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ChemicalBook >> CAS DataBase List >>Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Structure
Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 structure
CAS No.
944451-33-6
Chemical Name:
Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　
Synonyms
(S)-RuCl[(p-cyMene)(DTBM-SEGPHOS)]Cl;[RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL;[RuCl(p-cymene)((S)-dtbm-segphos[R])]Cl;oro{(S)-(+)-5,5''-bis[di(3,5-di-t-butyL;[RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl;[RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl;Chloro[(S)-(+)-5,5'-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride;Chloro[(S)-(+)-5,5'-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride;Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　;Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dtbm-segphos(R))]Cl
CBNumber:
CB72512465
Molecular Formula:
C84H112Cl2O8P2Ru
Molecular Weight:
1483.73
MDL Number:
MFCD09753019
MOL File:
944451-33-6.mol
Last updated:2023-06-08 17:06:35
Request For Quotation

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Properties

Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color orange to brown
Sensitive air sensitive

SAFETY

Risk and Safety Statements

WGK Germany  3
HS Code  2843.90.0000

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 693073 (S)-RuCl[(p-cymene)(DTBM-SEGPHOS?)]Cl 944451-33-6 100mg $22.56 2024-03-01 Buy
Sigma-Aldrich 693073 (S)-RuCl[(p-cymene)(DTBM-SEGPHOS?)]Cl 944451-33-6 50mg $28.9 2023-01-07 Buy
TCI Chemical R0159 [RuCl(p-cymene)((S)-dtbm-segphos[R])]Cl 944451-33-6 200mg $57 2024-03-01 Buy
TCI Chemical R0159 [RuCl(p-cymene)((S)-dtbm-segphos[R])]Cl 944451-33-6 1g $186 2024-03-01 Buy
Strem Chemicals 44-0103 Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dtbm-segphos(R))]Cl 944451-33-6 250mg $53 2024-03-01 Buy
Product number Packaging Price Buy
693073 100mg $22.56 Buy
693073 50mg $28.9 Buy
R0159 200mg $57 Buy
R0159 1g $186 Buy
44-0103 250mg $53 Buy

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chemical Properties,Uses,Production

Reaction

Biaryl bisphosphine ligand with narrow dihedral angle. The DTBM SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity through dynamic kinetic resolution in the asymmetric hydrogenation of a-substituted-β-ketoesters useful in the synthesis of carbapenum antibiotics. Reactions of 944451-33-6  

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Preparation Products And Raw materials

Raw materials

Preparation Products

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Suppliers

Global( 22)Suppliers
Supplier Tel Email Country ProdList Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd. 		+86-057181025280; +8617767106207 sales@molcore.com China 49734 58
Zibo Hangyu Biotechnology Development Co., Ltd 		+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 10986 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94657 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44688 61
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28387 80
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 sales@kingorgchem.com China 953 55
TCI Chemicals 021-67121386, 800-988-0390 Sales-CN@TCIchemicals.com China 5391 58
Jiangsu aikang biomedical research and development co., LTD 025-66110311 13155353615 qzhang@aikonchem.com China 15527 58
CHG Opto-Electronic Corporation Limited 2537653158 16621191650 2537653158@qq.com China 7096 58
Supplier Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd. 		58
Zibo Hangyu Biotechnology Development Co., Ltd 		58
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
TOKYO CHEMICAL INDUSTRY CO., LTD. 80
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
TCI Chemicals 58
Jiangsu aikang biomedical research and development co., LTD 58
CHG Opto-Electronic Corporation Limited 58

944451-33-6(Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　)Related Search:

Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　

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Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 (S)-RuCl[(p-cyMene)(DTBM-SEGPHOS)]Cl [RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL Chloro[(S)-(+)-5,5'-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dtbm-segphos(R))]Cl [RuCl(p-cymene)((S)-dtbm-segphos[R])]Cl [RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl oro{(S)-(+)-5,5''-bis[di(3,5-di-t-butyL Chloro[(S)-(+)-5,5'-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride 944451-33-6