ChemicalBook >> CAS DataBase List >>Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
![Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Structure](CAS/GIF/12354-85-7.gif)
- CAS No.
- 12354-85-7
- Chemical Name:
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
- Synonyms
- Rh(Cp*)Cl2]2;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;tube1183;Chiralyst P618;)rhodium(III) DichL;Bis[(pentamethylcycl;RHODIUM (III) CHLORIDE DIMER;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
- CBNumber:
- CB7482876
- Molecular Formula:
- C20H30Cl4Rh210*
- Molecular Weight:
- 618.08
- MDL Number:
- MFCD00061552
- MOL File:
- 12354-85-7.mol
- MSDS File:
- SDS
Last updated:2025-01-27 09:38:02
| Melting point | >300°C |
|---|---|
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform (Sparingly), Methanol (Slightly) |
| form | crystal |
| color | red |
| Water Solubility | Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether |
| Stability | Hygroscopic |
| NIST Chemistry Reference | Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315 | |||||||||
| Precautionary statements | P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38-R36/37/38-R20/21/22 | |||||||||
| Safety Statements | 26-36-S36-S26-24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] price More Price(49)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 338370 | Pentamethylcyclopentadienylrhodium(III) chloride dimer 97% | 12354-85-7 | 250mg | $344 | 2024-03-01 | Buy |
| Sigma-Aldrich | 338370 | Pentamethylcyclopentadienylrhodium(III) chloride dimer 97% | 12354-85-7 | 1g | $855 | 2024-03-01 | Buy |
| TCI Chemical | P1788 | (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer >96.0%(T) | 12354-85-7 | 1g | $476 | 2024-03-01 | Buy |
| TCI Chemical | P1788 | (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer >96.0%(T) | 12354-85-7 | 200mg | $162 | 2024-03-01 | Buy |
| Alfa Aesar | 033657 | Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99% | 12354-85-7 | 250mg | $203 | 2023-06-20 | Buy |
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties,Uses,Production
Reaction
- Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
- Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
- Catalyst used in the asymmetric transfer hydrogenation of imines in water.
- Facile rhodium-catalyzed synthesis of fluorinated pyridines.
- Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
Chemical Properties
burgundy solid
Uses
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.
Uses
Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A
reaction suitability
core: rhodium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 260)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-+86-371-66670886 | info@dakenam.com | China | 19832 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21631 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29863 | 58 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | sales@dolonchem.com | CHINA | 2972 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 19199 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
View Lastest Price from Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
![Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] pictures](/ProductImageEN1/2024-08/Small/3b99b35e-760f-4db0-a101-a009e6285616.gif) |
2024-08-05 | Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
|
US $0.10 / KG | 1KG | 99.0% | 1000 tons | Shaanxi Dideu Medichem Co. Ltd | |
![Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] pictures](/ProductImageEN/2020-11/Small/1fb07d7f-84a9-4274-853d-273ac45b7bcc.jpg) |
2020-11-16 | Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
|
US $20.00 / KG | 1KG | 99% | 10000KG | Longyan Tianhua Biological Technology Co., Ltd | |
![Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] pictures](https://img.chemicalbook.com/ProductImageEN/2019-7/Small/85a7d95f-4993-4103-9cde-98e891d250ea.png) |
2019-07-06 | Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
- US $0.10 / KG
- 99.0%
- Shaanxi Dideu Medichem Co. Ltd
-
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
- US $20.00 / KG
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
-
- Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] ISO 9001：2015 REACH
PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
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Chiralyst P618
Pentamethylcyclopentadineylrhodium(III) chloride dimer
Bis(chloro)(pentamethylcyclopentadienyl)rhodium(III)Dimer
12354-85-7
C10H15Cl4Rh2
C20H48Cl4Rh2
CH35C5RhCl22
RhC5Me5Cl22
C20H30Cl4Rh2
C20H30Cl4Rh210
2C10H152Cl2Rh
Catalysis and Inorganic Chemistry
metallocene
Catalysis and Inorganic Chemistry
Chemical Synthesis
Rhodium
Catalysts for Organic Synthesis
Classes of Metal Compounds
Homogeneous Catalysts
Metal Complexes