(5α,25α)-8,14-Didehydrocevane-3β,15β-diol
- CAS No.
- 20072-14-4
- Chemical Name:
- (5α,25α)-8,14-Didehydrocevane-3β,15β-diol
- Synonyms
- Korseveridine;Cevane-3,15-diol, 8,14-didehydro-, (3β,5α,15β,25α)- (9CI)
- CBNumber:
- CB72178777
- Molecular Formula:
- C27H43NO2
- Molecular Weight:
- 413.64
- MDL Number:
- MOL File:
- 20072-14-4.mol
(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Chemical Properties,Uses,Production
Description
This steroidal alkaloid is present in the bulbs of Korolkowia sewerzowii. It forms a series of crystalline salts, e.g. the hydrochloride, m.p. 326°C; hydrobromide, m.p. 315°C; hydriodide, m.p. 306°C and the methiodide, m.p. 312°C. The 0,0- diacetate has m.p. 200-l oC. When treated with aluminium in phenol and Me2 CO at 100°C for 4 hours, the alkaloid yields korseveridinone, m.p. 123-4°C. The positions of all the functional groups have been ascertained by NMR and mass spectroscopy.
References
Nuriddinov, Yunusov., Khim. Prir. Soedin., 3, 398 (1967)
Nuriddinov, Yunusov., ibid, 4, 101 (1968)
(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Preparation Products And Raw materials
Raw materials
Preparation Products
Korseveridine
Cevane-3,15-diol, 8,14-didehydro-, (3β,5α,15β,25α)- (9CI)
20072-14-4