ChemicalBook >> CAS DataBase List >>2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
- CAS No.
- 98015-45-3
- Chemical Name:
- 2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
- Synonyms
- BEMP;>=97% (GC);Hexanal ≥imino-2-diethyL;L-Norleucinol ≥amino-1,3-dimethyL;2-Pentyne-1-ol ≥DL-Nornicotine ≥3-Cyanocoumarin ≥3-Methoxyphenol &ge
- CBNumber:
- CB7301715
- Molecular Formula:
- C13H31N4P
- Molecular Weight:
- 274.39
- MDL Number:
- MFCD00043143
- MOL File:
- 98015-45-3.mol
- MSDS File:
- SDS
Last updated:2025-01-27 09:38:02
| Boiling point | 74 °C0.03 mm Hg(lit.) |
|---|---|
| Density | 0.948 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 127 °F |
| storage temp. | Room Temperature |
| solubility | Acetonitrile (Slightly), Water (Slightly) |
| form | Liquid |
| color | Colorless |
| BRN | 5534901 |
| FDA UNII | DF15J146QI |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|---|---|
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 |
| Hazard Codes | C,N,F |
| Risk Statements | 34-67-65-62-51/53-48/20-11 |
| Safety Statements | 26-36/37/39-45-62-61-16 |
| RIDADR | UN 2920 8/PG 2 |
| WGK Germany | 3 |
| F | 10-34 |
| HazardClass | 3.2 |
| PackingGroup | III |
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 20025 | 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine purum, ≥98.0% (GC) | 98015-45-3 | 1ml | $138 | 2024-03-01 | Buy |
| Sigma-Aldrich | 20025 | 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine purum, ≥98.0% (GC) | 98015-45-3 | 5ml | $658 | 2024-03-01 | Buy |
| Sigma-Aldrich | 728411 | 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution 1 M in hexane, ≥97% (GC), 97% (GC) | 98015-45-3 | 25ml | $285 | 2024-03-01 | Buy |
| Sigma-Aldrich | 728411 | 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution 1 M in hexane, ≥97% (GC), 97% (GC) | 98015-45-3 | 100ml | $887 | 2024-03-01 | Buy |
| Sigma-Aldrich | 20025 | 2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine purum, ≥98.0% (GC) | 98015-45-3 | 25ml | $804 | 2024-03-01 | Buy |
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE Chemical Properties,Uses,Production
Uses
Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases
General Description
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine (BEMP) is a phosphazene base. BEMP participates in the mild base catalyzed nucleophilic ring opening of N-sulfonyl aziridines. BEMP supported on polystyrene (PS-BEMP) has been reported as an efficient catalyst for the ring-opening of epoxides with phenols. BEMP is about 2000 times more basic and also much more sterically hindered than DBU (l,8-diazabicyclo[5.4.0]undecene).
References
1. Schwesinger, R.; Willaredt, J.; Sclemper, H.; Keller, M.; Schmitt, D.; Fritz, H., Chem. Ber. 1994, 127, 2435.
2. Schwesinger, R., Chimia 1985, 39, 269.
3. Commercially available from Fluka.
4. Xu, W.; Mohan, R.; Morrissey, M. M., Biorg. Med. Chem. Lett. 1998, 8, 1089.
5. McComas, W.; Chen, L.; Kim, K., Tetrahedron Lett. 2000, 41, 3573.
6. Caldarelli, M.; Habermann, J.; Ley, S. V., J. Chem. Soc., Perkin Trans. 1. 1999, 107.
Synthesis of 2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE from Phosphoramidimidic dichloride, N'-(1,1-dimethylethyl)-N,N-diethyl-
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE Preparation Products And Raw materials
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE Suppliers
Global( 52)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49476 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57505 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615350571055 | Sibel@weibangbio.com | China | 6087 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 021-61259108 18621169109 | market03@meryer.com | China | 40228 | 62 |
| Beijing Ouhe Technology Co., Ltd | 010-82967028 13552068683 | 2355560935@qq.com | China | 12443 | 60 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42958 | 64 |
| Thermo Fisher Scientific | 800-810-5118 | cnchemical@thermofisher.com | China | 17770 | 75 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51456 | 80 |
98015-45-3(2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE)Related Search:
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE ON POLYSTYRENE
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE, POLYMER-BOUND
PHOSPHAZENE BASE P1-T-BU
IMINO-TRIS(DIMETHYLAMINO)PHOSPHORANE
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
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1,3-Dimethyl-2-(diethylamino)-2-(tert-butylimino)-1,3-diaza-2-phospha(V)cyclohexane
1,3-Dimethyl-2-(diethylamino)-2-(tert-butylimino)hexahydro-1,3,2-diazaphosphorine
2-(tert-Butylimino)-2-(diethylamino)-1,3-dimethylhexahydro-1,3,2-diazaphosphorine
2,6-Dimethyl-1-(tert-butylimino)-N,N-diethyl-1,1-dihydro-2,6-diazaphosphorinane-1-amine
2-tert-Butylimino-2-diethylamino-1,3-dimethylhexahydro-1,3,2-diazaphosphorine
N,N-Diethyl-1,3-dimethyl-2-(tert-butylimino)-1,2,3,4,5,6-hexahydro-2H,2H-1,3,2-diazaphosphorine-2-amine
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DIMETHYL-PERHYDRO-1,3,2-DIAZAPHOSPHORINE
2-TERT-BUTYLIMINO-2-DIETHYLAMINO-1,3-DI- METHYLPERHYDRODIAZAPHOSPHORINE, 98%
2-T-BU-IMINO-2-DIETHAMINO-1,3,DIME-PER-H YDRO-DIAZAPHOSPHOR.
2-tert-Butylimino-2-diethylamino-1,3-diethyl-perhydro-1,3,2-diazaphosphorine
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution 1 M in hexane, >=97% (GC), 97% (GC)
2-tert-Butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2
2-tert-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine purum, >=98.0% (GC)
>=97% (GC)
2-|tert|-Butylimino-2-diethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine solution
3,5-Dibromo-2,4,6-trimethylpyridine &ge
5-Iodo-2-methoxypyridine &ge
1-Bromo-3-hydroxypropane &ge
4-Chlorobutyl acetate &ge
2-Bromo-3-methyl-5-nitropyridine &ge
4-Acetyl-piperidine-1-carboxylic acid tert-butyl ester &ge
3-Amino-4-bromopyridine &ge
2-Bromo-5-chloropyridine &ge
3-Iodomethyl-pyrrolidine-1-carboxylic acid tert-butyl ester &ge
2-Chloro-4-methoxypyridine &ge
2λ5-1,3,2-Diazaphosphorin-2-amine, 2-[(1,1-dimethylethyl)imino]-N,N-diethylhexahydro-1,3-dimethyl-
amino-1,3-dimethyL
imino-2-diethyL
perhydro-1,3,2-diazaphosphorine
2-tert-Butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine solution, 1M in hexane
2-tert-butylimino-N,N-diethyl-1,3-dimethyl-1,3,2
8-Bromoquinoline &ge
3-(3-Methoxyphenyl)propionic acid &ge
(Bromomethyl)cyclopropane &ge
Cyclopropylacetic acid &ge
3-(4-Fluorophenoxy)propanenitrile &ge
(+/-)-2-Hydroxydecanoic acid &ge
1-Benzyl-4-formylpiperidine &ge
n-Dodecyltrimethoxysilane &ge
1-Benzylpyrrolidin-3-yl-methanol &ge
4-Phenoxyaniline &ge
3,4,5-Trimethoxyaniline &ge
1-N-Boc-4-bromopiperidine &ge
1-(5-Chloropyridin-2-yl)piperazine &ge
2-Cyano-3-methylaniline &ge
3-Methoxy-2-butanol &ge
N-Methyl-N-tetrahydro-2H-pyran-4-ylamine &ge
3-Bromo-4-methylphenol &ge
Tert-Butyl Trans-(2-Hydroxymethyl)Cyclopropylcarbamate &ge
2-Ethoxybenzaldehyde &ge
2-Iodo-1-methyl-3-nitrobenzene &ge
4-Hydroxy-3-methoxy-a-methylbenzyl alcohol &ge
2-(Benzyloxy)acetic acid &ge
3-Bromoquinoline &ge
Tetrahydropyran-4-carbaldehyde &ge
2-Chloro-3-methylpyridine &ge
1-Pyridin-3-ylmethyl-piperazine &ge
tert-Butyl 2-aminopropylcarbamate &ge