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Diisobutyryl peroxide

CAS No.
3437-84-1
Chemical Name:
Diisobutyryl peroxide
Synonyms
Isobutyryl peroxide;Diisobutyryl peroxide;bisisobutyryl peroxide;Diisobutyroyl peroxide;diisobutyryl peroxide, 33-52%;Bis(2-methyl-1-oxopropyl)peroxide;Bis(2-methyl-1-oxopropyl) peroxide;Peroxide,bis(2-methyl-1-oxopropyl);Peroxide, bis(2-methyl-1-oxopropyl);2-methylpropanoyl 2-methylpropaneperoxoate
CBNumber:
CB4852034
Molecular Formula:
C8H14O4
Molecular Weight:
174.19
MDL Number:
MOL File:
3437-84-1.mol
MSDS File:
SDS
Last updated:2023-05-04 15:16:39

Diisobutyryl peroxide Properties

Boiling point 225.17°C (rough estimate)
Density 1.0817 (rough estimate)
vapor pressure 1.2-2.41hPa at 20-25℃
refractive index 1.4220 (estimate)
Water Solubility 49.1g/L at 25℃
LogP 0.94-2.6 at 20-25℃
FDA UNII 25V73818UN
EPA Substance Registry System Peroxide, bis(2-methyl-1-oxopropyl) (3437-84-1)

Diisobutyryl peroxide Chemical Properties,Uses,Production

General Description

Diisobutyryl peroxide(in solution,content≤52%) is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently.

Reactivity Profile

Most of the isolated diacyl(including sulfonyl) peroxides are solids with relatively low decomposition temperatures, and are explosive, and sensitive to shock, heat, or friction. Several, particularly the lower members, will detonate on the slightest disturbance. Autocatalytic, self-accelerating decomposition, which is promoted by tertiary amines, is involved. A sample of ISOBUTYRYL PEROXIDE in ether was being evaporated to dryness with a stream of air when Diisobutyryl peroxide(in solution,content≤52%) exploded violently, [MCA Case History No. 579]. Can generate electrostatic charges. REF [Handling Chemicals Safely, 1980. p. 250].

Flammability and Explosibility

Not classified

Safety Profile

May explode when dried at room temperature. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES.

Diisobutyryl peroxide Preparation Products And Raw materials

Raw materials

Preparation Products

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bisisobutyryl peroxide Isobutyryl peroxide Diisobutyryl peroxide Peroxide, bis(2-methyl-1-oxopropyl) Peroxide,bis(2-methyl-1-oxopropyl) Diisobutyryl peroxide(in solution,content≤52%) Diisobutyroyl peroxide Bis(2-methyl-1-oxopropyl) peroxide Bis(2-methyl-1-oxopropyl)peroxide 2-methylperoxypropionic acid isobutyryl ester 2-methylpropanoyl 2-methylpropaneperoxoate diisobutyryl peroxide, 33-52% Diisobutyryl peroxide[content ≤32%, with type B thinner ≥68%] 3437-84-1 CH32CHCO2O2