Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Structure
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP structure
CAS No.
828927-95-3
Chemical Name:
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
Synonyms
(R,R)-O-PINAP;Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1R)-;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
CBNumber:
CB42527987
Molecular Formula:
C38H29N2OP
Molecular Weight:
560.62
MDL Number:
MFCD11973799
MOL File:
828927-95-3.mol
Last updated:2023-04-23 13:52:06
Request For Quotation

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Properties

Melting point 64-65°C
alpha +78.5° (c 0.25, CHCl3)
Boiling point 726.4±60.0 °C(Predicted)
pka 3.45±0.30(Predicted)
form crystal
color colorless
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-1782 (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP 828927-95-3 250mg $114 2021-12-16 Buy
Strem Chemicals 15-1782 (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP 828927-95-3 1g $342 2021-12-16 Buy
Product number Packaging Price Buy
15-1782 250mg $114 Buy
15-1782 1g $342 Buy

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Chemical Properties,Uses,Production

Reaction

  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
  2. With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
  3. With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
Reactions of 828927-95-3

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP Suppliers

Global( 9)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5818 58
Energy Chemical 021-58432009 400-005-6266 marketing@energy-chemical.com China 44941 58
Jiangsu Nanchuang Chemical and Life Health Research Institute Co., Ltd. 15720605021 zhang_lei@jsnchem.com China 1546 58
Shanghai Haohong Scientific Co., Ltd. 400-400-8210725 malulu@leyan.com China 40041 58
Beijing Solarbio Science & Tecnology Co., Ltd. 010-50973130 17801761073 Gsiyu@solarbio.com China 50751 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Bide Pharmatech Ltd. 60
LaaJoo 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
Energy Chemical 58
Jiangsu Nanchuang Chemical and Life Health Research Institute Co., Ltd. 58
Shanghai Haohong Scientific Co., Ltd. 58
Beijing Solarbio Science & Tecnology Co., Ltd. 58
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP (R,R)-O-PINAP Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1R)- 828927-95-3 C38H29N2OP PINAP Series Chiral Phosphine