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Dichloro(1,5-cyclooctadiene)palladium(II)

CAS No.
12107-56-1
Chemical Name:
Dichloro(1,5-cyclooctadiene)palladium(II)
Synonyms
PdCl2(cod);1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE;adium(Ⅱ);NSC 169973;ooctadiene)paL;Dichloro(1,5-cyclooctadience;DICHLORO(CYCLOOCTA-1,5-DIENE)PAL;Dichloro-(1,5-cyclooctadiene)-palladium;Dichloro(1,5-cyclooctadiene)palladium(Ⅱ);(1,5-CYCLOOCTADIENE)PALLADIUM(II)CHLORIDE
CBNumber:
CB5488849
Molecular Formula:
C8H12Cl2Pd
Molecular Weight:
285.51
MDL Number:
MFCD00012412
MOL File:
12107-56-1.mol
MSDS File:
SDS
Last updated:2024-12-18 14:15:30

Dichloro(1,5-cyclooctadiene)palladium(II) Properties

Melting point 210 °C (dec.) (lit.)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in dichloromethane
form crystal
color yellow
Water Solubility insoluble
Sensitive Hygroscopic
InChI InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChIKey NEKYMUKEOUDFPP-XRGHXPOKSA-L
SMILES C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6|
CAS DataBase Reference 12107-56-1(CAS DataBase Reference)
FDA UNII SK5GRF586M
EPA Substance Registry System Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
TSCA  Yes
HS Code  28439000
NFPA 704
1
0 1

Dichloro(1,5-cyclooctadiene)palladium(II) price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 275891 Dichloro(1,5-cyclooctadiene)palladium(II) 99% 12107-56-1 2g $251 2024-03-01 Buy
TCI Chemical D2604 Dichloro(1,5-cyclooctadiene)palladium(II) >98.0%(T) 12107-56-1 1g $336 2024-03-01 Buy
TCI Chemical D2604 Dichloro(1,5-cyclooctadiene)palladium(II) >98.0%(T) 12107-56-1 5g $1226 2024-03-01 Buy
Alfa Aesar 010493 Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7% 12107-56-1 1g $133 2023-06-20 Buy
Alfa Aesar 010493 Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7% 12107-56-1 5g $628 2023-06-20 Buy
Product number Packaging Price Buy
275891 2g $251 Buy
D2604 1g $336 Buy
D2604 5g $1226 Buy
010493 1g $133 Buy
010493 5g $628 Buy

Dichloro(1,5-cyclooctadiene)palladium(II) Chemical Properties,Uses,Production

Chemical Properties

yellow

Uses

Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.

Uses

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

1042309-89-6
12107-56-1
Synthesis of Dichloro(1,5-cyclooctadiene)palladium(II) from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-

Dichloro(1,5-cyclooctadiene)palladium(II) Preparation Products And Raw materials

Global( 257)Suppliers
Supplier Tel Email Country ProdList Advantage
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580 cooperation@kean-chem.com China 40066 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18751 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32957 60
Zjartschem
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career henan chemical co
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Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Accela ChemBio Inc.
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Yunbio Tech Co.,Ltd.
+86-010-60605551 +86-18046518538 yunbiochem@126.com China 321 58
Wuhan Pengo Technology.,Ltd.
+86-27-81330736 +86-13628634921 sunny.w@boronicgroup.com CHINA 171 58

View Lastest Price from Dichloro(1,5-cyclooctadiene)palladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dichloro(1,5-cyclooctadiene)palladium(II) pictures 2022-09-24 Dichloro(1,5-cyclooctadiene)palladium(II)
12107-56-1
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
Dichloro(1,5-cyclooctadiene)palladium(II) pictures 2019-07-06 Dichloro(1,5-cyclooctadiene)palladium(II)
12107-56-1
US $1.00 / KG 1KG 99% Customized Career Henan Chemical Co
dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladiu (1,5-CYCLOOCTADIENE)PALLADIUM(II)CHLORIDE DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADATE (II) DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADIUM(II) DICHLORO(ETA-CYCLOOCTA-1,5-DIENE)PALLADIUM (II) DICHLORO(1,5-CYCLOOCTYLDIENE)PALLADIUM(II) DICHLORO(1,5-CYCLOOCTADIENE)PALLADIUM(II) (CIS, CIS-1,5-CYCLOOCTADIENE)PALLADIUM(II) CHLORIDE dichloro[(1,2,5,6-eta)-cycloocta-1,5-diene]palladium Dichloro(1,5-cyclooctadiene)palladium(II) (cis,cis-1,5-Cyclooctadiene)palladium(II) chloride Dichloro(cycloocta-1,5-dienyl)palladium(II) Dichloro(1,5-cyclooctadiene)palladium(II),99% Dichloro-(1,5-cyclooctadiene)-palladium DICHLORO(1,5-CYCLOOCTADIENE)PALLADIUM(LL) Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7% Dichloro(cycloocta-1,5-diene)palladium(II), Pd 37.3% (cis,cis-1,5-Cyclooctadiene)palladium(II) chloride,99% Dichloro(1,5-cyclooctadiene)palladium(Ⅱ) dichloro[(1,2,5,6-η)-cycloocta-1,5-diene]palladium Dichloro(1,5-cycloocatadiene)palladium(II) Dichloro(1,5-cyclooctadiene)palladiuM(II),98% (COD)PdCl2 Palladium,dichloro[(1,2,5,6-h)-1,5-cyclooctadiene]- Dichloro(1,5-cyclooctadience) palladium(II) NSC 169973 DICHLORO(CYCLOOCTA-1,5-DIENE)PAL adium(Ⅱ) ooctadiene)paL Dichloro(1,5-cyclooctadiene)palladium(II)> Palladium, dichloro[(1,2,5,6-η)-1,5-cyclooctadiene]- Dichloro(1,5-cyclooctadiene)palladium(II) ISO 9001:2015 REACH Dichloro[(1,2,5,6-η)-1,5-cyclooctadiene]-palladium 1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE PdCl2(cod) Dichloro(1,2,5,6-eta)-1,5-cyclooctadienepalladium Dichloro(1,5-cyclooctadience 12107-56-1 1207-56-1 PdCl2C8H12 PdCl215C8H12 C8H12Cl2Pd PdCODCl2 Catalysis and Inorganic Chemistry Homogeneous Pd Catalysts Metal Complexes Homogeneous Catalysts Classes of Metal Compounds Transition Metal Compounds Pd (Palladium) Compounds Catalysts for Organic Synthesis chemical reaction,pharm,electronic,materials organometallic complexes Catalysis and Inorganic Chemistry Homogeneous Pd Catalysts Palladium Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Metal Complexes