ChemicalBook >> CAS DataBase List >>4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

CAS No.
53413-67-5
Chemical Name:
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Synonyms
6-NITROVERATRYL BROMIDE;1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;4,5-dimenoxy-2-nitrobenzyl bromide;3,4-Dimethoxy-6-nitrobenzyl bromide;4,5-DIMETHOXY-2-NITROBENZYL BROMIDE;4,5-Dimethoxy-2-nitrobenzyl bromide 95%;4,5-Dimethoxy-2-nitro-1-bromomethylbenzene;1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene
CBNumber:
CB4762285
Molecular Formula:
C9H10BrNO4
Molecular Weight:
276.08
MDL Number:
MFCD00192064
MOL File:
53413-67-5.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Properties

Melting point 131-133 °C (lit.)
Boiling point 372.3±37.0 °C(Predicted)
Density 1.544
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Crystalline Powder or Needles
color Yellow to brown
Sensitive Lachrymatory
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  22-26-27-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
HazardClass  8
PackingGroup  III
HS Code  29093090

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 53413-67-5 1g $124 2024-03-01 Buy
Sigma-Aldrich 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 53413-67-5 5g $196.8 2024-03-01 Buy
Biosynth Carbosynth FB139514 4,5-Dimethoxy-2-nitrobenzyl bromide 53413-67-5 5G $550 2021-12-16 Buy
AK Scientific 7598AB 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene 53413-67-5 5g $271 2021-12-16 Buy
Biosynth Carbosynth FB139514 4,5-Dimethoxy-2-nitrobenzyl bromide 53413-67-5 2g $320 2021-12-16 Buy
Product number Packaging Price Buy
392855 1g $124 Buy
392855 5g $196.8 Buy
FB139514 5G $550 Buy
7598AB 5g $271 Buy
FB139514 2g $320 Buy

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Chemical Properties,Uses,Production

Uses

1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene is a useful research chemical.

Uses

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis of N-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid. It may be used in the synthesis of the following:

  • 4-(4′,5′-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehyde
  • N-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamide
  • caged derivative of pyridostatin ([C]-PDS)
  • photosensitive polyimide (PI-DMNB)
  • caged β-ecdysone
  • 4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SBNV) nucleobase
  • alkylation of dihydrofluorescein
  • 4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde

General Description

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNBB, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene) is a 4,5-dimethoxy-2-nitrobenzyl derivative. 4,5-Dimethoxy-2-nitrobenzyl (DMNB) group of DMNBB is used as a photolabile protecting group in caging technology to develop pro-drugs. Synthesis of 1-(bromomethyl)-4,5-dimethoxy-2-nitrobenzene by using 6-nitroveratraldehyde as starting reagent has been reported.

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Suppliers

Global( 82)Suppliers
Supplier Tel Email Country ProdList Advantage
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10032 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 11849 58
Career Henan Chemica Co
+86-0371-86658258 +8613203830695 laboratory@coreychem.com China 30236 58
Win-Win chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14431 58
Nanjing Fred Technology Co., Ltd
+86-25-84696168 +86-15380713688 Austin@fredbio.com China 2428 58
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43340 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
Compound Net Biotechnology Inc.
+8615303909093 sales@compound-net.com China 2914 58
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE 4,5-Dimethoxy-2-nitrobenzyl bromide 95% 1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene 4,5-dimenoxy-2-nitrobenzyl bromide 3,4-Dimethoxy-6-nitrobenzyl bromide 4,5-Dimethoxy-2-nitro-1-bromomethylbenzene -4,5-dimethoxy-2-nitrobenzene JR-13611, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene, 97% Benzene, 1-(bromomethyl)-4,5-dimethoxy-2-nitro- -4,5-dimethoxy-2-nitrobenzene 6-NITROVERATRYL BROMIDE 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene 53413-67-5 O2NC6H2OCH32CH2Br Organic Building Blocks Nitrogen Compounds Nitro Compounds Building Blocks