1,8-Dibromonaphthalene
- CAS No.
- 17135-74-9
- Chemical Name:
- 1,8-Dibromonaphthalene
- Synonyms
- CASC;1,8-DBN;1,8-dibromonalene;8-DIBROMONAPHTALENE;1,8-DibromonaphthaL;1,8-dibroMophthalene;1,8-DIBROMONAPHTALENE;1,8-dibromonaphthylene;1,8-dibromonaphthalene;Naphthalene,1,8-dibromo-
- CBNumber:
- CB7303678
- Molecular Formula:
- C10H6Br2
- Molecular Weight:
- 285.96
- MDL Number:
- MFCD00183574
- MOL File:
- 17135-74-9.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H411 |
| Precautionary statements | P273-P301+P312+P330 |
| Hazard Codes | Xn,N |
| Risk Statements | 22-50 |
| Safety Statements | 61 |
| RIDADR | UN 3077 9 / PGIII |
| WGK Germany | 3 |
| HS Code | 29039990 |
1,8-Dibromonaphthalene price More Price(40)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 764094 | 1,8-Dibromonaphthalene 97% | 17135-74-9 | 1g | $127 | 2024-03-01 | Buy |
| TCI Chemical | D4656 | 1,8-Dibromonaphthalene >98.0%(GC) | 17135-74-9 | 1g | $54 | 2024-03-01 | Buy |
| TCI Chemical | D4656 | 1,8-Dibromonaphthalene >98.0%(GC) | 17135-74-9 | 5g | $156 | 2024-03-01 | Buy |
| TRC | D426273 | 1,8-Dibromonaphthalene | 17135-74-9 | 50mg | $60 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD33422 | 1,8-Dibromonaphthalene | 17135-74-9 | 1g | $65 | 2021-12-16 | Buy |
1,8-Dibromonaphthalene Chemical Properties,Uses,Production
Chemical Properties
White to yellow powder/crystals.
Application
1,8-Diarylnaphthalene show great potential in highly efficient photoluminescent blue and green OLEDs, chiral ligands and sensors, nonlinear optic chromophores, stereo-dynamic switches and other optoelectronic devices.
Preparation
1,8-dibromonaphthalene was prepared by diazotisation of triazine 1 with sodium nitrite in sulfuric acid, followed by the addition of CuBr/HBr in 44% yield, and cyanation of the dibromide (5) by Weissman’s method gave naphthalene-1,8-dicarbonitrile (4) in 78% yield (Scheme 2).
Reactions
Influence of the conditions on the Pd-catalyzed reaction of 1,8-dibromonaphthalene with 1,2,3,4-tetrafluorobenzene.
Scope of the Pd-catalyzed direct arylation reaction of 2,5-substituted heteroarenes with 1,8-dibromonaphthalene.
Structure and conformation
1,8-Dibromonaphthalene (1,8-DBN) is a symmetrical double bromo-substituted naphthalene with two bromos sitting at the naphthalene ring mirroring each other along the joining carbons.
References
[1] W. NOLAND D. B Venkata Srinivasarao Narina. Synthesis and Crystallography of 8-Halonaphthalene-1-Carbonitriles and Naphthalene-1,8-Dicarbonitrile[J]. Journal of Chemical Research-s, 2011, 383 1: 694-697. DOI:10.3184/174751911X13222107572093.
[2] PROF. DR. ANNA V. GULEVSKAYA Eugeny A E. 1,8‐Diarylnaphthalenes: Synthesis, Properties, and Applications[J]. European Journal of Organic Chemistry, 2022, 2022 48: Pages 53-111. DOI:10.1002/ejoc.202201192.
[3] KETATA N, LIU L, SALEM R B, et al. Mono or double Pd-catalyzed C–H bond functionalization for the annulative π-extension of 1,8-dibromonaphthalene: a one pot access to fluoranthene derivatives[J]. Beilstein Journal of Organic Chemistry, 2024, 16 1. DOI:10.3762/bjoc.20.37.
1,8-Dibromonaphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Yurui (Shanghai) Chemical Co., Ltd. | +86-021-50456736 +8615000292053 | sales209@riyngroup.com | China | 1031 | 58 |
| Baynoe Chem (Suzhou) Co., Ltd. | +86-512 65869404 +86-18934593683 | sales06@baynoe.com | China | 257 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +86-17531190177; +8617531190177 | peter@yan-xi.com | China | 5872 | 58 |
| Hebei Xinsheng New Material Technology Co., LTD. | +86-16632316109 | xinshengkeji@xsmaterial.com | China | 1090 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16914 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21668 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9332 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32760 | 60 |
View Lastest Price from 1,8-Dibromonaphthalene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-08-15 | 1,8-DIBROMONAPHTALENE
17135-74-9
|
US $0.00 / kg | 1kg | 0.99 | 20 tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2024-08-15 | 1,8-Dibromonaphthalene
17135-74-9
|
US $0.00 / KG | 1KG | 98.00% | 150KG /month | Shanghai Daken Advanced Materials Co.,Ltd | |
 |
2023-11-14 | 1,8-DIBROMONAPHTALENE
17135-74-9
|
US $0.00-0.00 / kg | 1kg | 99.9% | 30000 Kg | Hebei Xinsheng New Material Technology Co., LTD. |
-
- 1,8-DIBROMONAPHTALENE
17135-74-9
- US $0.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
-
- 1,8-Dibromonaphthalene
17135-74-9
- US $0.00 / KG
- 98.00%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- 1,8-DIBROMONAPHTALENE
17135-74-9
- US $0.00-0.00 / kg
- 99.9%
- Hebei Xinsheng New Material Technology Co., LTD.