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ISOPROPENYLMAGNESIUM BROMIDE

ISOPROPENYLMAGNESIUM BROMIDE structure

CAS No.: 13291-18-4

Chemical Name:: ISOPROPENYLMAGNESIUM BROMIDE

Synonyms: IsopropenyL;Bromoisopropenylmagnesium;ISOPROPENYLMAGNESIUM BROMIDE;1-Methylvinylmagnesium bromide;bromo(prop-1-en-2-yl)magnesium;1-Methylethenylmagnesium bromide;bromo(1-methylethenyl)-Magnesium;(1-Methylethenyl)magnesium bromide;IsopropenylMagnesiuM broMide soluti;Isopropenylmagnesium bromide(1M THF)

CBNumber:: CB4783309

Molecular Formula:: C3H5BrMg

Molecular Weight:: 145.28

MDL Number:: MFCD00192240

MOL File:: 13291-18-4.mol

Last updated:2025-01-27 09:38:02

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ISOPROPENYLMAGNESIUM BROMIDE Properties

Melting point	102-104 °C
Boiling point	67 °C
Density	0.94 g/mL at 20 °C
Flash point	−36 °F
storage temp.	2-8°C
form	Crystalline Powder
color	White to yellow to orange
BRN	3587297
InChIKey	LFTYALBVGVNGLI-UHFFFAOYSA-M
UNSPSC Code	12352103
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225-H260-H302-H314-H335-H351
Precautionary statements	P210-P231+P232-P280-P370+P378-P402+P404-P403+P235
Hazard Codes	F,C
Risk Statements	11-14/15-34-40-37-19-14
Safety Statements	26-30-36/37/39-43-45-7/8-16
RIDADR	UN 3399 4.3/PG 1
WGK Germany	1
F	1-3-10-34
HS Code	29319090

ISOPROPENYLMAGNESIUM BROMIDE price More Price(9)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	419567	Isopropenylmagnesium bromide solution 0.5 M in THF	13291-18-4	100ml	$190	2024-03-01	Buy
Sigma-Aldrich	419567	Isopropenylmagnesium bromide solution 0.5 M in THF	13291-18-4	800ml	$352	2024-03-01	Buy
Sigma-Aldrich	772836	Isopropenylmagnesium bromide solution 1.0 M in 2-methyltetrahydrofuran	13291-18-4	25ml	$138	2024-03-01	Buy
Sigma-Aldrich	772836	Isopropenylmagnesium bromide solution 1.0 M in 2-methyltetrahydrofuran	13291-18-4	100ml	$209	2024-03-01	Buy
GFS CHEMICALS	17523	ISOPROPENYLMAGNESIUMBROMIDE,0.5MinTETRAHYDROFURAN	13291-18-4	1L	$180.6	2021-12-16	Buy

Product number	Packaging	Price	Buy
419567	100ml	$190	Buy
419567	800ml	$352	Buy
772836	25ml	$138	Buy
772836	100ml	$209	Buy
17523	1L	$180.6	Buy

ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties,Uses,Production

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.

General Description

This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

reaction suitability

reaction type: Grignard Reaction

Synthesis

The Preparative Method of 2-Propenylmagnesium Bromide-Copper(I) Iodide: prepared in situ under anhydrous conditions by reacting 2-propenylmagnesium bromide (1) with Copper(I) Iodide (2) in varying molar ratios.

ISOPROPENYLMAGNESIUM BROMIDE synthesis

Synthesis of ISOPROPENYLMAGNESIUM BROMIDE from 2-BROMOPROPENE

ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Isopropenylboronic acid pinacol ester H-TBU-GLY-OTBU HCL prop-1-ene-2-sulfonyl chloride

ISOPROPENYLMAGNESIUM BROMIDE Suppliers

Global( 184)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29857	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22963	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49732	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30230	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Apeloa Pharmaceutical Co., Ltd.	+86-0571-87635730 +8615858229168	chem1022@hengdian-group.com	China	1478	58
ANHUI WITOP BIOTECH CO., LTD	+8615255079626	eric@witopchemical.com	China	23541	58

Supplier	Advantage
career henan chemical co	58
Jinan Carbotang Biotech Co.,Ltd.	58
Hubei xin bonus chemical co. LTD	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Antai Fine Chemical Technology Co.,Limited	58
Career Henan Chemica Co	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Apeloa Pharmaceutical Co., Ltd.	58
ANHUI WITOP BIOTECH CO., LTD	58

View Lastest Price from ISOPROPENYLMAGNESIUM BROMIDE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2023-07-19	Bromo(isopropenyl)magnesium 13291-18-4	US $30.00 / KG	1KG	99%	20 Tons	Wuhan wingroup Pharmaceutical Co., Ltd
	2019-07-06	isopropenylmagnesium bromide 13291-18-4	US $1.00 / kg	1kg	99%	Customized	Career Henan Chemical Co

Bromo(isopropenyl)magnesium
13291-18-4
US $30.00 / KG
99%
Wuhan wingroup Pharmaceutical Co., Ltd

isopropenylmagnesium bromide
13291-18-4
US $1.00 / kg
99%
Career Henan Chemical Co

13291-18-4(ISOPROPENYLMAGNESIUM BROMIDE)Related Search:

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Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal Isopropenylmagnesium bromide 1M solution in tetrahydrofuran ISOPROPENYLMAGNESIUM BROMIDE isopropenylmagnesium bromide solution ISOPROPENYLMAGNESIUM BROMIDE SOLUTION, ~ 0.5 M IN THF ISOPROPENYLMAGNESIUM BROMIDE, 0.5M SOLUT ION IN TETRAHYDROFURAN ISOPROPENYLMAGNESIUM BROMIDE in ETHYL ETHER ISOPROPENYLMAGNESIUM BROMIDE in TETRAHYDROFURAN (1-Methylethenyl)magnesium bromide 1-Methylethenylmagnesium bromide 1-Methylvinylmagnesium bromide Bromoisopropenylmagnesium Isopropenylmagnesium bromide,0.5M solution inTHF Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal§3 Isopropenylmagnesium bromide solution 0.5 in THF Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal Iso Propenyl MagnesiuM BroMide0.5M In Thf IsopropenylMagnesiuM broMide soluti IsopropenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal IsopropenylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal Bromo(isopropenyl)magnesium Solution (0.5M in THF) Isopropenylmagnesium bromide(1M THF) Isopropenylmagnesium bromide, 0.5 M solution in THF, J&KSeal Isopropenylmagnesium bromide( 1.0 M solution in THF) ISOPROPENYLMAGNESIUM BROMIDE 0.5 M THF ISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURAN ISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURAN IsopropenyL Isopropenylmagnesium bromide (0.5M in THF) FandaSeal Magnesium, bromo(1-methylethenyl)- (9CI) bromo(1-methylethenyl)-Magnesium Iso Propenyl Magnesium Bromide .5M in THF Iso Propenyl Magnesium Bromide 1.M in 2-Methyl THF ISOPROPENYL MAGNESIUM BROMIDE 0.5M THF/1.0M &2M THF ISOPROPENYLMAGNESIUM BROMIDE 0.5M IN THF/1.0M IN 2Me THF Iso Propenyl Magnesium Bromide 1.5M in 2-Methyl THF bromo(prop-1-en-2-yl)magnesium 13291-18-4 13219-18-4 CH2CCH3MgBr H2CCCH3MgCl Alkenyl Grignard Reagents Organometallic Reagents Grignard Reagent Alkenyl Grignard Reagents Organometallic Reagents