ALUMINUM TERT-BUTOXIDE
- CAS No.
- 556-91-2
- Chemical Name:
- ALUMINUM TERT-BUTOXIDE
- Synonyms
- ALUMINUM T-BUTOXIDE;uminum tert-butoxide;Alumiuniumt-butoxide,;Aluminium t-Butoxide;ALUMINUM TERT-BUTOXIDE;ALUMINUM TERT-BUTYLATE;tri-tert-butoxyaluminum;ALUMINUM(III)T-BUTOXIDE;ALUMINUM TRI-T-BUTOXIDE;ALUMINIUM TERT-BUTOXIDE
- CBNumber:
- CB5682825
- Molecular Formula:
- C12H27AlO3
- Molecular Weight:
- 246.32
- MDL Number:
- MFCD00008801
- MOL File:
- 556-91-2.mol
Melting point | 241°C |
---|---|
Boiling point | 156°C 2mm |
Density | 1,0251 g/cm3 |
Flash point | >65°C |
solubility | Very soluble in organic solvents like alcohols, benzene, toluene and xylene. |
form | Powder |
color | White to Gray |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
Sensitive | Moisture Sensitive |
Merck | 14,333 |
BRN | 4148229 |
Stability | Stable, but air and moisture sensitive. Incompatible with acids, strong oxidizing agents. Highly flammable. |
CAS DataBase Reference | 556-91-2(CAS DataBase Reference) |
FDA UNII | 6D623JMP3R |
EPA Substance Registry System | 2-Propanol, 2-methyl-, aluminum salt (556-91-2) |
UNSPSC Code | 12352103 |
NACRES | NA.23 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS05 |
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Signal word | Danger | |||||||||
Hazard statements | H228-H314 | |||||||||
Precautionary statements | P210-P240-P260-P280-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | F,C | |||||||||
Risk Statements | 11-34 | |||||||||
Safety Statements | 8-16-26-36/37/39-45 | |||||||||
RIDADR | UN 2925 4.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 8-21 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 4.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29051990 | |||||||||
NFPA 704 |
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ALUMINUM TERT-BUTOXIDE price More Price(22)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 235849 | Aluminum tert-butoxide technical grade | 556-91-2 | 10g | $43.62 | 2024-03-01 | Buy |
Sigma-Aldrich | 235849 | Aluminum tert-butoxide technical grade | 556-91-2 | 50g | $303 | 2024-03-01 | Buy |
TCI Chemical | A0804 | Aluminum tert-Butoxide >98.0%(T) | 556-91-2 | 5g | $49 | 2024-03-01 | Buy |
Alfa Aesar | 089891 | Aluminum tert-butoxide, 97% | 556-91-2 | 5g | $39.65 | 2024-03-01 | Buy |
Alfa Aesar | 089891 | Aluminum tert-butoxide, 97% | 556-91-2 | 25g | $179 | 2024-03-01 | Buy |
ALUMINUM TERT-BUTOXIDE Chemical Properties,Uses,Production
Chemical Properties
slightly yellow crystalline powder
Uses
Reagent for oxidation of alcohols to ketones; in dealcoholation of orthoesters.
Uses
Aluminum tert-butoxide is utilized as a reagent in the Oppenauer oxidation of alcohols to ketones. It is also used in Meerwein-Ponndorf-Verley reduction of ketones. It is actively involved in the preparation of 1,1,2-triethoxyethene by reacting with 1,1,2,2-tetraethoxyethane followed by the elimination of alcohol.
reaction suitability
core: aluminum
Purification Methods
Crystallise it from *C6H6 and it sublimes it at 180o. [McElvain & Davie J Am Chem Soc 73 1400 1951, Beilstein 1 IV 1612.]
ALUMINUM TERT-BUTOXIDE Preparation Products And Raw materials
ALUMINUM TERT-BUTOXIDE Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21631 | 55 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49732 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29808 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 | mcbio_sales@163.com | China | 2251 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 7722 | 58 |
Alfa Chemistry | info@alfa-chemistry.com | United States | 2344 | 58 | |
Aston Chemical | 13000000000 | sales@astonchem.com | United States | 1634 | 58 |
View Lastest Price from ALUMINUM TERT-BUTOXIDE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2020-01-13 | ALUMINUM TERT-BUTOXIDE)
556-91-2
|
US $1.00 / KG | 1KG | 98%-99.9% | 200kg | Career Henan Chemical Co |
-
- ALUMINUM TERT-BUTOXIDE)
556-91-2
- US $1.00 / KG
- 98%-99.9%
- Career Henan Chemical Co