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Dipropionyl peroxide(in solution,content≤27%)

CAS No.
3248-28-0
Chemical Name:
Dipropionyl peroxide(in solution,content≤27%)
Synonyms
Propionyl peroxide.;dipropionyl peroxide;Bis(1-oxopropyl)peroxide;Bis(1-oxopropyl) peroxide;Peroxide, bis(1-oxopropyl);propanoyl propaneperoxoate;peroxypropionic acid propionyl ester;dipropionyl peroxide, <= 27% in solution;Dipropionyl peroxide(in solution,content≤27%)
CBNumber:
CB2851947
Molecular Formula:
C6H10O4
Molecular Weight:
146.14
MDL Number:
MFCD00126887
MOL File:
3248-28-0.mol
Last updated:2023-05-26 13:35:53

Dipropionyl peroxide(in solution,content≤27%) Properties

Melting point 200 °C
Boiling point 185.74°C (rough estimate)
Density 1.0945 (rough estimate)
refractive index 1.4310 (estimate)
EPA Substance Registry System Peroxide, bis(1-oxopropyl) (3248-28-0)

SAFETY

Risk and Safety Statements

RIDADR  3117
HazardClass  5.2
PackingGroup  II

Dipropionyl peroxide(in solution,content≤27%) Chemical Properties,Uses,Production

Uses

Initiator in polymerization reactions, such as the high-pressure polymerization of ethylene.

Definition

Avail- able as a 25% solution in a high-boiling hydrocar- bon, flash p 125F (51.6C).

General Description

Available only as a 25% solution. Pure material poses a severe explosion hazard. Used as an initiator in polymerization reactions.

Air & Water Reactions

Highly flammable. May ignite spontaneously if exposed to air.

Reactivity Profile

Dipropionyl peroxide(in solution,content≤27%) is a good oxidizing agent. May cause ignition of organic compounds on contact . Reacts violently with strongly reduced material such as sulfides, nitrides, and hydrides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. May become explosive when evaporated to dryness or near-dryness. May explode from heat, contamination or loss of temperature control.

Hazard

Strong oxidizing agent, may explode if shocked or heated.

Safety Profile

material explodes at room temperature. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES.

123-62-6
3248-28-0
Synthesis of Dipropionyl peroxide(in solution,content≤27%) from Propionic anhydride

Dipropionyl peroxide(in solution,content≤27%) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dipropionyl peroxide(in solution,content≤27%) dipropionyl peroxide Propionyl peroxide. dipropionyl peroxide, <= 27% in solution Bis(1-oxopropyl) peroxide Bis(1-oxopropyl)peroxide peroxypropionic acid propionyl ester propanoyl propaneperoxoate Peroxide, bis(1-oxopropyl) 3248-28-0 CH3CH2CO2O2