(5α,25α)-8,14-Didehydrocevane-3β,15β-diol

(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Struktur
20072-14-4
CAS-Nr.
20072-14-4
Englisch Name:
(5α,25α)-8,14-Didehydrocevane-3β,15β-diol
Synonyma:
Korseveridine;Cevane-3,15-diol, 8,14-didehydro-, (3β,5α,15β,25α)- (9CI)
CBNumber:
CB72178777
Summenformel:
C27H43NO2
Molgewicht:
413.64
MOL-Datei:
20072-14-4.mol

(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Eigenschaften

Schmelzpunkt:
291- 2°C

Sicherheit

(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

This steroidal alkaloid is present in the bulbs of Korolkowia sewerzowii. It forms a series of crystalline salts, e.g. the hydrochloride, m.p. 326°C; hydrobromide, m.p. 315°C; hydriodide, m.p. 306°C and the methiodide, m.p. 312°C. The 0,0- diacetate has m.p. 200-l oC. When treated with aluminium in phenol and Me2 CO at 100°C for 4 hours, the alkaloid yields korseveridinone, m.p. 123-4°C. The positions of all the functional groups have been ascertained by NMR and mass spectroscopy.

Einzelnachweise

Nuriddinov, Yunusov., Khim. Prir. Soedin., 3, 398 (1967)
Nuriddinov, Yunusov., ibid, 4, 101 (1968)

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  • Korseveridine
  • Cevane-3,15-diol, 8,14-didehydro-, (3β,5α,15β,25α)- (9CI)
  • 20072-14-4
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