9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline
![9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline Structure](CAS/GIF/70173-54-5.gif)
- CAS No.
- 70173-54-5
- Chemical Name:
- 9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline
- Synonyms
- 9-Bromo-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinoline;4-BROMO-JULOLIDINE;9-BROMO-JULOLIDINE;1H,5H-Benzo[ij]quinolizine, 9-bromo-2,3,6,7-tetrahydro-;9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline;9-Bromo-2,3,6,7-tetrahydro-1h,5h-pyrido[3,2,1-ij]quinolone
- CBNumber:
- CB2682268
- Molecular Formula:
- C12H14BrN
- Molecular Weight:
- 252.15
- MDL Number:
- MFCD03001720
- MOL File:
- 70173-54-5.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 36.5 °C |
|---|---|
| Boiling point | 135.0-136.5 °C(Press: 0.15 Torr) |
| Density | 1.48±0.1 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| pka | 5.61±0.20(Predicted) |
| Appearance | Brown to reddish brown <36.5°C Solid,>36.5°C Liquid |
| CAS DataBase Reference | 70173-54-5(CAS DataBase Reference) |
| Comptox DTXSID | DTXSID20373703 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| Risk Statements | 20/21/22 |
| Safety Statements | 22-36/37/39 |
| HS Code | 29339900 |
9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline price More Price(38)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AstaTech | 66937 | 9-BROMO-JULOLIDINE 97% | 70173-54-5 | 0.25G | $57 | 2026-04-30 | Buy |
| AstaTech | 66937 | 9-BROMO-JULOLIDINE 97% | 70173-54-5 | 1G | $114 | 2026-04-30 | Buy |
| AstaTech | 66937 | 9-BROMO-JULOLIDINE 97% | 70173-54-5 | 5G | $434 | 2026-04-30 | Buy |
| Synthonix | B55894 | 9-Bromo-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinoline 95% | 70173-54-5 | 250mg | $53 | 2026-05-06 | Buy |
| Synthonix | B55894 | 9-Bromo-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinoline 95% | 70173-54-5 | 1g | $60 | 2026-05-06 | Buy |
9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline Chemical Properties, Uses, Production
Chemical Properties
White Crystalline
Synthesis
479-59-4
![9-BROMO-2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3,2,1-IJ]QUINOLINE](/CAS/GIF/70173-54-5.gif)
70173-54-5
The general procedure for the synthesis of 9-bromo-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinoline from julolidine: julolidine (675 mg, 3.90 mmol) and N-bromosuccinimide (832 mg, 4.68 mmol) were dissolved in 10 mL of N,N-dimethylformamide (DMF), and the reaction was stirred at room temperature for 5 hours. After completion of the reaction, the crude product was purified by silica gel column chromatography (eluent: hexane/dichloromethane, 3:1, v/v) to afford the target compound 9-bromo-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinoline (786 mg, 80% yield) as an oil. The structure of the product was confirmed by the following characterization: 1H NMR (500 MHz, CDCl3) δ/ppm: 6.87 (s, 2H), 3.10 (t, 4H, J=5.50 Hz), 2.70 (t, 4H, J=6.35 Hz), 1.94 (m, 4H); 13C NMR (500 MHz, CDCl3) δ/ppm: 142.0 ,129.3,123.7,107.3,50.0,27.6,21.9; IR (KBr, cm-1): 3045,2935,2836,1581,1506,1462,1446,1310; high-resolution mass spectrometry (TOFMS-EI) m/z: calculated value C12H14NBr [M]+ 251.0310 , measured value 251.0309.
References
[1] Chemical and Pharmaceutical Bulletin, 1984, vol. 32, # 5, p. 1770 - 1779
[2] Canadian Journal of Chemistry, 2009, vol. 87, # 2, p. 440 - 447
[3] Journal of Organic Chemistry, 2011, vol. 76, # 22, p. 9391 - 9408
[4] Dyes and Pigments, 2013, vol. 99, # 3, p. 653 - 660
[5] European Journal of Organic Chemistry, 2011, # 30, p. 6100 - 6109
9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline Preparation Products And Raw materials
9-Bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 18916372613 | yanzihan@shyuanye.com | China | 87240 | 60 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Shanghai Rlavie Technology Co., Ltd. | 021-67759270 17717059219 | sales@rlavie.com | China | 1756 | 55 |
| Dalian lichuang Chemical Co., Ltd | 0411-0411-00000000 13644282108 | 3500508746@qq.com | China | 2968 | 55 |
| Aikon International Limited | 025-58859352 13913916777 | dt3@aikonchem.com | China | 15490 | 58 |
| Suzhou Nuoouman Biological Technology Co., Ltd. | 15026866316 | 180642609@qq.com | China | 4964 | 58 |
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2022-09-12 | 9-Bromo-2,3,6,7-tetrahydro-1h,5h-pyrido[3,2,1-ij]quinolone
70173-54-5
|
1G | 98%min | 50kg/month | Shanghai Rlavie Technology Co ltd |
-
- 9-Bromo-2,3,6,7-tetrahydro-1h,5h-pyrido[3,2,1-ij]quinolone
70173-54-5
- 98%min
- Shanghai Rlavie Technology Co ltd
