ChemicalBook >> CAS DataBase List >>(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE
(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE
- CAS No.
- 851308-40-2
- Chemical Name:
- (R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE
- Synonyms
- r-np-xyl;(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]eth;(R)-1-[(R)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine;(R)-1-[(S)-2-(Di-1-naphtylphosphino)ferrocenyl]-ethyl-di-3,5-xylylphosphine;(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine;(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine >=97%;(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine,Min.97%;(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino) ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%;(2R)-1-[(1R)-1-[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE;(r,r)-1-{1-[bis(3,5-dimethylphenyl)phosphino]ethyl}-2-[di(1-naphthyl)phosphino]ferrocene (acc to cas)
- CBNumber:
- CB2501536
- Molecular Formula:
- C43H39P2.C5H5.Fe
- Molecular Weight:
- 738.669
- MDL Number:
- MFCD08561162
- MOL File:
- 851308-40-2.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
alpha | -163° ±10° (c 0.5, CHCl3) |
---|---|
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | Powder |
color | orange |
CAS DataBase Reference | 851308-40-2 |
(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE price More Price(13)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Strem Chemicals | 26-1175 | (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97% | 851308-40-2 | 100mg | $107 | 2024-03-01 | Buy |
Strem Chemicals | 26-1175 | (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97% | 851308-40-2 | 500mg | $375 | 2024-03-01 | Buy |
Strem Chemicals | 26-1175 | (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97% | 851308-40-2 | 2g | $1031 | 2024-03-01 | Buy |
Strem Chemicals | 26-1175 | (R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97% | 851308-40-2 | 10g | $4379 | 2024-03-01 | Buy |
American Custom Chemicals Corporation | CCH0004828 | (R)-1-((SP)-2-(DI(1-NAPHTHYL)PHOSPHINO)FERROCENYL)ETHYLDI(3,5-XYLYL)PHOSPHINE 95.00% | 851308-40-2 | 1G | $1269.75 | 2021-12-16 | Buy |
(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE Chemical Properties,Uses,Production
Reactions
- Ferrocenylphosphine ligands of the type cpFecp(PR2)(*CH(CH3)PR'2) are a class of asymmetric ligands developed at Solvias in Basel, Switzerland. Ligands of this type are currently used industrially in the stereoselective synthesis of commercial products. A unique feature of these bidentate ligands is the presence of a fixed phosphine moiety and a stereogenic, functionalized side chain, which can be easily modified to accommodate electronic and steric requirements. Based on a versatile synthetic procedure starting with optically active ferrocenes of the type cpFecp(PR2)(*CH(CH3)X) [X = OAc or NR2], a variety of donor atoms can be introduced into the side chain.4 These ferrocene based phosphine ligands have wide application in the stereoselective hydrogenation of substituted acetamidoacrylates, enol acetates, β-ketoesters and simple alkenes.
- Useful as a ligand in Pd-catalyzed C-N bond-forming reactions.
- Pd-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides.
- Asymmetric hydrogenation of ketones and phosphinylketimines.
- Michael addition of Grignard reagents to α,α-unsaturated esters and thioesters.
- Boration of α,α-unsaturated esters and nitriles.
- Reaction of aryl halides with ammonia.
- Cu-catalyzed reduction of activated C=C bonds with PMHS.
- Regio- and enantioselective hydroboration of vinyl arenes.
- Rh-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes.
Chemical Properties
Orange powder
General Description
sold in collaboration with Solvias AG
(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE Preparation Products And Raw materials
Raw materials
Preparation Products
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851308-40-2((R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE)Related Search:
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1,3-Bis(diphenylphosphino)propane
1of4
(r,r)-1-{1-[bis(3,5-dimethylphenyl)phosphino]ethyl}-2-[di(1-naphthyl)phosphino]ferrocene (acc to cas)
(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino) ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%
(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]eth
(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine,Min.97%
(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine
(R)-1-[(S)-2-(Di-1-naphtylphosphino)ferrocenyl]-ethyl-di-3,5-xylylphosphine
(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine >=97%
(R)-1-[(R)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine
r-np-xyl
1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1S)-1-[bis(3,5-dim ethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3 ,4,5-cyclopentanepentayl, iron salt (1:1:1)
(2R)-1-[(1R)-1-[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE
Ferrocene, 1-[(1R)-1-[bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-, (2R)- (9CI)
851308-40-2
C48H44FeP2
Josiphos Series
Chiral Phosphine
Ferrocene Series
organometallic complex