POTASSIUM 2-METHYL-2-BUTOXIDE
- CAS No.
- 41233-93-6
- Chemical Name:
- POTASSIUM 2-METHYL-2-BUTOXIDE
- Synonyms
- Potassium tert-amylate;potassium 2-methylbutan-2-olate;POTASSIUM TERT-PENTOXIDE;POTASSIUM TERT-PENTYLATE;Potassium T-Amylate;Kta;potassium-amylate;potassium tert-pentoxide solution;POTASSIUM 2-METHYL-2;POTASSIUM T-AMYLOXIDE
- CBNumber:
- CB2487346
- Molecular Formula:
- C5H13KO
- Molecular Weight:
- 128.26
- MDL Number:
- MFCD00064808
- MOL File:
- 41233-93-6.mol
- MSDS File:
- SDS
| Melting point | >160°C dec |
|---|---|
| Boiling point | 81°C |
| Density | 0.90 g/mL at 20 °C |
| vapor pressure | 0.001-0.49Pa at 20-90℃ |
| Flash point | 4°C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | soluble in THF, DME, aromatic hydrocarbons |
| form | Liquid |
| Specific Gravity | 0.8 |
| Water Solubility | Reacts with water. |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 4149025 |
| Exposure limits |
ACGIH: TWA 20 ppm OSHA: Ceiling 300 ppm; TWA 200 ppm NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) |
| InChIKey | ZRLVQFQTCMUIRM-UHFFFAOYSA-N |
| EPA Substance Registry System | 2-Butanol, 2-methyl-, potassium salt (41233-93-6) |
| UNSPSC Code | 12352001 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H304-H314-H336-H361d-H373-H412 | |||||||||
| Precautionary statements | P210-P280-P301+P310+P331-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310 | |||||||||
| Hazard Codes | F,C | |||||||||
| Risk Statements | 11-14-34-48/20-63-65-67-40-37-19 | |||||||||
| Safety Statements | 26-36/37/39-43-45-62-16 | |||||||||
| RIDADR | UN 2924 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 1-10 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| NFPA 704 |
|
POTASSIUM 2-METHYL-2-BUTOXIDE price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 60435 | Potassium tert-pentoxide solution technical, ~25% in toluene (T, ~1.7 M) | 41233-93-6 | 250ml | $133 | 2024-03-01 | Buy |
| Sigma-Aldrich | 60435 | Potassium tert-pentoxide solution technical, ~25% in toluene (T, ~1.7 M) | 41233-93-6 | 1l | $337 | 2024-03-01 | Buy |
| TCI Chemical | P2246 | Potassium tert-Pentoxide (ca. 15% in Cyclohexane, ca. 1mol/L) | 41233-93-6 | 25mL | $78 | 2021-12-16 | Buy |
| TCI Chemical | P2246 | Potassium tert-Pentoxide (ca. 15% in Cyclohexane, ca. 1mol/L) | 41233-93-6 | 100mL | $272 | 2021-12-16 | Buy |
| Alfa Aesar | 041394 | Potassium tert-pentyloxide, 14-18% w/v in cyclohexane | 41233-93-6 | 25g | $93.65 | 2024-03-01 | Buy |
POTASSIUM 2-METHYL-2-BUTOXIDE Chemical Properties,Uses,Production
Uses
Potassium tert-pentyloxide is used in wide range of applications in organic synthesis, agrochemicals, pharmaceuticals, colorants and aroma chemicals. It is also used in manufacturing detergents and biodiesel. They also act as catalysts in polymerization and isomerizations.
Uses
Potassium tert-pentoxide solution has been used as a base to synthesize [RuClPh(CO)(H2IMes)(PCy3)] from second-generation Grubbs metathesis catalyst, [RuCl2(=CHPh)(H2IMes)(PCy3)], (where H2IMes is 1,3-dimethyl-4,5-dihydroimidazol-2-ylidene and PCy3 is tricyclohexylphosphine) and benzyl alcohol. This complex is a solid, air-stable and highly active isomerization catalyst.
Synthesis
The Preparative Method of Potassium 2-Methyl-2-butoxide: amber-coloured 0.15-0.20 M EtCMe2OH solutions of the reagent are prepared in situ by refluxing oxide-free potassium metal in the anhydrous alcohol for 3-4 h. Solutions of the base, which are 1.0-2.0 M in THF, benzene, or toluene, are prepared by treating oil-free Potassium Hydride with an equivalent amount of anhydrous t-pentyl alcohol in the anhydrous solvent under an inert atmosphere.
Precautions
Solutions should be handled with the same precautions used for solutions of t-BuOK (see Potassium t-Butoxide). Avoid contact with the eyes, skin, and clothing. Conduct all reactions under a dry nitrogen or argon atmosphere. In the absence of air and moisture, solutions of the base in benzene or toluene may be stored in a refrigerator for up to 1 year without significant deterioration. However, for critical experiments, it is recommended that the reagent be freshly prepared. Use in a fume hood.
POTASSIUM 2-METHYL-2-BUTOXIDE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531157085 | abby@chuanghaibio.com | China | 8808 | 58 |
| Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12809 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5868 | 58 |
| Hangzhou ICH Biofarm Co., Ltd | +86-0571-28186870; +undefined8613073685410 | sales@ichemie.com | China | 1015 | 58 |
| Hangzhou Bayee Chemical Co., Ltd. | 0086-571-86990109 | rachelhoo@bayeechem.com | China | 104 | 55 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21628 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29859 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
View Lastest Price from POTASSIUM 2-METHYL-2-BUTOXIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-04-23 | POTASSIUM 2-METHYL-2-BUTOXIDE
41233-93-6
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-03-21 | POTASSIUM 2-METHYL-2-BUTOXIDE
41233-93-6
|
US $100.00 / KG | 1KG | 99% | 5000KG | Hebei Mujin Biotechnology Co.,Ltd | |
 |
2024-10-11 | POTASSIUM 2-METHYL-2-BUTOXIDE
41233-93-6
|
US $9.00 / KG | 1KG | 99.8% | 100tons | Hebei Chuanghai Biotechnology Co,.LTD |
-
- POTASSIUM 2-METHYL-2-BUTOXIDE
41233-93-6
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- POTASSIUM 2-METHYL-2-BUTOXIDE
41233-93-6
- US $100.00 / KG
- 99%
- Hebei Mujin Biotechnology Co.,Ltd
-
- POTASSIUM 2-METHYL-2-BUTOXIDE
41233-93-6
- US $9.00 / KG
- 99.8%
- Hebei Chuanghai Biotechnology Co,.LTD