Benzyl methacrylate
- CAS No.
- 2495-37-6
- Chemical Name:
- Benzyl methacrylate
- Synonyms
- BZMA;Benzylmethacrylat;BENZYL METHACRYLATE;BENZYLMETHACRAYLATE;Benzyl 2-methylacrylate;Methacrylic acid benzyl;Benzyl methacrylate ,98%;benzyl 2-methylprop-2-enoate;METHACRYLIC ACID BENZYL ESTER;Benzyl Methacrylate, stabilized
- CBNumber:
- CB7306028
- Molecular Formula:
- C11H12O2
- Molecular Weight:
- 176.21
- MDL Number:
- MFCD00053684
- MOL File:
- 2495-37-6.mol
- MSDS File:
- SDS
| Melting point | <25 °C |
|---|---|
| Boiling point | 95-98 °C/4 mmHg (lit.) |
| Density | 1.04 g/mL at 25 °C (lit.) |
| vapor pressure | 3Pa at 20℃ |
| refractive index |
n |
| Flash point | 225 °F |
| storage temp. | 2-8°C(protect from light) |
| form | clear liquid |
| color | Colorless |
| Viscosity | 2.51mm2/s |
| Water Solubility | Insoluble in water. |
| Sensitive | Light Sensitive |
| BRN | 2045924 |
| Stability | Stable. Flammable. Incompatible with free-radical initiators, oxidizing agents, reducing agents. Avoid heat. Light-sensitive. |
| LogP | 3.1 at 20℃ |
| CAS DataBase Reference | 2495-37-6(CAS DataBase Reference) |
| FDA UNII | Z3248K2SSM |
| NIST Chemistry Reference | Benzyl methacrylate(2495-37-6) |
| EPA Substance Registry System | 2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6) |
| UNSPSC Code | 12162002 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26 | |||||||||
| WGK Germany | 1 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163990 | |||||||||
| NFPA 704 |
|
Benzyl methacrylate price More Price(19)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 409448 | Benzyl methacrylate 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor | 2495-37-6 | 250ml | $82.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 409448 | Benzyl methacrylate 96%, contains 50 ppm monomethyl ether hydroquinone as inhibitor | 2495-37-6 | 1l | $264 | 2024-03-01 | Buy |
| TCI Chemical | M0279 | Benzyl Methacrylate (stabilized with MEHQ) >98.0%(GC) | 2495-37-6 | 25mL | $20 | 2024-03-01 | Buy |
| TCI Chemical | M0279 | Benzyl Methacrylate (stabilized with MEHQ) >98.0%(GC) | 2495-37-6 | 500mL | $76 | 2024-03-01 | Buy |
| Alfa Aesar | L10840 | Benzyl methacrylate, 98%, stab. with ca 50-100ppm 4-methoxyphenol | 2495-37-6 | 50g | $23.65 | 2024-03-01 | Buy |
Benzyl methacrylate Chemical Properties,Uses,Production
Uses in Perfume
Benzyl methacrylate has found some use in perfume compositions where it may introduce very desirable notes in Rose and other floral fragrances, in Chypre, Oriental and heavy woody fragrance types, etc. It blends excellently with Oakmoss, Vetiver, Phenylacetaldehyde dimethylacetal, Citrcnel101,as well as with Lavender, Lavandin, Spike Lavender, etc. The ester is also used in soap and detergent perfumes, where its low cost allows for a more liberal application.
Description
The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].
Chemical Properties
Colorless oily liquid. Very slightly soluble in water, soluble in alcohol and oils. Soft, warm, herbaceous-rosy odor of moderate tenacity.
Uses
Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.
Flammability and Explosibility
Not classified
Advantages
The Tg of the copolymer was elevated, while thermal stability was first increased and then decreased with the introduction of Benzyl methacrylate. Besides, the water resistance of the latex PSA was improved by the presence of BzMA, which was confirmed by water contact angle measurements. Furthermore, as the BzMA content increased, the gel content slightly decreased, while sol molecular weight (Mw, Mn) of the polymer increased. Finally, with respect to the adhesive properties of the PSA, it was observed that loop tack decreased, while shear strength increased with the incorporation of BzMA. 180° peel strength initially increased and then decreased with the addition of Benzyl methacrylate from 0 to 30 wt%, with a maximum value at 5 wt%.
References
[1] Cheng Fang , Xiaolong Zhu, Fuxiang Zhou . “The application research of benzyl methacrylate (BzMA) in acrylate latex pressure sensitive adhesives.” International Journal of Adhesion and Adhesives 107 (2021): Article 102861.
Benzyl methacrylate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 | sales@qdrenas.com | China | 478 | 58 |
| Qingdao Zhongke Huatai Industrail Co., Ltd. | +86-532-86898076 +86-15153292017 | zkhtchem@163.com | China | 25 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8804 | 58 |
| Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12827 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20260 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29792 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 19915 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21632 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32965 | 60 |
View Lastest Price from Benzyl methacrylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-02-18 | Benzyl methacrylate
2495-37-6
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mujin Biotechnology Co.,Ltd | |
 |
2025-02-12 | Benzyl methacrylate
2495-37-6
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2025-02-05 | Benzyl methacrylate
2495-37-6
|
US $0.00 / kg | 20kg | 99.5％ | 10 toms | Qingdao RENAS Polymer Material Co., Ltd. |
-
- Benzyl methacrylate
2495-37-6
- US $0.00 / KG
- 99%
- Hebei Mujin Biotechnology Co.,Ltd
-
- Benzyl methacrylate
2495-37-6
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Benzyl methacrylate
2495-37-6
- US $0.00 / kg
- 99.5％
- Qingdao RENAS Polymer Material Co., Ltd.