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ChemicalBook >> CAS DataBase List >>Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Structure
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) structure
CAS No.
488809-34-3
Chemical Name:
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
Synonyms
(S)-[(RuCl(SEGPHOS;))?(μ-Cl)?][NH?Me?];NH2ME2][(RUCL((S)-SEGPHOS))2(U-CL)3;(S)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2];[NH2ME2][(RUCL((S)-SEGPHOS))2(Μ-CL)3];[NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3];(S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2];(S)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2];[NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3];Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
CBNumber:
CB31181091
Molecular Formula:
C78H68Cl5NO8P4Ru2
Molecular Weight:
1650.69
MDL Number:
MFCD09753037
MOL File:
488809-34-3.mol
Last updated:2023-06-08 17:06:34
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Properties

Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color light brown
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS08
Signal word  Danger
Hazard statements  H373-H360-H371
Precautionary statements  P260-P314-P501-P260-P264-P270-P309+P311-P405-P501
WGK Germany  3
HS Code  2843.90.0000

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 693162 (S)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] 488809-34-3 50mg $25.5 2023-01-07 Buy
Sigma-Aldrich 693162 (S)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] 488809-34-3 100mg $44 2023-01-07 Buy
TCI Chemical N1022 [NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3] 488809-34-3 200mg $56 2024-03-01 Buy
TCI Chemical N1022 [NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3] 488809-34-3 1g $180 2024-03-01 Buy
Strem Chemicals 44-0519 Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos(R))}2(μ-Cl)3] 488809-34-3 250mg $53 2024-03-01 Buy
Product number Packaging Price Buy
693162 50mg $25.5 Buy
693162 100mg $44 Buy
N1022 200mg $56 Buy
N1022 1g $180 Buy
44-0519 250mg $53 Buy

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Chemical Properties,Uses,Production

Reaction

  1. Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature. 
  2. Catalyst for enantioselective hydrogenation of enamines. 
Reactions of 488809-34-3

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Suppliers

Global( 29)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaoxin Catsyn Co., Ltd. 		+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6116 58
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 57511 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44700 61
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340 307593986@qq.com China 475 58
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28398 80
TCI Europe 320-37350700 sales@tcieurope.eu Europe 23680 75
TCI AMERICA 800-4238616 sales@tciamerica.com Americas 23662 75
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Supplier Advantage
Shaoxin Catsyn Co., Ltd. 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Shanghai Incat Chemtech Co.,Ltd. 58
TOKYO CHEMICAL INDUSTRY CO., LTD. 80
TCI Europe 75
TCI AMERICA 75
Sigma-Aldrich 80

488809-34-3(Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II))Related Search:

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　
Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　 Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

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[NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3] [NH2ME2][(RUCL((S)-SEGPHOS))2(Μ-CL)3] DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]DIRUTHENATE(II),[NH2ME2][ Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) (S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2] Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II) Dimethylammonium dichlorotri(chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(Cl)3] DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(μ-Cl)3] (S)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2] Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos(R))}2(μ-Cl)3] [NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3] (S)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2] NH2ME2][(RUCL((S)-SEGPHOS))2(U-CL)3 (S)-[(RuCl(SEGPHOS ))?(μ-Cl)?][NH?Me?] Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) 488809-34-3 CH32NH2C76H56Cl5O8P4Ru28722 Ru