Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride

CAS No.
2055837-32-4
Chemical Name:
Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride
Synonyms
Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride;Bis(triphenyl-lambda5-phosphanylidene)ammonium hydrogendifluoride;Triphenyl[(triphenylphosphoranylidene)amino]phosphonium Fluoride Hydrofluoride
CBNumber:
CB24813767
Molecular Formula:
C36H31F2NP2
Molecular Weight:
577.6
MDL Number:
MFCD31807315
MOL File:
2055837-32-4.mol

Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Properties

storage temp. 2-8°C

Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 901741 Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride 2055837-32-4 100mg $174 2023-06-20 Buy
Sigma-Aldrich 901741 Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride 2055837-32-4 250mg $423 2023-06-20 Buy
Product number Packaging Price Buy
901741 100mg $174 Buy
901741 250mg $423 Buy

Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Chemical Properties,Uses,Production

Uses

Bifluoride salt reported by K. Barry Sharpless and colleagues as a catalyst for sulfur(VI) fluoride exchange (SuFEx)-based AA-BB polycondensation reactions to prepare polysulfonates with diverse structures, narrow polydispersity, and excellent thermal and hydrolytic stability. Bisalkylsulfonyl fluorides, the AA monomers, were prepared from ethenesulfonyl fluoride (746959) and amines/anilines while bisphenol bis(t-butyldimethylsilyl) ethers, the BB monomers, were synthesized using tert-butyldimethylsilyl chloride (190500) and bisphenols. Varying the amines, anilines, and bisphenols results in assorted polymeric backbones, including those bearing orthogonal side chains for modification post-polymerization (e.g. by CuAAC). Reaction is amenable to scale up.

General Description

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Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Preparation Products And Raw materials

Raw materials

Preparation Products

Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Suppliers

Global( 5)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52927 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 SY06@accelachem.com China 10313 58
Shanghai Aladdin Biochemical Technology Co.,Ltd. +86-18521732826 market@aladdin-e.com China 48465 58
Bis(triphenyl-λ5-phosphanylidene)ammonium hydrogendifluoride Bis(triphenyl-lambda5-phosphanylidene)ammonium hydrogendifluoride Triphenyl[(triphenylphosphoranylidene)amino]phosphonium Fluoride Hydrofluoride 2055837-32-4