ChemicalBook >> CAS DataBase List >>4-Pyrrolidinopyridine
4-Pyrrolidinopyridine
- CAS No.
- 2456-81-7
- Chemical Name:
- 4-Pyrrolidinopyridine
- Synonyms
- Pyridine, 4-(1-pyrrolidinyl)-;4-PyrroL;4-Pyrrolidinylpyridine;IOSTEROL;idinopyridine;TIMTEC-BB SBB004083;4-PYRROLIDINOPYRIDINE;Pyrrolidinyl pyridine;1-(4-PYRIDYL)PYRROLIDINE;N-(4-PYRIDYL)PYRROLIDINE
- CBNumber:
- CB4719087
- Molecular Formula:
- C9H12N2
- Molecular Weight:
- 148.21
- MDL Number:
- MFCD00006415
- MOL File:
- 2456-81-7.mol
- MSDS File:
- SDS
Last updated:2023-04-27 16:27:43
| Melting point | 54-58 °C(lit.) |
|---|---|
| Boiling point | 171-173 °C (20.2527 mmHg) |
| Density | 1.0628 (rough estimate) |
| refractive index | 1.5378 (estimate) |
| Flash point | >230 °F |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | methanol: 0.1 g/mL, clear |
| pka | 9.58±0.10(Predicted) |
| form | Crystalline Mass, Crystals and/or Chunks |
| color | White to yellow to light brown |
| PH | 10.5 (3g/l, H2O, 21℃) |
| Water Solubility | 3 g/L (21 ºC) |
| BRN | 472443 |
| InChIKey | RGUKYNXWOWSRET-UHFFFAOYSA-N |
| CAS DataBase Reference | 2456-81-7(CAS DataBase Reference) |
| FDA UNII | DH59VKG9S4 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H314 | |||||||||
| Precautionary statements | P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 25-34-41-23/24/25 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 2923 8/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 8-10-23 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29333999 | |||||||||
| NFPA 704 |
|
4-Pyrrolidinopyridine price More Price(31)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 213373 | 4-Pyrrolidinopyridine 98% | 2456-81-7 | 25g | $73.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 213373 | 4-Pyrrolidinopyridine 98% | 2456-81-7 | 5g | $88.4 | 2024-03-01 | Buy |
| TCI Chemical | P0939 | 4-Pyrrolidinopyridine >98.0%(T) | 2456-81-7 | 5g | $23 | 2024-03-01 | Buy |
| TCI Chemical | P0939 | 4-Pyrrolidinopyridine >98.0%(T) | 2456-81-7 | 25g | $66 | 2024-03-01 | Buy |
| Alfa Aesar | B23989 | 4-(1-Pyrrolidinyl)pyridine, 98% | 2456-81-7 | 5g | $67.65 | 2024-03-01 | Buy |
4-Pyrrolidinopyridine Chemical Properties,Uses,Production
Description
4-Pyrrolidinopyridine is the pyridine derivative. It can be used as catalyst employed in polymerization reactions or Hypernucleophilic acylation catalyst. For example, it can be used as the catalyst for the geometry-selective (E-selective) acylation of tetrasubstituted α, α'-alkenediols. It can also be used as the ligand in metal complexes such as the Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes.
Chemical Properties
white to light brown crystalline mass
Uses
Catalyst employed in polymerization reactions. Ligand in metal complexes.
Synthesis Reference(s)
Synthetic Communications, 9, p. 251, 1979 DOI: 10.1080/00397917908064147
Synthesis, p. 985, 1988 DOI: 10.1055/s-1988-27777
References
http://www.sigmaaldrich.com/catalog/product/aldrich/213373?lang=en®ion=US
http://www.sigmaaldrich.com/catalog/product/sial/83275?lang=en®ion=US
Yamanaka M et al. "Origin of High E -Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α′-Alkenediol: A Computational and Experimental Study." Journal of Organic Chemistry 80.6(2015):3075-82.
J. G. Ma?ecki, and A. Maroń. "Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand."Transition Metal Chemistry 38.2(2013):133-142.
4-Pyrrolidinopyridine Preparation Products And Raw materials
Global( 281)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 9206 | 55 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10310 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29811 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17365 | 58 |
View Lastest Price from 4-Pyrrolidinopyridine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-09-16 | 4-Pyrrolidinopyridine
2456-81-7
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2021-10-26 | 4-Pyrrolidinopyridine
2456-81-7
|
US $1.10 / g | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | |
 |
2019-12-31 | 4-Pyrrolidinopyridine
2456-81-7
|
US $1.00 / KG | 1KG | 95-99% | 1ton | Career Henan Chemical Co |
-
- 4-Pyrrolidinopyridine
2456-81-7
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- 4-Pyrrolidinopyridine
2456-81-7
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
-
- 4-Pyrrolidinopyridine
2456-81-7
- US $1.00 / KG
- 95-99%
- Career Henan Chemical Co
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4-Pyrrolidinopyridine>
4-Pyrrolidinopyridine ISO 9001：2015 REACH
Pyridine, 4-(1-pyrrolidinyl)-
4-Pyrrolidinylpyridine
4-PyrroL
2456-81-7
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2456-81-7