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ChemicalBook >> CAS DataBase List >>2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Structure
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL structure
CAS No.
84783-64-2
Chemical Name:
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Synonyms
BIPHEP;98% BIPHEP;2,2'-Bis(diphenyL;phosphino)-1,1'-biphenyL;2,2'-Bis(diphenylphosphino)-1;2,2'-Bis(diphenylphosphino)bip;2,2'-Bis(diphenylphosphino)biphenyl;2,2'-Bis(diphenylphosphino)biphenyl >2,2’-Bis(diphenylphospino)-1,1’-biphenyl;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl
CBNumber:
CB3357299
Molecular Formula:
C36H28P2
Molecular Weight:
522.55
MDL Number:
MFCD03094574
MOL File:
84783-64-2.mol
Last updated:2025-01-27 09:38:02
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2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Properties

Melting point 210-214 °C
Boiling point 635.5±48.0 °C(Predicted)
solubility soluble in Toluene
form crystal
color white
UNSPSC Code 12352200

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38-36
Safety Statements  37/39-26
TSCA  No
HS Code  29310099
NFPA 704
0
2 1

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich CDS020234 2,2′-Bis(diphenylphosphino)-1,1′-biphenyl AldrichCPR 84783-64-2 25MG $70.9 2024-03-01 Buy
TCI Chemical B2630 2,2'-Bis(diphenylphosphino)biphenyl >98.0%(GC) 84783-64-2 1g $163 2024-03-01 Buy
TCI Chemical B2630 2,2'-Bis(diphenylphosphino)biphenyl >98.0%(GC) 84783-64-2 100mg $29 2024-03-01 Buy
Alfa Aesar H31306 2,2'-Bis(diphenylphosphino)biphenyl, 98% 84783-64-2 1g $178.65 2024-03-01 Buy
Alfa Aesar H31306 2,2'-Bis(diphenylphosphino)biphenyl, 98% 84783-64-2 5g $583.65 2024-03-01 Buy
Product number Packaging Price Buy
CDS020234 25MG $70.9 Buy
B2630 1g $163 Buy
B2630 100mg $29 Buy
H31306 1g $178.65 Buy
H31306 5g $583.65 Buy

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties,Uses,Production

Reaction

  1. Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
  2. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
  3. Useful ligand for palladium-catalyzed synthesis of butatrenes.
  4. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
  5. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
  6. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
  7. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
  8. Ruthenium-catalyzed synthesis of indoles.
  9. Ruthenium-catalyzed oxidative cyclization.
  10. Rhodium-catalyzed boron arylation. 
Reactions of 84783-64-2_1
Reactions of 84783-64-2_2
Reactions of 84783-64-2_3

Chemical Properties

white crystalline powder or crystals

Uses

2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Suppliers

Global( 118)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd 		+86-15531157085 +86-15531157085 abby@chuanghaibio.com China 8805 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-+86-371-66670886 info@dakenam.com China 19852 58
Nanjing Dolon Biotechnology Co.,Ltd. 		18905173768 sales@dolonchem.com CHINA 2972 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
Shaanxi Dideu Medichem Co. Ltd 		+86-29-81139210 +86-18192627656 1059@dideu.com China 3003 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5600 58
Antai Fine Chemical Technology Co.,Limited 		18503026267 info@antaichem.com CHINA 9636 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com China 52849 58
CD Chemical Group Limited 		+8615986615575 info@codchem.com China 20342 58
Henan Alfa Chemical Co., Ltd 		China 13179 58
Supplier Advantage
Hebei Chuanghai Biotechnology Co., Ltd 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
Nanjing Dolon Biotechnology Co.,Ltd. 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Shaanxi Dideu Medichem Co. Ltd 		58
Richest Group Ltd 		58
Antai Fine Chemical Technology Co.,Limited 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
CD Chemical Group Limited 		58
Henan Alfa Chemical Co., Ltd 		58

View Lastest Price from 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL pictures 2025-02-19 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
84783-64-2
 US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
2,2'-Bis(diphenylphosphino)biphenyl pictures 2020-03-16 2,2'-Bis(diphenylphosphino)biphenyl
84783-64-2
 US $1.00-0.00 / KG 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Spectrum

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL(84783-64-2)1HNMR2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL(84783-64-2)31PNMR

84783-64-2(2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL)Related Search:

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL R-(+)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 3',6'-BIS(DIETHYLAMINO)-2-(4-NITROPHENYL)SPIRO[ISOINDOLE-1,9'-XANTHENE]-3-ONE Diphenylphosphine DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
PHOSPHINE OXIDE, [1,1'-BINAPHTHALENE]-2,2'-DIYLBIS DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) (R)-H8-BINAP
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct

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BIPHEP 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP) 2,2’-Bis(diphenylphospino)-1,1’-biphenyl PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL- 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL,98% 2,2'-Bis(diphenylphosphino)bip {2-[2-(diphenylphosphanyl)phenyl]phenyl}diphenylphosphane 98% BIPHEP 1,1'-[[1,1'-Biphenyl]-2,2'-diyl]bis[1,1-diphenylphosphine] 2,2'-Bis(diphenylphosphino)-1 [2-(2-diphenylphosphinophenyl)phenyl]-diphenylphosphine 2,2'-Bis(diphenylphosphino)biphenyl > 2,2'-Bis(diphenyL phosphino)-1,1'-biphenyL 2,2'-Bis(diphenylphosphino)biphenyl 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98% BIPHEP 2,2''-Bis(diphenylphosphino)-1,1''-biphenyl 84783-64-2 C36H28P2 Phosphine Ligands Achiral Phosphine Aryl Phosphine Phosphines Biphenyl & Diphenyl ether Phosphine Ligands Synthetic Organic Chemistry