Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Structure
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL structure
CAS No.
185913-97-7
Chemical Name:
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Synonyms
95.0% (H-NMR);(R)-CL-MEO-BIPHEP;(S)-CL-MEO-BIPHEP;(R)-MeO-Cl-BIPHEP;(R)-(+)-5，5′-Dichloro-2，2′-dimethoxy-1，1′min.(r)-cl-meo-biphep;-bis(diphenylphosphino)-6，6′(+)-5,5'-DICHLORO-2,2'-BIS(DIPHE.PHOS)6,6'-DIMETHOXYBIPHENYL
CBNumber:
CB6337966
Molecular Formula:
C38H30Cl2O2P2
Molecular Weight:
651.5
MDL Number:
MFCD03426987
MOL File:
185913-97-7.mol
Last updated:2023-04-23 13:52:06
Request For Quotation

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Properties

Melting point 176-180 °C
Boiling point 678.2±55.0 °C(Predicted)
form Powder
color yellow-white
optical activity [α]/D +59±4°, c = 1% in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Safety Statements  24/25
WGK Germany  3
F  10-23

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 96738 (R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl ≥95.0%(H-NMR) 185913-97-7 250mg $337 2024-03-01 Buy
Strem Chemicals 15-1055 (R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (R)-Cl-MeO-BIPHEP 185913-97-7 250mg $119 2024-03-01 Buy
Strem Chemicals 15-1055 (R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (R)-Cl-MeO-BIPHEP 185913-97-7 1g $414 2024-03-01 Buy
American Custom Chemicals Corporation ING0001309 (R)-(+)-5,5'-DICHLORO-6,6'- DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL 95.00% 185913-97-7 1G $1321.9 2021-12-16 Buy
BLDpharm BD232024 (R)-(5,5'-Dichloro-6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 98% 185913-97-7 1g $737 2021-12-16 Buy
Product number Packaging Price Buy
96738 250mg $337 Buy
15-1055 250mg $119 Buy
15-1055 1g $414 Buy
ING0001309 1G $1321.9 Buy
BD232024 1g $737 Buy

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties,Uses,Production

Description

1. Ligand used in the ruthenium catalyzed, enantioselective hydrogenation of alkenes, carbonyls, and imines.
2. Ligand used in the rhodium-catalyzed cyclization of acetylenic aldehydes.
3. Ligand used in the iridium-catalyzed hydrogenative coupling of alkynes to aromatic and aliphatic N-arylsulfonyl aldimines.
4. Asymmetric Cu-catalyzed propargylic substitution with amines,4a and enamines.4b
5. Catalytic desymmetrizing intramolecular Heck reaction.
6. Assembly of 1,3-polyols.
7. Pd-catalyzed diastereo/enantioselective allylic alkylations of ketone enolates.
8. Enantioselective vinylogous Reformatsky-type addition.
9. Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron- substituted allylcopper complexes.
and their In situ site-, diastereo-, and enantioselective additions to ketones.
Uses of (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Suppliers

Global( 27)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3009 60
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
Guangzhou CATO Research Chemicals Inc. 		+86-020-81960175-617 +8615602392859 Intermediate@cato-chem.com China 8056 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5876 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94657 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40228 62
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 sales@kingorgchem.com China 953 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2603 58
Shandong Ono Chemical Co., Ltd. 0539-6362799 20） China 9998 58
Supplier Advantage
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
Aladdin Scientific 		58
Guangzhou CATO Research Chemicals Inc. 		58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
LaaJoo 58
Shandong Ono Chemical Co., Ltd. 58

185913-97-7((R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL)Related Search:

Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM (II) CHLORIDE Chloro[(S)-(-)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 3-chloro[1,1'-biphenyl]-2-ol CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYL-PHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM(II) CHLORIDE CH2CL2 ADDUCT

1of2

(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL (R)-CL-MEO-BIPHEP (S)-(-)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL (S)-CL-MEO-BIPHEP (-)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL (+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL (-)-5,5'-DICHLORO-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL (+)-5,5'-DICHLORO-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL (-)-(5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL)-2,2'-DIYL-BIS(DIPHENYLPHOSPHINE) (+)-(5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL)-2,2'-DIYL-BIS(DIPHENYLPHOSPHINE) (+)-5,5'-DICHLORO-2,2'-BIS(DIPHE.PHOS)6,6'-DIMETHOXYBIPHENYL min.(r)-cl-meo-biphep (R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl,min.95%(R)-Cl-MeO-BIPHEP (s)-(+)-5,5'-dichloro-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-(+)-5,5'-Dichloro-6,6'- diMethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl (R)-Cl-MeO-BIPHEP (R)-MeO-Cl-BIPHEP Phosphine, 1,1'-[(1R)-5,5'-dichloro-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl- (R)-(+)-5,5'-Dichloro-2,2'-bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl >=95.0% (H-NMR) (R)-(5,5'-Dichloro-6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) (R)-(+)-5，5′ -bis(diphenylphosphino)-6，6′ -Dichloro-2，2′ -dimethoxy-1，1′ (R)-(5,5’-Dichloro-6,6’-dimethoxy-[1,1’-biphenyl]-2,2’-diyl)bis(diphenylphosphine) 95.0% (H-NMR) (R)-(+)-5,5''-Dichloro-6,6''-dimethoxy-2,2''-bis(diphenylphosphino)-1,1''-biphenyl 185913-97-7 Privileged Ligands BIPHEPs Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine MeOBIPHEP Series