ChemicalBook >> CAS DataBase List >>(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%

CAS No.
817176-80-0
Chemical Name:
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
Synonyms
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%;(S)-(1,2',3,3'-Tetrahydro-1,2'-spirobi[indene]-4,7'-diyl)bis(di-p-tolylphosphine);(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE];Phosphine, 1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)-
CBNumber:
CB32129579
Molecular Formula:
C45H42P2
Molecular Weight:
644.76
MDL Number:
MFCD08459345
MOL File:
817176-80-0.mol
Last updated:2023-04-23 13:52:06

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Properties

Melting point 150-152°C
Boiling point 722.0±60.0 °C(Predicted)
alpha -221° (c 0.54, CH2Cl2)
storage temp. -20°C
form solid
color white
optical activity [α]22/D 206°, c = 1 in chloroform
Sensitive air sensitive
InChIKey VLIOMJFCGWZUON-UHFFFAOYSA-N

SAFETY

Risk and Safety Statements

WGK Germany  3

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 700835 (S)-Tol-SDP 817176-80-0 50mg $169 2022-05-15 Buy
Strem Chemicals 15-5181 (S)-(-)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-Tol-SDP 817176-80-0 25mg $76 2024-03-01 Buy
Strem Chemicals 15-5181 (S)-(-)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-Tol-SDP 817176-80-0 100mg $229 2024-03-01 Buy
Product number Packaging Price Buy
700835 50mg $169 Buy
15-5181 25mg $76 Buy
15-5181 100mg $229 Buy

(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Chemical Properties,Uses,Production

Reaction

  1. Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
  2. Ligands used for palladium-catalyzed asymmetric allylic alkylations. 

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(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% 1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE] Phosphine, 1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)- (S)-(1,2',3,3'-Tetrahydro-1,2'-spirobi[indene]-4,7'-diyl)bis(di-p-tolylphosphine) 817176-80-0