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4,5-Dichloro-1,2,3-dithiazolium chloride

CAS No.
75318-43-3
Chemical Name:
4,5-Dichloro-1,2,3-dithiazolium chloride
Synonyms
D14145;Appel salt;Appel's Salt;4,5-Dichlorodithiaz;4,5-dichlorodithiazol-1-ium;4,5-DICHLORO-1,2,3-DITHIAZOLIUM;4,5-Dichlorodithiazol-2-ium chloride;4,5-dichlorodithiazol-1-ium chloride;4,5-Dichloro-[1,2,3]dithiazol-2-ylium;4,5-Dichloro-1,2,3-dithiazolium chloride
CBNumber:
CB3511622
Molecular Formula:
C2Cl3NS2
Molecular Weight:
208.5
MDL Number:
MFCD03426194
MOL File:
75318-43-3.mol
Last updated:2023-10-20 13:21:50

4,5-Dichloro-1,2,3-dithiazolium chloride Properties

Melting point 172° (dec)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
color Brown
FDA UNII 156NP9484D

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H302+H312+H332-H315
Precautionary statements  P280-P301+P312-P362+P364
HS Code  2934999090

4,5-Dichloro-1,2,3-dithiazolium chloride price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC D432328 4,5-Dichloro-1,2,3-dithiazoliumchloride 75318-43-3 500mg $175 2021-12-16 Buy
AK Scientific 4308CS 4,5-Dichloro-1,2,3-dithiazol-1-iumchloride 75318-43-3 1g $215 2021-12-16 Buy
Biosynth Carbosynth FD149446 4,5-Dichloro-1,2,3-dithiazoliumchloride 75318-43-3 1g $250 2021-12-16 Buy
Biosynth Carbosynth FD149446 4,5-Dichloro-1,2,3-dithiazoliumchloride 75318-43-3 2g $450 2021-12-16 Buy
SynQuest Laboratories 7H70-5-0LT 4,5-Dichloro-1,2,3-dithiazol-2-yliumchloride tech% 75318-43-3 5G $453 2021-12-16 Buy
Product number Packaging Price Buy
D432328 500mg $175 Buy
4308CS 1g $215 Buy
FD149446 1g $250 Buy
FD149446 2g $450 Buy
7H70-5-0LT 5G $453 Buy

4,5-Dichloro-1,2,3-dithiazolium chloride Chemical Properties,Uses,Production

Description

4,5-Dichloro-1,2,3-dithiazolium chloride is an useful organosulfur compound. It is the chloride salt of the 4,5-dichloro-1,2,3-dithiazolium cation. It is a green solid that is poorly soluble in organic solvents. Most primary arylamines react readily with 4,5-dichloro-1,2,3-dithiazolium chloride to give, after treatment with tertiary amine base (2 equiv.), the corresponding N-aryl-4-chloro-5H-1,2,3-dithiazolimines in good to excellent yields. This compound is commonly used to synthesize monocyclic 1,2,3-dithiazoles which act as fungicides, antibacterials, antivirals or anticancer agents[1-2].
4,5-DICHLORO-1,2,3-DITHIAZOLIUM CHLORIDE

Uses

Synthon in heterocyclic chemistry; in conversion of alcohols and carboxylic acids to esters.

References

[1] Kalogirou A, et al. The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines. Molecules, 2009; 14: 2356–2362.    
[2] Plakas K, et al. Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with 2-(Phenylsulfonyl)acetonitrile. Molbank, 2022; 2022: M1322.

107-14-2
75318-43-3
Synthesis of 4,5-Dichloro-1,2,3-dithiazolium chloride from Chloroacetonitrile

4,5-Dichloro-1,2,3-dithiazolium chloride Preparation Products And Raw materials

4,5-Dichloro-1,2,3-dithiazolium chloride Suppliers

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4,5-Dichloro-1,2,3-dithiazol-1-ium chloride Appel salt 4,5-Dichloro-1,2,3-dithiazolium chloride D14145 4,5-DICHLORO-1,2,3-DITHIAZOLIUM 4,5-Dichloro-1,2,3-dithiazol-2-ylium chloride 4,5-Dichlorodithiazol-2-ium chloride Appel's Salt 4,5-Dichloro-1,2,3-dithiazol-2-ylium chloride, tech 4,5-Dichlorodithiaz DICHLORO-1,2,3-DITHIAZOL-1-YLIUM CHLORIDE 4,5-dichloro-3H-dithiazol-3-ium chloride 4,5-Dichloro-[1,2,3]dithiazol-2-ylium 4,5-dichlorodithiazol-1-ium 4,5-dichloro-5H-dithiazol-3-ium chloride 4,5-dichlorodithiazol-1-ium chloride dichloro-1lambda4,2,3-dithiazol-1-ylium chloride 1,2,3-Dithiazol-1-ium, 4,5-dichloro-, chloride (1:1) 4,5-dichloro-1,2,3-Dithiazol-1-ium chloride (1:1) 4,5-Dichloro-1,2,3-dithiazol-2-ium Chloride 75318-43-3 C2Cl2NS2Cl