tert-Butyl nitrite
- CAS No.
- 540-80-7
- Chemical Name:
- tert-Butyl nitrite
- Synonyms
- t-BuNO2;T-BUTYL NITRITE;t-butyl ester;2-Methyl-2-nitrosooxy-propane;t-Buthyl nitrite;ert-buty nitrite;ert-Butylnitrite;Tert-buty nitrite;TERT-BUTYL NITRITE;TIMTEC-BB SBB007659
- CBNumber:
- CB6853772
- Molecular Formula:
- C4H9NO2
- Molecular Weight:
- 103.12
- MDL Number:
- MFCD00002055
- MOL File:
- 540-80-7.mol
- MSDS File:
- SDS
Boiling point | 61-63 °C(lit.) |
---|---|
Density | 0.867 g/mL at 25 °C(lit.) |
vapor pressure | 13.466kPa at 25℃ |
refractive index |
n |
Flash point | −10 °F |
storage temp. | 2-8°C |
solubility | alcohol: very soluble(lit.) |
form | Liquid |
color | Clear yellow |
Water Solubility | slightly soluble |
Merck | 14,1583 |
BRN | 1209339 |
LogP | 2.24 at 20℃ |
CAS DataBase Reference | 540-80-7(CAS DataBase Reference) |
EWG's Food Scores | 1 |
FDA UNII | 4780H7U8LU |
NIST Chemistry Reference | (CH3)3CONO(540-80-7) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225-H302+H332 | |||||||||
Precautionary statements | P210-P233-P240-P241-P301+P312-P304+P340+P312 | |||||||||
Hazard Codes | F,Xn | |||||||||
Risk Statements | 11-20/22 | |||||||||
Safety Statements | 16-24-46 | |||||||||
RIDADR | UN 2351 3/PG 2 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | RA0802000 | |||||||||
F | 8 | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29209085 | |||||||||
NFPA 704 |
|
tert-Butyl nitrite price More Price(19)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 20370 | tert-Butyl nitrite technical, ≥90% (GC) | 540-80-7 | 100mL | $92 | 2024-03-01 | Buy |
Sigma-Aldrich | 20370 | tert-Butyl nitrite technical, ≥90% (GC) | 540-80-7 | 500mL | $323 | 2024-03-01 | Buy |
TCI Chemical | N0357 | tert-Butyl Nitrite >90.0%(GC) | 540-80-7 | 25mL | $65 | 2024-03-01 | Buy |
TCI Chemical | N0357 | tert-Butyl Nitrite >90.0%(GC) | 540-80-7 | 250mL | $392 | 2024-03-01 | Buy |
Alfa Aesar | L16135 | tert-Butyl nitrite tech. 90% | 540-80-7 | 25g | $35.4 | 2023-06-20 | Buy |
tert-Butyl nitrite Chemical Properties,Uses,Production
Chemical Properties
clear yellow liquid
Uses
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.
Uses
Jet propellant.
General Description
tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.
Purification Methods
If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]
tert-Butyl nitrite Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
1of3
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5889 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20285 | 58 |
airuikechemical co., ltd. | +undefined86-15315557071 | sales02@sdzhonghuimaterial.com | China | 983 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 9150 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29880 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8618959220845 | sales@amoychem.com | China | 6383 | 58 |
View Lastest Price from tert-Butyl nitrite manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-10-25 | tert-Butyl nitrite
540-80-7
|
US $50.00 / KG | 25KG | 98% | 200 tons | Hebei Yanxi Chemical Co., Ltd. | ||
2024-10-15 | Tert-Butyl nitrite
540-80-7
|
US $0.00-0.00 / Kg | 1Kg | 99.99% | 20 tons | airuikechemical co., ltd. | ||
2024-10-11 | tert-Butyl nitrite
540-80-7
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD |
- tert-Butyl nitrite
540-80-7
- US $50.00 / KG
- 98%
- Hebei Yanxi Chemical Co., Ltd.
- Tert-Butyl nitrite
540-80-7
- US $0.00-0.00 / Kg
- 99.99%
- airuikechemical co., ltd.
- tert-Butyl nitrite
540-80-7
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD