Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- CAS No.
- 887919-35-9
- Chemical Name:
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- Synonyms
- Pd132;Pd(amphos)Cl2;Pd(Amphos)2Cl2;PdCl2(Amphos)2;(A-taPhos)2PdCl2;PdAMPHOS;BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II);pall;Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…;Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II)
- CBNumber:
- CB8972714
- Molecular Formula:
- C32H58Cl2N2P2Pd
- Molecular Weight:
- 710.1
- MDL Number:
- MFCD09265123
- MOL File:
- 887919-35-9.mol
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
---|---|
form | Powder |
color | yellow |
Water Solubility | Insoluble in water. |
InChI | InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H; |
InChIKey | AWOFSUFKCXRJMV-UHFFFAOYSA-N |
SMILES | P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C |
UNSPSC Code | 12352101 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | No | |||||||||
HS Code | 28439000 | |||||||||
NFPA 704 |
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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) price More Price(43)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 678740 | Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 95% | 887919-35-9 | 1g | $163 | 2024-03-01 | Buy |
Sigma-Aldrich | 678740 | Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 95% | 887919-35-9 | 5g | $776 | 2024-03-01 | Buy |
Alfa Aesar | 045511 | Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II), Pd 15% | 887919-35-9 | 1g | $236.65 | 2024-03-01 | Buy |
Strem Chemicals | 46-0825 | Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos | 887919-35-9 | 250mg | $55 | 2024-03-01 | Buy |
Strem Chemicals | 46-0825 | Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos | 887919-35-9 | 1g | $162 | 2024-03-01 | Buy |
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Chemical Properties,Uses,Production
Reaction
- Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
- Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate.

Chemical Properties
Yellow powder
Uses
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
Uses
Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
Synthesis
To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.



Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 408 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20235 | 58 |
SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40066 | 58 |
Hangzhou ICH Biofarm Co., Ltd | +86-0571-28186870; +undefined8613073685410 | sales@ichemie.com | China | 1015 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-+86-371-66670886 | info@dakenam.com | China | 19805 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21628 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
AB PharmaTech,LLC | 323-480-4688 | sales@acrospharmatech.com | United States | 989 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29858 | 58 |
View Lastest Price from Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2025-03-21 | Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II)
887919-35-9
|
US $0.00 / KG | 1KG | 98% | 100KG /month | Shanghai Daken Advanced Materials Co.,Ltd | |
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2024-12-28 | Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
887919-35-9
|
US $0.00-0.00 / kg | 0.10000000149011612kg | 99.0%min | 200kg | Hangzhou ICH Biofarm Co., Ltd | |
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2024-01-22 | Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II)
887919-35-9
|
US $8.00-0.80 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
-
- Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II)
887919-35-9
- US $0.00 / KG
- 98%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
887919-35-9
- US $0.00-0.00 / kg
- 99.0%min
- Hangzhou ICH Biofarm Co., Ltd
-
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II)
887919-35-9
- US $8.00-0.80 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
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