chemical Co

4-Methyl-3-nitroaniline Spectrum

4-Methyl-3-nitroaniline(119-32-4)MS 4-Methyl-3-nitroaniline(119-32-4)¹HNMR 4-Methyl-3-nitroaniline(119-32-4)¹³CNMR 4-Methyl-3-nitroaniline(119-32-4)IR1 4-Methyl-3-nitroaniline(119-32-4)IR2 4-Methyl-3-nitroaniline(119-32-4)IR3

119-32-4(4-Methyl-3-nitroaniline)Related Search:

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Musk ketone 9-DICYANOMETHYLENE-2,4,7-TRINITROFLUORENE MUSK TIBETEN 2,4-DINITROBENZOIC ACID 2,4,5,7-TETRANITRO-9-FLUORENONE

Musk xylene 2,4,7-TRINITRO-9-FLUORENONE 3,5-Dinitro-2-methylbenzoic acid 4-Methyl-3-nitroaniline 1,1,3,3,5-PENTAMETHYL-4,6-DINITROINDANE

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LABOTEST-BB LTBB000402 5-nitro-4-toluidin p-Toluidine, 3-nitro- 4-methyl-3-nitro-benzenamin 4-Amino-2-nitrotoluene~3-Nitro-p-toluidine 4-Methyl-3-Nitro Benzeneamine 4-METHYL-3-NITROANILINE OEKANAL, 250 MG Benzenamine, 4-methyl-3-nitro- 3-NITRO-PARA-TOLUIDINE Red Base GL 3-Nitro-p-toluidine (NH2=1) 4-METHYL-3-NITROANILINE 98% 4-METHYL-3-NITROLANILINE 3-NITRO-4-TOLUIDINE 4-AMINO-1-METHYL-2-NITROBENZENE 4-AMINO-6-NITROTOLUENE 4-METHYL-3-NITROBENZENAMINE 4-METHYL-3-NITROANILINE 1-AMINO-4-METHYL-2-NITROBENZENE 2-NITRO-4-METHYL ANILINE 2-NITRO-4-AMINOTOLUENE 2-Nitro-4-toluidine M-NITRO-O-TOLUIDINE m-Nitro-p-toluidine' RED G BASE RED GL BASE TIMTEC-BB SBB007596 3-nitro-4-aminomethylbenzene 3-nitro-4-toluidin 3-nitro-p-toluidin 3-Nitro-4-methylaniline, 3-Nitro-p-toluidine, 4-Amino-2-nitro-toluene 3-Nitro-4-methylbenzenamine 4-Methyl-3-nitroaniline,97% 3-Nitro-4-methylaniline / 4-Amino-2-nitrotoluene 4-Amino-2-nitrotoluene (4-Methyl-3-nitroaniline) 4-Amino-2-nitrotoluene, 5-Amino-2-methylnitrobenzene NSC 7731 4-Amino-1-methyl-2-nitrobenzene 3-Nitro-p-toluidine 4-Methyl-3-nitroaniline, 97% 25GR 4-Methyl-3-nitroaniline, 97% 5GR p-Toluidine, 3-nitro- (8CI) 4-Amino-2-nitrotoluene, 5-Amino-2-methylnitrobenzene, 3-Nitro-p-toluidine 3-Nitro-methylaniline 4-Methyl-3-nitroaniline ISO 9001：2015 REACH m-Nitro-ρ-toluidine LABOTEST-BB LTBB000623 FAST RED G BASE FAST RED GL FAST RED GL BASE 5-Nitro-4-toluidine Gl-amin META NITRO PARA TOLUIDINE 3-NITRO-P-TOLUIDINE 3-NITRO-4-METHYLANILINE 3-NITRO-4-AMINOTOLUENE 4-AMINO-2-NITROTOLUENE MNPT 4-Methyl-2-Nitroaniline (MNPT)