ChemicalBook >> CAS DataBase List >>(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

CAS No.
148461-14-7
Chemical Name:
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
Synonyms
(S)-iPr-Phox;Diphenylphosphinophenylmethylethyldihydrooxazole;(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-;)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo;(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole;(-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
CBNumber:
CB6159670
Molecular Formula:
C24H24NOP
Molecular Weight:
373.43
MDL Number:
MFCD03427599
MOL File:
148461-14-7.mol
Last updated:2024-03-22 17:12:53

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Properties

Melting point 85-90 °C
alpha -44° (c 1.4, CHCl3)
Boiling point 492.7±28.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka 4.31±0.70(Predicted)
form Powder
color white
optical activity [α]20/D 48±3°, c = 1% in chloroform
Sensitive air sensitive
BRN 5879302

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26-24/25
WGK Germany  3
10-23
Hazard Note  Irritant
HS Code  29349990

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-1822 (S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX 148461-14-7 50mg $103 2024-03-01 Buy
Strem Chemicals 15-1822 (S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX 148461-14-7 250mg $361 2024-03-01 Buy
Strem Chemicals 15-1822 (S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX 148461-14-7 1g $1084 2024-03-01 Buy
ChemScene CS-W011786 (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole >97.0% 148461-14-7 250mg $68 2021-12-16 Buy
AK Scientific 5316AQ (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole 148461-14-7 250mg $599.6 2021-12-16 Buy
Product number Packaging Price Buy
15-1822 50mg $103 Buy
15-1822 250mg $361 Buy
15-1822 1g $1084 Buy
CS-W011786 250mg $68 Buy
5316AQ 250mg $599.6 Buy

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties,Uses,Production

Chemical Properties

White crystalline powder

Reactions

  1. Chiral ligand used in the asymmetric reduction of highly substituted olefins.
  2. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
  3. Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
  4. Decarboxylative allylic alkylation.
Reactions of 148461-14-7

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Suppliers

Global( 93)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18751 58
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com China 52849 58
Zhuoer Chemical Co., Ltd
02120970332; +8613524231522 sales@zhuoerchem.com China 2904 58
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 403 58
PT CHEM GROUP LIMITED
+86-85511178; +86-85511178; peter68@ptchemgroup.com China 35425 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490 info@gihichemicals.com China 49978 58
Shaoxin Catsyn Co., Ltd.
+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58

View Lastest Price from (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE pictures 2024-12-17 (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
148461-14-7
US $0.00-0.00 / g 1g 97% 5kg XINXIANG RUNYU MATERIAL CO., LTD.
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE pictures 2019-07-11 (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
148461-14-7
US $3.00 / KG 1KG 99% 100kg Career Henan Chemical Co
(S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE (-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2- (4S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole Diphenylphosphinophenylmethylethyldihydrooxazole (4S)-(-)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98% (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98% (-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97% 2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole (S)-(-)-2-[(2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE,98%(S)-IPR-PHOX (4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole (4S)-(-)-2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole )-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN) [2-[(4S)-4-isopropyl-4,5-Dihydrooxazol-2-yl]phenyl]-diphenyl-phosphane Oxazole,2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-, (4S)- (4S)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e. (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole (S)-2-(2-(diphenylphosphanyl)phenyl)-4-isopropyl-4,5-dihydrooxazole (S)-iPr-Phox (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE 148461-14-7 C24H24NOP PHOX Privileged Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Chiral Phosphine PHOX Series organophosphine ligand