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| Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Basic information | Reaction |
Product Name: | Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] | Synonyms: | Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium;Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE;DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER;BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM];PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&;Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer;Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium | CAS: | 12354-85-7 | MF: | C20H30Cl4Rh210* | MW: | 618.08 | EINECS: | | Product Categories: | metallocene;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Rh | Mol File: | 12354-85-7.mol | ![Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Structure](CAS/GIF/12354-85-7.gif) |
| Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties |
Melting point | >300°C | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | solubility | Chloroform (Sparingly), Methanol (Slightly) | form | crystal | color | red | Water Solubility | Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether | Stability: | Hygroscopic | NIST Chemistry Reference | Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7) |
| Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis |
Reaction |
- Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
- Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
- Catalyst used in the asymmetric transfer hydrogenation of imines in water.
- Facile rhodium-catalyzed synthesis of fluorinated pyridines.
- Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
![Reactions of 12354-85-7_1](/NewsImg/2018-05-18/20185181032628741.jpg)
| Chemical Properties | burgundy solid | Uses | Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives. | Uses | Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A |
| Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials |
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