ChemicalBook >> CAS DataBase List >>(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE

(-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE

(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE structure

CAS No.: 185346-09-2

Chemical Name:: (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE

Synonyms: SF150006;(S,R)-In-Pybox;(3aS,8aR)-in-pybox;2,6-BIS((3AS,8AR)-8H-INDENO(1,2-D)OXAZO&;2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine;aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine;(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-I...;2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine;2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine;(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

CBNumber:: CB7448533

Molecular Formula:: C25H19N3O2

Molecular Weight:: 393.44

MDL Number:: MFCD05861599

MOL File:: 185346-09-2.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Properties

Melting point	265°C (dec.)
Boiling point	633.0±55.0 °C(Predicted)
alpha	-364.0° (c 1.04, CH2Cl2)
Density	1.50±0.1 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
pka	4.35±0.20(Predicted)
form	Powder
color	white to off-white
optical activity	[α]20/D -375°, c = 1 in dichloromethane (typical)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302
Precautionary statements	P280-P305+P351+P338
Risk Statements	36/37/38
Safety Statements	26-36/37/39-36
WGK Germany	3
HS Code	29333990

(-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE price More Price(34)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	673978	2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine	185346-09-2	250mg	$83.4	2024-03-01	Buy
Sigma-Aldrich	673978	2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine	185346-09-2	1g	$450	2024-03-01	Buy
Strem Chemicals	07-1367	(-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE	185346-09-2	250mg	$120	2024-03-01	Buy
Strem Chemicals	07-0280	(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX	185346-09-2	250mg	$264	2024-03-01	Buy
Strem Chemicals	07-0280	(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX	185346-09-2	1g	$795	2024-03-01	Buy

Product number	Packaging	Price	Buy
673978	250mg	$83.4	Buy
673978	1g	$450	Buy
07-1367	250mg	$120	Buy
07-0280	250mg	$264	Buy
07-0280	1g	$795	Buy

(-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Chemical Properties,Uses,Production

Reaction

Ligand for Iridium-catalyzed enantio- and diastereoselective reductive aldol reactions
Ligand for Scandium-catalyzed asymmetric Nazarov reactions
Ligand for Scandium-catalyzed enantioselective pyrrole alkylations of α,β-unsaturated 2-acyl imidazoles
Ligand for Scandium-catalyzed enantioselective Friedel-Crafts Alkylations
Ligand for Nickel-catalyzed asymmetric cross-couplings of racemic propargyl groups with arylzinc reagents
Ligand for Scandium-catalyzed enantioselective intramolecular carbonyl-ene reaction, the synthesis of (+)-triptophenolide
Ligand for Scandium-catalyzed asymmetric synthesis of substituted 3-hydroxy-2-oxindoles
Ligand for Indium-catalyzed enantio- and regioselective addition of pyrroles to isatins
Ligand for Scandium-catalyzed asymmetric [3+2] annulation of allylsilanes with isatins in the synthesis of spirooxindoles
Ligand for Scandium-catalyzed enantioselective allylation of isatins using allylsilanes
Ligand for Scandium-catalyzed enantioselective carboannulation with allylsilanes

Chemical Properties

White powder

Uses

Reactant involved in synthesis of:

Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
Chiral N,N,N-tridentate pybos and pyboxazine ligands

(-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Suppliers

Global( 64)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18779	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	13503	58
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30240	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +8618949823763	sales@tnjchem.com	China	25356	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6114	58
LEAPCHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	43340	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	57505	58
Suzhou ARTK Medchem Co., Ltd.	+86-512-68323658 +86-18168183658	sales1@artkmedchem.com	China	39004	58
Amadis Chemical Company Limited	571-89925085	sales@amadischem.com	China	131957	58

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
Alchem Pharmtech,Inc.	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Career Henan Chemica Co	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Shaoxin Catsyn Co., Ltd.	58
LEAPCHEM CO., LTD.	58
Aladdin Scientific	58
Suzhou ARTK Medchem Co., Ltd.	58
Amadis Chemical Company Limited	58

185346-09-2((-)-2,6-BIS[2-[3AS-(2(3'AR,8'AS),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE)Related Search:

2,6-bis[(4R,5R)-4,5-dihydro-1-[(4-methylphenyl)sulfonyl]-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& (S)-5-CF3-pyrox-tBu

2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE (1S,2R)-(-)-cis-1-Amino-2-indanol METHYL PICOLINIMIDATE PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER

1of3

(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX 2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97% aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e. (-)-2,6-BIS[2-{3AS-(2(3'AR*,8'AS*),3AΑ,8AΑ)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE}]PYRIDINE 2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine (3aS,8aR)-in-pybox 2,6-BIS((3AS,8AR)-8H-INDENO(1,2-D)OXAZO& (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha,8aalpha)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,min.97% (3aS,8aR)-in-pybox, (3aS,3μaS,8aR,8μaR)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha:,8aalpha:)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine, min. 97% (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno [1,2-d]oxazole}]pyridine, min. 97%　 (-)-2,6-BIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLIN-2-YL]PYRIDINE,MIN.97%INDENYL-PYBOX (3aR,8bS)-2-[6-[(3aR,8bS)-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridin-2-yl]-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazole SF150006 [3aS-[2(3'aRS,8'aSR),3aα,8aα]]-2,2'-(2,6-pyridinediyl)bis-[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], 95%, (99% ee) (-)-2,6-Bis[2-[3as-(2(3'ar*,8'as*),3a alpha,8aalpha)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine 2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine, 98%, for synthesis 8H-Indeno[1,2-d]oxazole, 2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aS,3'aS,8aR,8'aR)- (S,R)-In-Pybox (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-I... (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97% (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97% 185346-09-2 BOX series Chiral Nitrogen organic amine

(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE

(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE Properties