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VANADIUM PENTAFLUORIDE

CAS No.
7783-72-4
Chemical Name:
VANADIUM PENTAFLUORIDE
Synonyms
Vanadium(V) fluoride;VANADIUM PENTAFLUORIDE;Five vanadium fluoride;Vanadium(V)pentafluoride
CBNumber:
CB6144733
Molecular Formula:
F5V
Molecular Weight:
145.93
MDL Number:
MFCD00137321
MOL File:
7783-72-4.mol
Last updated:2024-08-28 13:53:25

VANADIUM PENTAFLUORIDE Properties

Melting point 19.5°
Boiling point bp 47.9°
Density d419.5 2.502
solubility reacts with H2O
form colorless liquid
color colorless
Water Solubility hydrolyzed in H2O, dilute alkali; soluble anhydrous HF [MER06]
crystal system Nogata
Space group Pmcn
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.541.6720.7539090900.6799
EWG's Food Scores 1
FDA UNII 1GNN7H50UE

SAFETY

Risk and Safety Statements

RIDADR  2922
HazardClass  8
PackingGroup  I
HS Code  2826199090

VANADIUM PENTAFLUORIDE Chemical Properties,Uses,Production

Chemical Properties

liquid; etches glass slowly at room temp; appreciable vapor pressure at room temp; enthalpy of vaporization 44.52 kJ/mol; enthalpy of fusion 49.96 kJ/mol [CRC10] [MER06]

Synthesis

A small nickel or platinum boat containing VF 4 is placed in a nickel tube and gradually heated to 650°C in a stream of dry N2 . The exit gases are collected in a large-diameter quartz trap maintained at —78°C. The trap is attached to a drying tube with anhydrous KF to exclude atmospheric moisture. The heating process must be effected slowly, since otherwise the unreacted VF4 is blown out of the reaction tube. The product is allowed to cool in a nitrogen stream and the VF5 is discharged directly from the gas trap into a storage container. A greenish-yellowish residue (VF4) remains in the boat. The yield is almost quantitative.

storage

The product is stored in sealed iron, nickel, copper or platinum containers.

VANADIUM PENTAFLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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VANADIUM PENTAFLUORIDE Vanadium(V) fluoride Vanadium(V)pentafluoride Five vanadium fluoride 7783-72-4 F5V