Allylboronic acid pinacol ester
- CAS No.
- 72824-04-5
- Chemical Name:
- Allylboronic acid pinacol ester
- Synonyms
- 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane;AKOS BRN-1082;PINACOL ALLYLBORONATE;Allyl pinacol boronate;Pinacolyl 2-propenylboronate;Allylboronic acid pinacolate;Allylboronic acid picol ester;Allyl boronic acid pinal ester;ALLYLBORONIC ACID PINACOL ESTER
- CBNumber:
- CB7169827
- Molecular Formula:
- C9H17BO2
- Molecular Weight:
- 168.04
- MDL Number:
- MFCD00013347
- MOL File:
- 72824-04-5.mol
- MSDS File:
- SDS
Boiling point | 50-53 °C/5 mmHg (lit.) |
---|---|
Density | 0.896 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 115 °F |
storage temp. | 2-8°C |
solubility | Chloroform, Methanol (Slightly) |
form | Liquid |
color | Clear colorless |
Water Solubility | Not miscible or difficult to mix in water. |
BRN | 4244068 |
CAS DataBase Reference | 72824-04-5(CAS DataBase Reference) |
UNSPSC Code | 12352103 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS02 |
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Signal word | Warning | |||||||||
Hazard statements | H226 | |||||||||
Precautionary statements | P210-P233-P240-P241-P242-P243 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 10-36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
RIDADR | UN 1993 3/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Irritant | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29310095 | |||||||||
NFPA 704 |
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Allylboronic acid pinacol ester price More Price(47)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 324647 | Allylboronic acid pinacol ester 97% | 72824-04-5 | 1g | $50.1 | 2024-03-01 | Buy |
Sigma-Aldrich | 324647 | Allylboronic acid pinacol ester 97% | 72824-04-5 | 10g | $308 | 2024-03-01 | Buy |
TCI Chemical | A2157 | 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >96.0%(GC) | 72824-04-5 | 1g | $41 | 2024-03-01 | Buy |
TCI Chemical | A2157 | 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >96.0%(GC) | 72824-04-5 | 5g | $115 | 2024-03-01 | Buy |
Alfa Aesar | L16232 | Allylboronic acid pinacol ester, 98+% | 72824-04-5 | 1g | $37.65 | 2024-03-01 | Buy |
Allylboronic acid pinacol ester Chemical Properties,Uses,Production
Chemical Properties
Clear corless liquid
Uses
Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .
Uses
Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.
Allylboronic acid pinacol ester Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20234 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-+86-371-66670886 | info@dakenam.com | China | 19805 | 58 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 904 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 19825 | 58 |
Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2176 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
View Lastest Price from Allylboronic acid pinacol ester manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2024-04-08 | Allylboronic acid pinacol ester
72824-04-5
|
US $34.00-1.20 / kg | 1kg | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
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2021-07-13 | Allylboronic acid pinacol ester
72824-04-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
![]() |
2021-07-10 | Allylboronic acid pinacol ester
72824-04-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
-
- Allylboronic acid pinacol ester
72824-04-5
- US $34.00-1.20 / kg
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Allylboronic acid pinacol ester
72824-04-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- Allylboronic acid pinacol ester
72824-04-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd