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POLY(METHYL METHACRYLATE)

CAS No.
9010-88-2
Chemical Name:
POLY(METHYL METHACRYLATE)
Synonyms
METHYL METHACRYLATE POLYMER;POLY(METHYL METHACRYLATE), ISOTACTIC;LUCITE;Eudragit E 30D;Polyacrylic Resin III;METHYL METHACRYLATE RESIN;POLYBEAD(R) PMMA MICROSPHERES;POLY(METHYL METHACRYLATE) 600;POLYMETHYL METHACRYLATE BEADS;POLY(METHYL METHACRYLATE) 2'000
CBNumber:
CB5169353
Molecular Formula:
C10H16O4
Molecular Weight:
200.23
MDL Number:
MFCD00134349
MOL File:
9010-88-2.mol
Last updated:2023-04-23 13:52:06

POLY(METHYL METHACRYLATE) Properties

Melting point 150 °C
Density 1.2 g/mL at 25 °C(lit.)
refractive index n20/D 1.49
solubility alcohols and aliphatic hydrocarbons: insoluble
form powder
Indirect Additives used in Food Contact Substances POLY(ETHYL ACRYLATE-CO-METHYL METHACRYLATE)
FDA UNII ETHYL ACRYLATE AND METHYL METHACRYLATE COPOLYMER DISPERSION (2:1; 750000 MW 40% AQUEOUS) (0MKJ04EU89)
ETHYL ACRYLATE AND METHYL METHACRYLATE COPOLYMER DISPERSION (2:1; 600000 MW 30% AQUEOUS) (3EW60Z566Z)
ETHYL ACRYLATE AND METHYL METHACRYLATE COPOLYMER DISPERSION (2:1; 750000 MW 30% AQUEOUS) (8NT5GK8OOD)
ETHYL ACRYLATE AND METHYL METHACRYLATE COPOLYMER (2:1; 750000 MW) (P2OM2Q86BI)
ETHYL ACRYLATE AND METHYL METHACRYLATE COPOLYMER (2:1; 600000 MW) (XRK36F13ZZ)
EPA Substance Registry System Ethyl acrylate methyl methacrylate polymer (9010-88-2)

SAFETY

Risk and Safety Statements

Hazard Codes  Xn
Risk Statements  20/22
Safety Statements  36
WGK Germany  3
RTECS  TR0400000
Autoignition Temperature 580 °F

POLY(METHYL METHACRYLATE) price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 182249 Poly(methyl methacrylate-co-ethyl acrylate) ethyl acrylate <5wt. %, average M 9010-88-2 25g $88 2024-03-01 Buy
Sigma-Aldrich 182249 Poly(methyl methacrylate-co-ethyl acrylate) ethyl acrylate <5wt. %, average M 9010-88-2 1kg $202.2 2024-03-01 Buy
American Custom Chemicals Corporation CHM0977199 ETHYL ACRYLATE-METHYL METHACRYLATE LATEX 95.00% 9010-88-2 5MG $501.7 2021-12-16 Buy
Product number Packaging Price Buy
182249 25g $88 Buy
182249 1kg $202.2 Buy
CHM0977199 5MG $501.7 Buy

POLY(METHYL METHACRYLATE) Chemical Properties,Uses,Production

Uses

Poly(methyl methacrylate-co-ethyl acrylate) (PMMAEA) copolymers may be used to prepare single phase mixture with phenolic derivative. PMMAEA may be used to form latex interpenetrating polymer networks (LIPNs). Membranes of PMMAEA were reportedly used for separation of heavy metal ions from aqueous solutions.

Preparation

Acrylic acid is H2C=CH-COOH and methacrylic acid is H2C=C(CH3)COOH. These compounds and their methyl esters are both quite reactive and difficult to store and handle. The monomer used to form poly(methyl methacrylate), 2-hydroxy-2-methylpropanenitrile, is prepared by the following reaction:
preparation of 2-methylpropanenitrile
2-Hydroxy-2-methylpropanenitrile is then reacted with methanol (or other alcohol) to yield methacrylate ester. Free-radical polymerization is initiated by peroxide or azo catalysts and produce poly(methyl methacrylate) resins having the following formula:
structure of Poly(methyl methacrylate)
Key properties are good resistance to heat, light, and weathering. This polymer is unaffected by most detergents, cleaning agents, and solutions of inorganic acids, alkalies, and aliphatic hydrocarbons. Poly(methyl methacrylate) has light transmittance of 92% with a haze of 1–3% and its clarity is equal to glass.

Industrial uses

Poly(methyl methacrylate), the polymerizedmethyl ester of methacrylic acid, is thermoplastic.The method of polymerization may be variedto achieve specific physical properties, orthe monomer may be combined with other components.Sheet materials may be prepared bycasting the monomer in bulk. Suspension polymerizationof the monomeric ester may be usedto prepare molding powders.
Conventional poly(methyl methacrylate) isamorphous; however, reports have been publishedof methyl methacrylate polymers of regularconfiguration, which are susceptible tocrystallization. Both the amorphous and crystallineforms of such crystallization-susceptible polymers possess physical properties that aredifferent from those of the conventional polymer,and suggest new applications.

Industrial uses

Polymethyl methacrylate is a clear solid, hardbut easily scratched. Its dielectric properties areonly moderate, and its use is restricted to undemandingconditions at normal ambient temperatures,usually in a molded form, where appearanceis important.

POLY(METHYL METHACRYLATE) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 57)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Dorne Chemical Technology co. LTD
+86-86-13583358881 +8618560316533 Ethan@dornechem.com China 3095 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 22883 58
Hebei Weibang Biotechnology Co., Ltd
+8617732866630 bess@weibangbio.com China 18154 58
Shenzhen Monkono Technology Co.,Ltd
+86-17063441314 sansbiotech@outlook.com China 677 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52925 58
Hebei Fengmu Trading Co., Ltd.
+8613393234347 Lyla@fengmuchem.com China 2948 58

View Lastest Price from POLY(METHYL METHACRYLATE) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
POLY(METHYL METHACRYLATE)  pictures 2022-07-25 POLY(METHYL METHACRYLATE)
9010-88-2
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
POLYBEAD(R) PMMA MICROSPHERES POLYBEAD(R) POLY(METHYL METHACRYLATE) MICROSPHERES POLY(METHYL METHACRYLATE-CO-ETHYL ACRYLATE) POLY(METHYL METHACRYLATE) 10'000 Methylmethacrylate,ethylacrylatecopolymer Methylmethacrylate,polymerwithethylacrylate METHYL METHACRYLATE, POLYMERIZED METHYL METHACRYLATE RESIN METHACRYLIC ACID METHYL ESTER POLYMER LUCITE POLY(METHYL METHACRYLATE-CO-ETHYL ACRYLA TE), AVERAGE MW CA. 101,000(G Eudragit E 30D Poly(Methyl Methacrylate-co-ethyl acrylate) ethyl acrylate <5 wt. %, average Mn ~39,500 by GPC, average Mw ~101,000 by GPC, powder ETHYL ACRYLATE-METHYL METHACRYLATE LATEX POLY(METHYL METHACRYLATE) 100'000 POLY(METHYL METHACRYLATE) 150'000 POLY(METHYL METHACRYLATE) 2'000 POLY(METHYL METHACRYLATE) 20'000 POLY(METHYL METHACRYLATE) 2'480'000 POLY(METHYL METHACRYLATE) 300'000 POLY(METHYL METHACRYLATE) 5'000 POLY(METHYL METHACRYLATE) 50'000 POLY(METHYL METHACRYLATE) 500'000 POLY(METHYL METHACRYLATE) 600 POLY(METHYL METHACRYLATE) 75'000 POLY(METHYL METHACRYLATE) 8'000 POLY(METHYL METHACRYLATE) 800'000 POLYMETHYL METHACRYLATE BEADS 2-Propenoicacid,2-methyl-,methylester,Copolymerwithethyl2-propenoate 2-propenoicacid,2-methyl-,methylester,polymerwithethyl2-propenoate Ethylacrylate,copolymerwithmethylmethacrylate Ethylacrylate,methylmethacrylatecopolymer ethyl prop-2-enoate,methyl 2-methylprop-2-enoate Polyacrylic Resin III POLY(METHYL METHACRYLATE), ISOTACTIC METHYL METHACRYLATE POLYMER 9010-88-2 90011-14-7 CH2CCH3CO2CH3XCH2CHCO2C2H5Y Analytical Chromatography Product Catalog Alphabetic Analytical Standards Organic Soluble Polymers Polymer Standards POLB - POLY Chromatography Methacrylate PolymersSelf Assembly&Contact Printing PMMA-Based Resins Acrylics Hydrophobic Polymers Stamps for Nanoprint Lithography&Microcontact Printing Contact Printing Hydrophobic Polymers Materials Science Methacrylate Polymers Micro/NanoElectronics Microcontact Printing PMMA-Based Resins