tert-Butyl hydroperoxide

tert-Butyl hydroperoxide C화학적 특성, 용도, 생산

용도

Tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis. TBHP is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene. It is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates. Other uses are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations. It is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.

Synthesis

Tert-Butyl hydroperoxide (TBHP) is produced by the liquid-phase reaction of isobutane and molecular oxygen or by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide. TBHP can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride. The manufacturing process of TBHP is in a closed system.

tert-Butyl hydroperoxide 준비 용품 및 원자재

원자재

준비 용품

tert-Butyl hydroperoxide 공급 업체

공급자	전화	이메일	국가	제품 수	이점
Sinomore New Material Company Limited	+86-15150124211 +86-15150124211	sales@sinomorechem.com	China	25	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	+86-0512-83500002 +8615195660023	sales@senfeida.com	China	23053	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+undefined18621343501	product@acmec-e.com	China	33350	58
Changshu New Venture Imp.&Exp. Co.,Ltd.	0512-52678575 13776233393	nvchem_deng@163.com	China	212	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	57511	58
Qingdao Dexin Chemical Co., Ltd	+86-15553333686 +86-15553333686	15553333686@qq.com	China	2862	58
Xiamen Eagle Chemical Limited Corporation	+86-5925023701 +86-18900207489	yiyunchem@163.com	China	6044	58
Beijing Ouhe Technology Co., Ltd	010-82967028 13552068683	2355560935@qq.com	China	12439	60
Shanghai Macklin Biochemical Co.,Ltd.	15221275939 15221275939	shenlinxing@macklin.cn	China	16168	55
Shanghai Uchem Inc.	15618758386 15618758386	sales3@myuchem.com	China	2012	55