Copper(I) bromide-dimethyl sulfide
- CAS No.
- 54678-23-8
- Chemical Name:
- Copper(I) bromide-dimethyl sulfide
- Synonyms
- COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%
- CBNumber:
- CB6332325
- Molecular Formula:
- C2H6BrCuS
- Molecular Weight:
- 205.58
- MDL Number:
- MFCD00043295
- MOL File:
- 54678-23-8.mol
- MSDS File:
- SDS
Melting point | 132 °C (dec.)(lit.) |
---|---|
form | Crystalline Powder and/or Chunks |
color | Pale brown or pale green |
Water Solubility | Soluble in water. Reacts with water and decomposes. |
Sensitive | Moisture Sensitive/Air Sensitive |
BRN | 4386581 |
Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
InChIKey | PMHQVHHXPFUNSP-UHFFFAOYSA-M |
CAS DataBase Reference | 54678-23-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P280g-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36-24/25 | |||||||||
RIDADR | 1759 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-13-21 | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29309090 | |||||||||
NFPA 704 |
|
Copper(I) bromide-dimethyl sulfide price More Price(28)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 230502 | Copper(I) bromide dimethyl sulfide complex 99% | 54678-23-8 | 10g | $118 | 2024-03-01 | Buy |
Sigma-Aldrich | 230502 | Copper(I) bromide dimethyl sulfide complex 99% | 54678-23-8 | 50g | $320 | 2024-03-01 | Buy |
Alfa Aesar | 019368 | Copper(I) bromide-dimethyl sulfide complex | 54678-23-8 | 2g | $22.65 | 2024-03-01 | Buy |
Alfa Aesar | 019368 | Copper(I) bromide-dimethyl sulfide complex | 54678-23-8 | 10g | $84.6 | 2024-03-01 | Buy |
Strem Chemicals | 29-0225 | Copper(I) bromide, dimethyl sulfide complex, 99% | 54678-23-8 | 25g | $225 | 2021-12-16 | Buy |
Copper(I) bromide-dimethyl sulfide Chemical Properties,Uses,Production
Chemical Properties
off-white to beige, grey or green crystalline
Uses
Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to [60]fullerene and 3 groups to [70]fullerene.
Uses
Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.
Uses
Copper(I) bromide-dimethyl sulfide complex is used as catalyst for adding Grignard reagents to fullerenes.
Purification Methods
Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].
Copper(I) bromide-dimethyl sulfide Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12450 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21668 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29894 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 13214 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34571 | 58 |
View Lastest Price from Copper(I) bromide-dimethyl sulfide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2023-10-16 | Copper(I) bromide-dimethyl sulfide
54678-23-8
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
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2023-09-06 | Copper(I) bromide-dimethyl sulfide
54678-23-8
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | |
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2019-08-06 | Copper(I) bromide-dimethyl sulfide
54678-23-8
|
US $1.00 / KG | 1KG | 98% | 10KG | Career Henan Chemical Co |
-
- Copper(I) bromide-dimethyl sulfide
54678-23-8
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- Copper(I) bromide-dimethyl sulfide
54678-23-8
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
-
- Copper(I) bromide-dimethyl sulfide
54678-23-8
- US $1.00 / KG
- 98%
- Career Henan Chemical Co
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