tert-Butyl hydroperoxide
tert-Butyl hydroperoxide Chemical Properties,Uses,Production
Uses
Tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis. TBHP is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene. It is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates. Other uses are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations. It is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
Synthesis
Tert-Butyl hydroperoxide (TBHP) is produced by the liquid-phase reaction of isobutane and molecular oxygen or by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide. TBHP can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride. The manufacturing process of TBHP is in a closed system.
tert-Butyl hydroperoxide Preparation Products And Raw materials
Raw materials
Preparation Products
tert-Butyl hydroperoxide Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Sinomore New Material Company Limited | +86-15150124211 +86-15150124211 | sales@sinomorechem.com | China | 25 | 58 |
| SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8615195660023 | sales@senfeida.com | China | 23053 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33350 | 58 |
| Changshu New Venture Imp.&Exp. Co.,Ltd. | 0512-52678575 13776233393 | nvchem_deng@163.com | China | 212 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
| Qingdao Dexin Chemical Co., Ltd | +86-15553333686 +86-15553333686 | 15553333686@qq.com | China | 2865 | 58 |
| Xiamen Eagle Chemical Limited Corporation | +86-5925023701 +86-18900207489 | yiyunchem@163.com | China | 6044 | 58 |
| Beijing Ouhe Technology Co., Ltd | 010-82967028 13552068683 | 2355560935@qq.com | China | 12439 | 60 |
| Shanghai Macklin Biochemical Co.,Ltd. | 15221275939 15221275939 | shenlinxing@macklin.cn | China | 16168 | 55 |
| Shanghai Uchem Inc. | 15618758386 15618758386 | sales3@myuchem.com | China | 2013 | 55 |
View Lastest Price from tert-Butyl hydroperoxide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-07-09 | Tert-butyl Hydroperoxide
75-91-2
|
US $0.00-0.00 / kg | 500kg | 70% | 200tons | Sinomore New Material Company Limited |
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- Tert-butyl Hydroperoxide
75-91-2
- US $0.00-0.00 / kg
- 70%
- Sinomore New Material Company Limited