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ChemicalBook >> CAS DataBase List >> 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole price.
  • $45 - $1360
  • Product name: 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
  • CAS: 1239478-87-5
  • MF: C44H47N4P
  • MW: 662.84
  • EINECS:
  • MDL Number:MFCD22200502
  • Synonyms:5-[Di(1-adaMantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97+% (AdaMantyl-BippyPhos);5-[Bis(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1,4′-bi-1H-pyrazole;5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole;Adamantyl-BippyPhos;5-[Di(1-adamantyl)phosphino]-1',3',5'-triphenyl-1'H-[1,4']bipyrazole 97%;5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, (Adamantyl-BippyPhos);5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]- 1',3',5'-triphenyl-1,4'-Bi-1H-pyrazole;1,4'-Bi-1H-pyrazole, 5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-1',3',5'-triphenyl-
6 prices
Selected condition:
Brand
  • American Custom Chemicals Corporation
  • ChemSupplyAustralia
  • Sigma-Aldrich
  • TRC
Package
  • 2.5mg
  • 5MG
  • 250mg
  • 1g
  • 5g
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOPC0001014
  • Product description5-[DI(1-ADAMANTYL)PHOSPHINO](1,3,5-TRIPHENYL-1H-PYRAZOL-4-YL)-1H-PYRAZOLE 95.00%
  • Packaging5MG
  • Price$455.87
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300040
  • Product description5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97%
  • Packaging250mg
  • Price$77
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number740845
  • Product description5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97%
  • Packaging250mg
  • Price$153
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number740845
  • Product description5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97%
  • Packaging1g
  • Price$400
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number740845
  • Product description5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97%
  • Packaging5g
  • Price$1360
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberD495213
  • Product description5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole
  • Packaging2.5mg
  • Price$45
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation OPC0001014 5-[DI(1-ADAMANTYL)PHOSPHINO](1,3,5-TRIPHENYL-1H-PYRAZOL-4-YL)-1H-PYRAZOLE 95.00% 5MG $455.87 2021-12-16 Buy
ChemSupplyAustralia 300040 5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97% 250mg $77 2021-12-16 Buy
Sigma-Aldrich 740845 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97% 250mg $153 2024-03-01 Buy
Sigma-Aldrich 740845 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97% 1g $400 2024-03-01 Buy
Sigma-Aldrich 740845 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole 97% 5g $1360 2024-03-01 Buy
TRC D495213 5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole 2.5mg $45 2021-12-16 Buy

Properties

Melting point :295-300°C
storage temp. :2-8°C
form :solid
pka :-0.58±0.19(Predicted)
color :white to light yellow

Safety Information

Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole (Ad-BippyPhos) is an effective ligand that catalyzes C-O coupling reactions of aryl and heteroaryl bromides/chlorides with primary aliphatic alcohols. It can also be used as a catalyst in the synthesis of fluorinated anilines by coupling fluoroalkylamines with aryl bromides and chlorides.