- Poly(tetrahydrofuran)
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- $100.00 / 25kg
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2024-06-18
- CAS:25190-06-1
- Min. Order: 25kg
- Purity: 98%
- Supply Ability: 10000
- Poly(tetrahydrofuran)
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- $18.00 / 10kg
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2024-05-19
- CAS:25190-06-1
- Min. Order: 1kg
- Purity: 99.9
- Supply Ability: 5000
- Poly(tetrahydrofuran)
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- $60.00 / 1kg
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2024-05-18
- CAS:25190-06-1
- Min. Order: 1kg
- Purity: 99
- Supply Ability: 5000
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| | Poly(tetrahydrofuran) Basic information |
| | Poly(tetrahydrofuran) Chemical Properties |
| Melting point | 33-36 °C | | Boiling point | >204 | | density | 1 g/mL at 25 °C | | vapor pressure | <0.01 mm Hg ( 25 °C) | | refractive index | n20/D 1.465 | | Fp | >230 °F | | storage temp. | Store below +30°C. | | solubility | <10g/l | | form | Fused mass | | Specific Gravity | 0.961 | | PH | 7 (H2O, 20℃)Aqueous solution | | EPA Substance Registry System | Poly(oxy-1,4-butanediyl), .alpha.-hydro-.omega.-hydroxy- (25190-06-1) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 1 | | RTECS | MD0916000 | | TSCA | TSCA listed | | HS Code | 3907 20 20 | | Toxicity | LD50 orally in Rabbit: > 5000 mg/kg |
| | Poly(tetrahydrofuran) Usage And Synthesis |
| Chemical Properties | mp 11 - 38 °C 100 - 4,400 mPa.s @ 40 °C | | Preparation | Low molecular weight polymers of tetrahydrofuran were introduced commercially in 1955. The polymers were intended for use in the preparation of
flexible polyurethane foams, being terminated by hydroxyl groups:
Although these polyethers produced good foams they were rather expensive
and were soon displaced by the cheaper propylene oxide-based polyethers.
However, these polymers of tetrahydrofuran (commonly called poly(oxytetramethylene)glycol) now find use in the preparation of polyamide, polyester and polyurethane thermoplastic elastomers.
Details of the manufacture of polytetrahydrofuran have not been disclosed.
Polymerization of tetrahydrofuran can be effected only by cationic initiators.
Combinations of metal halides with water are not effective but protic acids
(e.g. HCl04) and oxonium salts (e.g. (C2H5￡?3O+BF4-) are efficient initiators.
Polymerization occurs by a ring-opening mechanism involving a tertiary
oxonium ion, e.g.
| | Definition | ChEBI: A macromolecule composed of repeating oxybutylene units. | | Solubility in organics | Alcohol, slightly in water; Insoluble in ether |
| | Poly(tetrahydrofuran) Preparation Products And Raw materials |
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