4-Chloro-2-nitroaniline
- CAS No.
- 89-63-4
- Chemical Name:
- 4-Chloro-2-nitroaniline
- Synonyms
- FAST RED 3GL BASE;4-Chloro-2-nitrobenzenamine;PCONA;PARA CHLORO ORTHO NITRO ANILINE;c.i. azoic diazo component no. 9;PCON;red3gsalt;devolredf;NCI-C60355;red3gssalt
- CBNumber:
- CB3854602
- Molecular Formula:
- C6H5ClN2O2
- Molecular Weight:
- 172.57
- MDL Number:
- MFCD00007836
- MOL File:
- 89-63-4.mol
Melting point | 117-119 °C(lit.) |
---|---|
Boiling point | 200°C (rough estimate) |
Density | 1.37 |
refractive index | 1.6460 (estimate) |
Flash point | 191 °C |
storage temp. | room temp |
solubility | 0.5g/l (anhydrous substance) |
Colour Index | 37040 |
pka | pK1: 1.10(+1) (25°C) |
form | Crystalline Powder or Chunks |
color | Orange |
PH | 7 (0.5g/l, H2O, 20℃) |
Water Solubility | INSOLUBLE |
BRN | 512436 |
Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 89-63-4(CAS DataBase Reference) |
FDA UNII | 1929LY233C |
NIST Chemistry Reference | Aniline, 4-chloro-2-nitro-(89-63-4) |
EPA Substance Registry System | 4-Chloro-2-nitroaniline (89-63-4) |
UNSPSC Code | 12352100 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() GHS06,GHS08,GHS09 |
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Signal word | Danger | |||||||||
Hazard statements | H300+H310+H330-H373-H410 | |||||||||
Precautionary statements | P262-P273-P280-P302+P352+P310-P304+P340+P310-P314 | |||||||||
Hazard Codes | T+,N,T | |||||||||
Risk Statements | 26/27/28-33-51/53 | |||||||||
Safety Statements | 28-36/37-45-61-28A | |||||||||
RIDADR | UN 2237 6.1/PG 3 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | BX1575000 | |||||||||
Autoignition Temperature | 964 °F | |||||||||
Hazard Note | Very Toxic | |||||||||
TSCA | Yes | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29214210 | |||||||||
Hazardous Substances Data | 89-63-4(Hazardous Substances Data) | |||||||||
NFPA 704 |
|
4-Chloro-2-nitroaniline Chemical Properties,Uses,Production
Chemical Properties
bright orange powder
Uses
A nitro-aromatic amine with mutagenicity and carcinogenicity
Uses
4-Chloro-2-nitroaniline is used as pharmaceutical intermediate.
Uses
4-Chloro-2-nitroaniline is used almost exclusively as an intermediate in the synthesis of pigments. The greatest potential for human exposure to 4-chloro-2- nitroaniline is in production and use of pigments made from the compound.
Preparation
4-Chloro-2-nitrobenzenamine of chlorine.
Production Methods
1,4-Dichloro-2-nitrobenzene is aminated at 165 ℃ by using a process similar to that described for 2- nitroaniline.
General Description
Bright orange powder.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
4-Chloro-2-nitroaniline forms explosive products on reaction with nitric acid. Can react with oxidizing agents.
Hazard
Toxic by ingestion and inhalation.
Fire Hazard
4-Chloro-2-nitroaniline is probably combustible.
Purification Methods
Crystallise the aniline from hot H2O (m 115.8-116o), EtOH, EtOH/H2O or *C6H6, and dry it for 10hours at 60o in vacuo. It has m 115.5-116o after sublimation. [Beilstein 12 H 729, 12 I 355, 12 II 396, 12 III 1649, 12 IV 1669.]
4-Chloro-2-nitroaniline Preparation Products And Raw materials
Raw materials
Preparation Products
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