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2,2'-Biimidazole

CAS No.
492-98-8
Chemical Name:
2,2'-Biimidazole
Synonyms
bisimidazole;1H,1'H-2,2'-BiiMidazole;DK7399;DK7719;NSC 522950;2-BIIMIDAZOLE;2,2'-BIIMIDAZOLE;2,2'-Diimidazole;2,2'-Biimidazole;2,2'-Bisimidazole
CBNumber:
CB6356248
Molecular Formula:
C6H6N4
Molecular Weight:
134.14
MDL Number:
MFCD00047014
MOL File:
492-98-8.mol
Last updated:2024-07-11 17:04:31

2,2'-Biimidazole Properties

Melting point >350°C
Boiling point 455.5±28.0 °C(Predicted)
Density 1.371±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
pka pK1: 5.01(+1) (25°C,μ= 0.3)
color Light yellow to Brown to Dark green
λmax 274nm(HCl aq.)(lit.)
InChI InChI=1S/C6H6N4/c1-2-8-5(7-1)6-9-3-4-10-6/h1-4H,(H,7,8)(H,9,10)
InChIKey AZUHIVLOSAPWDM-UHFFFAOYSA-N
SMILES C1(C2NC=CN=2)NC=CN=1
FDA UNII WEZ56MM6EC

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
Hazard Codes  Xi
HS Code  2933.29.4300
HazardClass  IRRITANT

2,2'-Biimidazole price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B2487 2,2'-Biimidazole >98.0%(HPLC)(T) 492-98-8 1g $157 2024-03-01 Buy
TCI Chemical B2487 2,2'-Biimidazole >98.0%(HPLC)(T) 492-98-8 5g $543 2024-03-01 Buy
TRC B695145 1H,1''H-2,2''-Biimidazole 492-98-8 500mg $90 2021-12-16 Buy
AK Scientific 4239AE 2,2'-Biimidazole 492-98-8 1g $103 2021-12-16 Buy
ChemScene CS-W021324 1H,1'H-2,2'-Biimidazole ≥97.0% 492-98-8 5g $142 2021-12-16 Buy
Product number Packaging Price Buy
B2487 1g $157 Buy
B2487 5g $543 Buy
B695145 500mg $90 Buy
4239AE 1g $103 Buy
CS-W021324 5g $142 Buy

2,2'-Biimidazole Chemical Properties,Uses,Production

Chemical Properties

2,2'-Biimidazole is soluble in polar solvents such as methanol, water and dimethyl sulfoxide (DMSO).

Uses

1H,1''H-2,2''-Biimidazole is used in the preparation of complexes that exhibits photoluminescence and optical properties. Also used in the preparation of bismuth biimidazoles as semi-conductors.

Application

2,2'-Biimidazole is an important organic reagent used as:
(1) Preparation of catalytically active coordination compounds. It is a Lewis base capable of producing coordination compounds with metal ions such as Cu(I), Ag(I), Au(I-II) and palladium, which are used as efficient catalysts in other chemical reactions.
(2) Construction of hypercrosslinked polymers 2,2′-biimidazolyl HCPs, which are used as adsorbents and sensors for iodine capture and DNP detection in the field of environmental remediation.
(3) Synthesis of fluorescent proteins, nanoparticles and other ligand compounds.

Synthesis

120 ml of distilled water was added to 1,092 g (14.2 mol, 4.0 eq.) of ammonium acetate at 40 ℃, 500 g of 20 wt percent aqueous glyoxal (3.45 mol) was then slowly added dropwise to the resulting slurry for three hours while stirring vigorously. Immediately after the addition was finished, the reaction mixture was neutralized with distilled water to adjust the pH to 5-7. The produced brown-colored solid was filtered and washed alternately with 500 ml of acetone and 500 ml of distilled water several times to obtain 82.0 g (53.2 percent yield) of 2,2'-Biimidazole.

2,2'-Biimidazole Preparation Products And Raw materials

Global( 135)Suppliers
Supplier Tel Email Country ProdList Advantage
Finetech Industry Limited
+86-27-87465837 +8618971612321 info@finetechnology-ind.com China 9640 58
Shaanxi Dideu Medichem Co. Ltd
18192627656 1012@dideu.com China 3002 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12837 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18648 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32820 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29886 58
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd.
0431-80514535 13634302652 Extension@chemextension.com CHINA 967 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CHEMSOON CO.,LTD.
+8613761723174 sales01@chemsoon.com China 1211 58
Neostar United (Changzhou) Industrial Co., Ltd.
+86-0519-85551759 +8613506123987 marketing1@neostarunited.com China 8838 58

View Lastest Price from 2,2'-Biimidazole manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,2'-Biimidazole pictures 2024-07-11 2,2'-Biimidazole
492-98-8
US $1.00-100.00 / KG 1KG 95% 200000KG Shaanxi Dideu Medichem Co. Ltd
2,2'-BIIMIDAZOLE pictures 2023-08-26 2,2'-BIIMIDAZOLE
492-98-8
US $100.00 / KG 1KG 99% 5000KG Hebei Mojin Biotechnology Co., Ltd
2,2'-BIIMIDAZOLE pictures 2021-05-09 2,2'-BIIMIDAZOLE
492-98-8
US $10.00 / PCS 1KG 99% 100 mt Hebei Weibang Biotechnology Co., Ltd
LABOTEST-BB LTBB005450 2,2'-bi-1H-imidazole 2-(1H-imidazol-2-yl)-1H-imidazole 1H,1'H-[2,2']BIIMIDAZOLYL 2,2'-BIIMIDAZOLE 2,2'-Biimidazolyl 2,2'-Bisimidazole 2,2'-Diimidazole Glycosine of Debus NSC 522950 2,2'-Biimidazole > 2,2'-BIIMIDAZOLE ISO 9001:2015 REACH 2-BIIMIDAZOLE bisimidazole 1H,1'H-2,2'-BiiMidazole DK7399 DK7719 2,2'-Biimidazole 1H,1'H-2,2'-Biimidazole 2,2'-Bi-1H-imidazole 492-98-8