ChemicalBook >> CAS DataBase List >>5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole

CAS No.
1239478-87-5
Chemical Name:
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
Synonyms
AdBippyphos;Ad-BGPhos;Adamantyl-BippyPhos;5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole;5-[Bis(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1,4′-bi-1H-pyrazole;5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole;5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole;5-[Di(1-adamantyl)phosphino]-1',3',5'-triphenyl-1'H-[1,4']bipyrazole 97%;5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole;5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]- 1',3',5'-triphenyl-1,4'-Bi-1H-pyrazole
CBNumber:
CB72720831
Molecular Formula:
C44H47N4P
Molecular Weight:
662.84
MDL Number:
MFCD22200502
MOL File:
1239478-87-5.mol
MSDS File:
SDS
Last updated:2023-05-11 17:26:00

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole Properties

Melting point 295-300°C
storage temp. 2-8°C
form solid
pka -0.58±0.19(Predicted)
color white to light yellow

SAFETY

Risk and Safety Statements

Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P305+P351+P338-P304+P340-P405-P501A
Risk Statements  36/37/38
Safety Statements  26-37
WGK Germany  3
TSCA  No

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 740845 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97% 1239478-87-5 1g $400 2024-03-01 Buy
Sigma-Aldrich 740845 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97% 1239478-87-5 5g $1360 2024-03-01 Buy
Sigma-Aldrich 740845 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97% 1239478-87-5 250mg $153 2024-03-01 Buy
TRC D495213 5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole 1239478-87-5 2.5mg $45 2021-12-16 Buy
ChemSupplyAustralia 300040 5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97% 1239478-87-5 250mg $77 2021-12-16 Buy
Product number Packaging Price Buy
740845 1g $400 Buy
740845 5g $1360 Buy
740845 250mg $153 Buy
D495213 2.5mg $45 Buy
300040 250mg $77 Buy

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole Chemical Properties,Uses,Production

Uses

5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole can be used as a catalyst.

Uses

5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole (Ad-BippyPhos) is an effective ligand that catalyzes C-O coupling reactions of aryl and heteroaryl bromides/chlorides with primary aliphatic alcohols. It can also be used as a catalyst in the synthesis of fluorinated anilines by coupling fluoroalkylamines with aryl bromides and chlorides.

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 33)Suppliers
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Accela ChemBio Inc.
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JIAXING REGEN CHEMICAL CO.,LTD
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Zhengzhou Alfa Chemical Co.,Ltd
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Hangzhou MolCore BioPharmatech Co.,Ltd.
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LEAPCHEM CO., LTD.
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Aladdin Scientific
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Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32343 55
Beijing HwrkChemical Technology Co., Ltd 010-89508211 18501085097 sales.bj@hwrkchemical.com China 8415 55
Adamas Reagent, Ltd. 400-6009262 16621234537 chenyj@titansci.com China 14103 59
5-[Di(1-adaMantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97+% (AdaMantyl-BippyPhos) 5-[Bis(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1,4′-bi-1H-pyrazole 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole Adamantyl-BippyPhos 5-[Di(1-adamantyl)phosphino]-1',3',5'-triphenyl-1'H-[1,4']bipyrazole 97% 5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, (Adamantyl-BippyPhos) 5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]- 1',3',5'-triphenyl-1,4'-Bi-1H-pyrazole 1,4'-Bi-1H-pyrazole, 5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-1',3',5'-triphenyl- 5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole[Adamantyl-BippyPhos Ad-BGPhos AdBippyphos 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole 1239478-87-5 C44H47N4P