Allyl phenyl sulfone
- CAS No.
- 16212-05-8
- Chemical Name:
- Allyl phenyl sulfone
- Synonyms
- Allyl Phenyl sulone;ALLYLSULFONYLBENZENE;ALLYL PHENYL SULFONE;sulfone, allyl phenyl;Phenyl allyl sulfone.;ALLYL PHENYL SULPHONE;(allylsulphonyl)benzene;Allyl phenyl sulfone,98%;Allyl Phenyl Sulfone >Phenyl 2-propenyl sulfone
- CBNumber:
- CB5189995
- Molecular Formula:
- C9H10O2S
- Molecular Weight:
- 182.24
- MDL Number:
- MFCD00014739
- MOL File:
- 16212-05-8.mol
Boiling point | 110-113 °C/0.5 mmHg (lit.) |
---|---|
Density | 1.189 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | >230 °F |
storage temp. | 2-8°C |
form | clear liquid |
color | Colorless to Orange to Green |
Water Solubility | insol water; sol most organic solvents. |
Sensitive | Light Sensitive |
BRN | 1863561 |
InChIKey | KYPIULIVYSQNNT-UHFFFAOYSA-N |
CAS DataBase Reference | 16212-05-8(CAS DataBase Reference) |
EWG's Food Scores | 1 |
FDA UNII | 37KT5U3YH4 |
EPA Substance Registry System | Benzene, (2-propenylsulfonyl)- (16212-05-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | WR2400000 | |||||||||
F | 8-10 | |||||||||
TSCA | T | |||||||||
HazardClass | IRRITANT | |||||||||
HS Code | 2930909899 | |||||||||
Toxicity | mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02689, | |||||||||
NFPA 704 |
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Allyl phenyl sulfone price More Price(25)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 06061 | Allyl phenyl sulfone purum, ≥98.0% (GC) | 16212-05-8 | 50ml | $439 | 2024-03-01 | Buy |
Sigma-Aldrich | 06061 | Allyl phenyl sulfone purum, ≥98.0% (GC) | 16212-05-8 | 10ml | $125 | 2023-06-20 | Buy |
TCI Chemical | A1444 | Allyl Phenyl Sulfone >95.0%(GC) | 16212-05-8 | 5g | $64 | 2024-03-01 | Buy |
Alfa Aesar | A10401 | Allyl phenyl sulfone, 98% | 16212-05-8 | 5g | $49.65 | 2024-03-01 | Buy |
Alfa Aesar | A10401 | Allyl phenyl sulfone, 98% | 16212-05-8 | 25g | $156.65 | 2024-03-01 | Buy |
Allyl phenyl sulfone Chemical Properties,Uses,Production
Chemical Properties
CLEAR COLOURLESS TO FAINTLY YELLOW LIQUID
Uses
Possible usages of allyl phenyl sulfone:
- It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
- It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
- It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.
Reactivity Profile
Allyl phenyl sulfone could be used as metalated derivatives serve as ambident nucleophiles; reacts as a 1,1-allylic dianion or 1,1-allylic dipole equivalent[1].
Synthesis
The Preparative Method of Allyl phenyl sulfone: from Allyl Bromide and benzenesulfinate in ethanol according to the original procedure is most straightforward and avoids the use of strong-smelling thiols.
References
1. (a) Magnus, P. D. T 1977, 33, 2019. (b) Block, E. Reactions of Organosulfur Compounds; Academic Press: New York, 1978. (c) Biellmann, J.-F.; Ducep, J.-B. OR 1982, 27, 1.
2. Otto, R. LA 1894, 283, 18; Cope, A. C.; Morrison, D. E.; Field, L. JACS 1950, 72, 59. Vennstra, G. E.; Zwaneburg, B. S 1975, 519.
Allyl phenyl sulfone Preparation Products And Raw materials
Allyl phenyl sulfone Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
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career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29810 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 11885 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
Alfa Chemistry | info@alfa-chemistry.com | United States | 2344 | 58 | |
Aston Chemical | 13000000000 | sales@astonchem.com | United States | 1634 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
Nextpeptide Inc | +86-0571-81612335 +8613336028439 | sales@nextpeptide.com | China | 19908 | 58 |
Aromsyn Co., Ltd. | +86-0571-85585865 +8613336024896 | CB@aromsyn.com | China | 19183 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18151 | 58 |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49978 | 58 |
View Lastest Price from Allyl phenyl sulfone manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2019-12-26 | Allyl phenyl sulfone
16212-05-8
|
US $6.60 / KG | 500g | 98% | 1kg, 50kg, 100kg | Career Henan Chemical Co |
- Allyl phenyl sulfone
16212-05-8
- US $6.60 / KG
- 98%
- Career Henan Chemical Co