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Allyl phenyl sulfone

CAS No.
16212-05-8
Chemical Name:
Allyl phenyl sulfone
Synonyms
Allyl Phenyl sulone;ALLYLSULFONYLBENZENE;ALLYL PHENYL SULFONE;sulfone, allyl phenyl;Phenyl allyl sulfone.;ALLYL PHENYL SULPHONE;(allylsulphonyl)benzene;Allyl phenyl sulfone,98%;Allyl Phenyl Sulfone >Phenyl 2-propenyl sulfone
CBNumber:
CB5189995
Molecular Formula:
C9H10O2S
Molecular Weight:
182.24
MDL Number:
MFCD00014739
MOL File:
16212-05-8.mol
Last updated:2024-12-19 13:23:19

Allyl phenyl sulfone Properties

Boiling point 110-113 °C/0.5 mmHg (lit.)
Density 1.189 g/mL at 25 °C (lit.)
refractive index n20/D 1.548(lit.)
Flash point >230 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Orange to Green
Water Solubility insol water; sol most organic solvents.
Sensitive Light Sensitive
BRN 1863561
InChIKey KYPIULIVYSQNNT-UHFFFAOYSA-N
CAS DataBase Reference 16212-05-8(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 37KT5U3YH4
EPA Substance Registry System Benzene, (2-propenylsulfonyl)- (16212-05-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
RTECS  WR2400000
8-10
TSCA  T
HazardClass  IRRITANT
HS Code  2930909899
Toxicity mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02689,
NFPA 704
1
2 0

Allyl phenyl sulfone price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 06061 Allyl phenyl sulfone purum, ≥98.0% (GC) 16212-05-8 50ml $439 2024-03-01 Buy
Sigma-Aldrich 06061 Allyl phenyl sulfone purum, ≥98.0% (GC) 16212-05-8 10ml $125 2023-06-20 Buy
TCI Chemical A1444 Allyl Phenyl Sulfone >95.0%(GC) 16212-05-8 5g $64 2024-03-01 Buy
Alfa Aesar A10401 Allyl phenyl sulfone, 98% 16212-05-8 5g $49.65 2024-03-01 Buy
Alfa Aesar A10401 Allyl phenyl sulfone, 98% 16212-05-8 25g $156.65 2024-03-01 Buy
Product number Packaging Price Buy
06061 50ml $439 Buy
06061 10ml $125 Buy
A1444 5g $64 Buy
A10401 5g $49.65 Buy
A10401 25g $156.65 Buy

Allyl phenyl sulfone Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS TO FAINTLY YELLOW LIQUID

Uses

Possible usages of allyl phenyl sulfone:

  • It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
  • It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
  • It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Reactivity Profile

Allyl phenyl sulfone could be used as metalated derivatives serve as ambident nucleophiles; reacts as a 1,1-allylic dianion or 1,1-allylic dipole equivalent[1].

Synthesis

The Preparative Method of Allyl phenyl sulfone: from Allyl Bromide and benzenesulfinate in ethanol according to the original procedure is most straightforward and avoids the use of strong-smelling thiols.

References

1. (a) Magnus, P. D. T 1977, 33, 2019. (b) Block, E. Reactions of Organosulfur Compounds; Academic Press: New York, 1978. (c) Biellmann, J.-F.; Ducep, J.-B. OR 1982, 27, 1.
2. Otto, R. LA 1894, 283, 18; Cope, A. C.; Morrison, D. E.; Field, L. JACS 1950, 72, 59. Vennstra, G. E.; Zwaneburg, B. S 1975, 519.

5535-48-8
106-95-6
16212-05-8
Synthesis of Allyl phenyl sulfone from Phenyl vinyl sulfone and Allyl bromide

Allyl phenyl sulfone Suppliers

Global( 151)Suppliers
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View Lastest Price from Allyl phenyl sulfone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Allyl phenyl sulfone pictures 2019-12-26 Allyl phenyl sulfone
16212-05-8
US $6.60 / KG 500g 98% 1kg, 50kg, 100kg Career Henan Chemical Co
ALLYL PHENYL SULFONE ALLYL PHENYL SULPHONE ALLYLSULFONYLBENZENE (allylsulphonyl)benzene Allyl Phenyl sulone sulfone, allyl phenyl 3-(Phenylsulfonyl)-1-propene Phenyl (2-propenyl) sulfone Phenyl 2-propenyl sulfone Allyl phenyl sulfone,98% Phenyl allyl sulfone. (2-propenylsulfonyl)-benzen Benzene, (2-propenylsulfonyl)- Prop-2-enylsulfonylbenzene Allyl Phenyl Sulfone > Benzene, (2-propen-1-ylsulfonyl)- (Prop-2-ene-1-sulfonyl)-benzene 16212-05-8 16212-05-08 C9H10O2S C6H5SO2CH2CHCH2 KETONE Building Blocks Organic Building Blocks Sulfones Sulfur Compounds Sulfur Compounds (for Synthesis) Building Blocks Chemical Synthesis Organic Building Blocks Sulfur Compounds Phenyls & Phenyl-Het Sulfur Compounds (for Synthesis) Synthetic Organic Chemistry Phenyls & Phenyl-Het Organic Building Blocks Sulfones Sulfur Compounds