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N,N',N''-METHYLIDYNETRISFORMAMIDE

N,N',N''-METHYLIDYNETRISFORMAMIDE Structure
N,N',N''-METHYLIDYNETRISFORMAMIDE structure
CAS No.
4774-33-8
Chemical Name:
N,N',N''-METHYLIDYNETRISFORMAMIDE
Synonyms
TRIS-FORMAMINOMETHANE;N-(diformamidomethyl)formamide;N-(diformamidomethyl)methanamide;N,N',N''-METHYLIDYNETRISFORMAMIDE;N,N',N''-Methanetriyltriformamide;N,N',N''-METHYLIDYNETRISFORMAMIDE;Formamide, N,N',N''-methylidynetris-;N,N',N''-Methylidynetrisformamide 97%;Tris-formaminomethane/N,N',N''-Methylidynetrisformamide
CBNumber:
CB5417058
Molecular Formula:
C4H7N3O3
Molecular Weight:
145.12
MDL Number:
MFCD00003278
MOL File:
4774-33-8.mol
MSDS File:
SDS
Last updated:2025-02-07 13:23:53
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N,N',N''-METHYLIDYNETRISFORMAMIDE Properties

Melting point 170-172 °C (dec.)(lit.)
Boiling point 720.5±55.0 °C(Predicted)
Density 1.280±0.06 g/cm3(Predicted)
solubility water: soluble25mg/mL, clear, colorless
pka 12.69±0.23(Predicted)
form solid
Water Solubility water: soluble 25mg/mL, clear, colorless
FDA UNII 2C7AW8G2ZG
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3

N,N',N''-METHYLIDYNETRISFORMAMIDE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 159735 N,N′,N′′-Methylidynetrisformamide 97% 4774-33-8 5g $100 2024-03-01 Buy
American Custom Chemicals Corporation CHM0156734 N,N',N''-METHYLIDYNETRISFORMAMIDE 95.00% 4774-33-8 5G $857.66 2021-12-16 Buy
AHH MT-20196 N,N',N''-Methylidynetrisformamide 98% 4774-33-8 1000g $538 2021-12-16 Buy
Product number Packaging Price Buy
159735 5g $100 Buy
CHM0156734 5G $857.66 Buy
MT-20196 1000g $538 Buy

N,N',N''-METHYLIDYNETRISFORMAMIDE Chemical Properties,Uses,Production

Uses

N,N′N′′-methylidynetrisformamide (TRIFO) is a source for formamide; used for N-formylformamidine (H2N-CH=N-CHO); for the N-formylformimidoyl group (H-C=NHCHO) as a building block in heterocyclic synthesis).

Preparation

Triethyl Orthoformate reacts with formamide under catalysis of mineral acids to give TRIFO (eq 1). The reaction of excess formamide with inorganic and organic acyl chlorides such as PCl3, POCl3, SOCl2, acetyl chloride, benzoyl chloride, and ethyl chloroformate proceeds via iminium salts to afford TRIFO. Analogously, alkylating reagents such as dialkyl sulfates, alkyl sulfonates or triethyloxonium tetrafluoroborate transform formamide to TRIFO. Alkoxymethyleneiminium salts and formamidinium salts are intermediates in these reactions. Pure salts of this type are also converted to the reagent by formamide. Reaction of Dimethyl Sulfate with formamide is the easiest way to prepare TRIFO.
N,N',N''-METHYLIDYNETRISFORMAMIDE synthesis

General Description

N,N′,N′′-Methylidynetrisformamide is also referred as tris(formamido)methane.

Solubility in organics

N,N′N′′-methylidynetrisformamide is soluble in formamide; soluble in aprotic dipolar solvents such as DMF or DMA on heating.

storage

N,N′N′′-methylidynetrisformamide is stored at rt in closed bottles. Use in a fume hood.

N,N',N''-METHYLIDYNETRISFORMAMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

2-Amino-1,3,5-triazine

N,N',N''-METHYLIDYNETRISFORMAMIDE Suppliers

Global( 20)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd 		+86-29-81139210 +86-18192627656 1059@dideu.com China 3003 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29793 60
Amadis Chemical Company Limited 		571-89925085 sales@amadischem.com China 131957 58
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44689 61
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 sales@capotchem.com China 18207 66
Beijing Ouhe Technology Co., Ltd 010-82967028 13552068683 2355560935@qq.com China 12390 60
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42958 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Henan Kehong Biological Technology Co. LTD 0371-55969461； 0371-86658258 19139748274 info@kehobio.com China 2489 58
Bide Pharmatech Ltd. 400-1647117 13681763483 product02@bidepharm.com China 62075 58
Supplier Advantage
Shaanxi Dideu Medichem Co. Ltd 		58
Capot Chemical Co.,Ltd. 		60
Amadis Chemical Company Limited 		58
Energy Chemical 61
Capot Chemical Co., Ltd 66
Beijing Ouhe Technology Co., Ltd 60
Shanghai Hanhong Scientific Co.,Ltd. 64
Sigma-Aldrich 80
Henan Kehong Biological Technology Co. LTD 58
Bide Pharmatech Ltd. 58

View Lastest Price from N,N',N''-METHYLIDYNETRISFORMAMIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N,N',N''-METHYLIDYNETRISFORMAMIDE pictures 2024-07-16 N,N',N''-METHYLIDYNETRISFORMAMIDE
4774-33-8
 US $1.00-22.00 / KG 1KG 99% 100000KG Shaanxi Dideu Medichem Co. Ltd

N,N',N''-METHYLIDYNETRISFORMAMIDE Spectrum

N,N',N''-METHYLIDYNETRISFORMAMIDE(4774-33-8)MSN,N',N''-METHYLIDYNETRISFORMAMIDE(4774-33-8)1HNMRN,N',N''-METHYLIDYNETRISFORMAMIDE(4774-33-8)13CNMRN,N',N''-METHYLIDYNETRISFORMAMIDE(4774-33-8)IR1N,N',N''-METHYLIDYNETRISFORMAMIDE(4774-33-8)IR2N,N',N''-METHYLIDYNETRISFORMAMIDE(4774-33-8)Raman

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