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SELENIUM BROMIDE

CAS No.
7789-52-8
Chemical Name:
SELENIUM BROMIDE
Synonyms
12049-00-2;SELENIUM BROMIDE;Einecs 232-173-5;selenium(I) bromide;Diselenium dibromide;SELENIUM MONOBROMIDE;SELENIUM BROMIDE 99%;seleniumbromide(se2br2)
CBNumber:
CB5319710
Molecular Formula:
Br2Se2
Molecular Weight:
317.75
MDL Number:
MFCD00016326
MOL File:
7789-52-8.mol
Last updated:2024-07-12 14:40:58

SELENIUM BROMIDE Properties

Boiling point 227, decomposes [KIR82]
Density d415 3.604
solubility reacts with H2O; soluble in CS2, chloroform
form red liquid
color red
Water Solubility decomposes in H2O; soluble chloroform, ethyl bromide, carbon disulfide [MER06]
FDA UNII 678YXJ4HM6
EPA Substance Registry System Selenium bromide (Se2Br2) (7789-52-8)

SAFETY

Risk and Safety Statements

RIDADR  3289
HazardClass  6.1(a)
PackingGroup  II

SELENIUM BROMIDE Chemical Properties,Uses,Production

Chemical Properties

Dark red, almost black, oily liquid with an unpleasant odour; hygroscopic; rapidly liberates Br2 in air, simultaneously separating Se. Partially decomposed on heating; first, some Br2 escapes, then some SeBr4 sublimes, and between 225 and 230°C, a part of the Se2Br2 boils without decomposition, leaving a residue of Se. In water, Se2Br2 sinks to the bottom in oily drops and gradually decomposes into Se, SeO2 and HBr, soluble in CS2 and CHCl3.

Production Methods

A round-bottom flask, equipped with a separatory funnel and gas outlet tube connected to a P2O5 drying tube, is filled with a suspension of 20 g of pure powdered Se in 50 ml of dry CS2; 20 g of pure Br2 is then slowly added from the separatory funnel. If the flask is occasionally shaken, the reaction is soon complete. A reddish-brown solution is formed, from which the CS2 is evaporated in a vacuum as rapidly as possible. The product is deep-red, pure Se2Br2.

Synthesis

A round-bottom flask, equipped with a separatory funnel and gas outlet tube connected to a P2O5 drying tube, is filled with a suspension of 20 g. of pure powdered Se in 50 ml. of dry CS2; 20 g. of pure Br2 is then slowly added from the separatory funnel. If the flask is occasionally shaken, the reaction is soon complete. A reddish-brown solution is formed, from which the CS2 is evaporated in vacuum as rapidly as possible. The product is deep-red, pure Se2Br2 .

SELENIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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SELENIUM BROMIDE SELENIUM MONOBROMIDE selenium(I) bromide Diselenium dibromide Einecs 232-173-5 seleniumbromide(se2br2) SELENIUM BROMIDE 99% 12049-00-2 7789-52-8 Br2Se2