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Poly(tetrahydrofuran)

CAS No.
25190-06-1
Chemical Name:
Poly(tetrahydrofuran)
Synonyms
ptmg;PTMEG 2000;ptmg1000;POLYTETRAHYDROFURAN;PTHF;PTMEG 1000;TETRAMETHYLENE ETHER GLYCOL 2000 POLYMER;ptmg2000;polymeg;PTMEG 250
CBNumber:
CB6323066
Molecular Formula:
(C4H8O)nH2O
Molecular Weight:
305.43
MDL Number:
MFCD00148879
MOL File:
25190-06-1.mol
MSDS File:
SDS
Last updated:2024-10-24 21:11:45

Poly(tetrahydrofuran) Properties

Melting point 33-36 °C
Boiling point >204
Density 1 g/mL at 25 °C
vapor pressure <0.01 mm Hg ( 25 °C)
refractive index n20/D 1.465
Flash point >230 °F
storage temp. Store below +30°C.
solubility <10g/l
form Fused mass
Specific Gravity 0.961
PH 7 (H2O, 20℃)Aqueous solution
Viscosity 3,200-4,200cp (40C)
Indirect Additives used in Food Contact Substances POLYBUTYLENE GLYCOL
EPA Substance Registry System Poly(oxy-1,4-butanediyl), .alpha.-hydro-.omega.-hydroxy- (25190-06-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H412
Precautionary statements  P273
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  1
RTECS  MD0916000
TSCA  TSCA listed
HS Code  3907 20 20
Toxicity LD50 orally in Rabbit: > 5000 mg/kg

Poly(tetrahydrofuran) price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.18402 Polytetrahydrofuran 1000 (stabilisedwith2,6-di-tert-butyl-4-methylphenol)forsynthesis 25190-06-1 100g $39.5 2024-03-01 Buy
Sigma-Aldrich 8.18402 Polytetrahydrofuran 1000 (stabilisedwith2,6-di-tert-butyl-4-methylphenol)forsynthesis 25190-06-1 500g $57.5 2024-03-01 Buy
Sigma-Aldrich 345261 Poly(tetrahydrofuran) average Mn ~250 25190-06-1 1l $122 2023-06-20 Buy
Sigma-Aldrich 345261 Poly(tetrahydrofuran) average Mn ~250 25190-06-1 3l $259 2023-06-20 Buy
scipoly 758 Poly(tetramethylene ether) glycol 25190-06-1 250g $35 2024-07-03 Buy
Product number Packaging Price Buy
8.18402 100g $39.5 Buy
8.18402 500g $57.5 Buy
345261 1l $122 Buy
345261 3l $259 Buy
758 250g $35 Buy

Poly(tetrahydrofuran) Chemical Properties,Uses,Production

Chemical Properties

mp 11 - 38 °C 100 - 4,400 mPa.s @ 40 °C

Preparation

Low molecular weight polymers of tetrahydrofuran were introduced commercially in 1955. The polymers were intended for use in the preparation of flexible polyurethane foams, being terminated by hydroxyl groups:

25190-06-1 synthesis_1


Although these polyethers produced good foams they were rather expensive and were soon displaced by the cheaper propylene oxide-based polyethers. However, these polymers of tetrahydrofuran (commonly called poly(oxytetramethylene)glycol) now find use in the preparation of polyamide, polyester and polyurethane thermoplastic elastomers.
Details of the manufacture of polytetrahydrofuran have not been disclosed. Polymerization of tetrahydrofuran can be effected only by cationic initiators. Combinations of metal halides with water are not effective but protic acids (e.g. HCl04) and oxonium salts (e.g. (C2H5£?3O+BF4-) are efficient initiators. Polymerization occurs by a ring-opening mechanism involving a tertiary oxonium ion, e.g.

25190-06-1 synthesis_2

Definition

ChEBI: A macromolecule composed of repeating oxybutylene units.

Solubility in organics

Alcohol, slightly in water; Insoluble in ether

Poly(tetrahydrofuran) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 222)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12840 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5857 58
Hebei Weibang Biotechnology Co., Ltd
+8617732866630 bess@weibangbio.com China 18154 58
airuikechemical co., ltd.
+undefined86-15315557071 sales02@sdzhonghuimaterial.com China 983 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3002 58
Hebei Shengyang Water Conservancy Engineering Co., Ltd.
+8615373025980 clara@hbshengyang.com China 874 58
Hebei Youfeidi Trading Co., LTD
+8615530197691 admin@yfdchem.cn China 105 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Xiamen AmoyChem Co., Ltd
+86-86-5926051114 +8618959220845 sales@amoychem.com China 6383 58

View Lastest Price from Poly(tetrahydrofuran) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Poly(tetrahydrofuran) pictures 2024-11-20 Poly(tetrahydrofuran)
25190-06-1
US $60.00 / kg 1kg 99 5000 Hebei Zhuanglai Chemical Trading Co.,Ltd
Poly(tetrahydrofuran) pictures 2024-10-25 Poly(tetrahydrofuran)
25190-06-1
US $40.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
Poly(tetrahydrofuran) pictures 2024-10-24 Poly(tetrahydrofuran)
25190-06-1
US $30.00-10.00 / KG 50KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd

Poly(tetrahydrofuran) Spectrum

4-butanediyl),.alpha.-hydro-.omega.-hydroxy-poly(oxy-1 alpha-hydro-omega-hydroxy-poly(oxy-4-butanediyl) b2000 glycols,polytetramethylene hiprenemc532 polifurit poly(butyleneoxide) poly(oxy-1,4-butylene)glycol poly(oxybutylene)glycol poly(oxytetramethylene) poly(oxytetramethylene)diol poly(tetramethyleneether) poly(tetramethyleneether)diol poly(tetramethyleneglycol) poly(tetramethyleneoxide)glycol polybutyleneglycol polyfurit polyfurit1000 polyfurite polymeg1000 polymeg1020 polymeg2000 polymeg2010 polymeg600 polymeg650 polytetramethyleneetherglycols polytetramethyleneglycol ptg100 ptg200 ptg300 ptg400 ptg500 ptg500p qopolymeg qopolymeg1000 teracol teracol1000 teracol2000 teracol30 teracol650 terathane terathane1000 terathane2900 Tetrahydrofuranhomopolymer POLYETETRAHYDROFURAN, LINEAR-CHAIN POLYMER POLY(1,4-OXYBUTYLENE) GLYCOL POLYTETRAHYDROFURAN 1000 POLYTETRAHYDROFURAN 1000 S POLYTETRAHYDROFURAN 1400 POLYTETRAHYDROFURAN 1800 POLY(TETRAMETHYLENE ETHER) GLYCOL POLYTETRAMETHYLENE ETHER GLYCOL 1000 POLYTETRAMETHYLENE ETHER GLYCOL 1000 S POLYTETRAHYDROFURAN 2000 POLYTETRAHYDROFURAN 250 POLYTETRAHYDROFURAN 650 S POLYTETRAHYDROFURAN, LINEAR-CHAIN POLYMER POLY(TETRAMETHYLENE OXIDE) 2,000