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Ammonium bisulfate

CAS No.
7803-63-6
Chemical Name:
Ammonium bisulfate
Synonyms
AMMONIUM BISULFATE;Acid ammnonium sulfate;AMMONIUMBI-SULPHATE;Ammonium hydrogen su;Acid aMMoniuM sulfate;Ammonium acid sulfate;Ammoniumhydrogensulfat;AMMONIUM HYDROGEN SULFATE;ammonium hydrogensulphate;Ammonium bisulfate-crystal
CBNumber:
CB7854367
Molecular Formula:
H5NO4S
Molecular Weight:
115.11
MDL Number:
MFCD00051073
MOL File:
7803-63-6.mol
MSDS File:
SDS
Last updated:2024-01-18 09:21:29

Ammonium bisulfate Properties

Melting point 147 °C
Boiling point 350 °C (dec.)(lit.)
Density 1.79 g/mL at 25 °C(lit.)
solubility H2O: 1 M at 20 °C, clear, colorless
form Crystalline Powder
Specific Gravity 1.79
color White
Water Solubility Soluble in water (~115.1 mg/ml at 20°C). Insoluble in acetone, alcohol, and pyridine.
Sensitive Hygroscopic
Merck 13,500
Stability Stable. Hygroscopic. Incompatible with acids, bases, oxidizing agents.
InChI InChI=1S/H3N.H2O4S/c;1-5(2,3)4/h1H3;(H2,1,2,3,4)
InChIKey BIGPRXCJEDHCLP-UHFFFAOYSA-N
SMILES S(=O)(=O)(O)O.N
LogP -1.031 (est)
CAS DataBase Reference 7803-63-6(CAS DataBase Reference)
FDA UNII 6218R7MBZB
EPA Substance Registry System Ammonium bisulfate (7803-63-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 2506 8/PG 2
WGK Germany  1
3
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  28332990
NFPA 704
1
3 1

Ammonium bisulfate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 455849 Ammonium hydrogensulfate 99.99% trace metals basis 7803-63-6 25g $77.7 2024-03-01 Buy
Alfa Aesar 014485 Ammonium hydrogen sulfate, 99.9% (metals basis) 7803-63-6 100g $77.65 2024-03-01 Buy
Alfa Aesar 014485 Ammonium hydrogen sulfate, 99.9% (metals basis) 7803-63-6 25g $34.6 2023-06-20 Buy
Sigma-Aldrich 455849 Ammonium hydrogensulfate 99.99% trace metals basis 7803-63-6 100g $194 2024-03-01 Buy
Alfa Aesar 014485 Ammonium hydrogen sulfate, 99.9% (metals basis) 7803-63-6 500g $264 2023-06-20 Buy
Product number Packaging Price Buy
455849 25g $77.7 Buy
014485 100g $77.65 Buy
014485 25g $34.6 Buy
455849 100g $194 Buy
014485 500g $264 Buy

Ammonium bisulfate Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder or chunks. This compound is one of several salts that can form from the reaction of ammonia and sulfur bearing gases, most particularly sulfur trioxide. This product is frequently found in the overhead of crude distillation units and can be quite corrosive to steel equipment. Chemical corrosion inhibitors are often used to control corrosion from ammonium bisulfate.

Uses

In hair-waving preparations; as catalyst for organic reactions.

Uses

Ammonium hydrogen sulfate is used as pharmaceutical intermediates and chemical reagents.

General Description

Ammonium hydrogen sulfate is a colorless to white, powdered solid. Ammonium hydrogen sulfate is toxic by ingestion. When heated to high temperatures, Ammonium hydrogen sulfate may release toxic sulfur oxide and nitrogen oxide fumes. Ammonium hydrogen sulfate is soluble in water. Ammonium hydrogen sulfate is a chemical catalyst, used in hair preparations.

Air & Water Reactions

Ammonium hydrogen sulfate dissolves in water with the evolution of some heat and hydrolyzes to form some amounts of sulfuric acid. Deliquescent.

Reactivity Profile

Acidic salts, such as Ammonium hydrogen sulfate, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

Moderately toxic by ingestion. A corrosive. See also SULFATES. Dangerous; when heated to decomposition it emits highly toxic fumes of sulfuric acid and SO,, NH3, and NOx,.

Purification Methods

It crystallises from water at room temperature (1mL/g) on adding EtOH and cooling. (NH4) HSO4 is formed as deliquescent rhombic crystals on cooling a solution of (NH4)2SO4 in hot conc H2SO4 but EtOH decomposes it to (NH4)3H(SO4)2 [Dunnicliff J Chem Soc 123 476 1923]. When powdered (NH4)2SO4 is heated below 100o, it loses NH3, and at 300o it is completely converted to fused (NH4) HSO4, m 140o, but >300o it decomposes to SO2 and N2 [Smith J Chem Soc 30 253 1911].

5329-14-6
7803-63-6
Synthesis of Ammonium bisulfate from Sulfamic acid
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View Lastest Price from Ammonium bisulfate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ammonium hydrogen sulfate pictures 2020-01-13 Ammonium hydrogen sulfate
7803-63-6
US $1.00 / KG 1KG 98%-99.9% 200kg Career Henan Chemical Co

Ammonium bisulfate Spectrum

AMMONIUMBI-SULPHATE Ammoniumhydrogensulfat Ammonium hydrogen sulfate, 99.9% (metals basis) Ammonium bisulfate: (Ammonium hydrogen sulfate) Ammonium hydrogen sulfate, Ammonium sulfate monobasic AMMONIUM HYDROGEN SULFATE, FOR ANALYSIS Sulfuric acid hydrogen ammonium salt Ammonium hydrogen su Acid aMMoniuM sulfate Ammonium bisulfate-crystal AMMoniuM hydrogen sulfate(aMMoniuM bi sulfate) Ammonium Hydrogen Sulfate (Metals Basis) AMMoniuM hydrogen sulfate, 99%, for analysis AMMoniuM hydrogen sulfate, extra pure Ammonium hydrogensulfate 99.99% trace metals basis Ammonium hydrogen sulfate, 99.9% trace metals basis Sulfuric acid, aMMoniuMsalt (1:1) Sulfuricacid,monoammoniumsalt Ammonium hydrogensulfate, 99.99% metals basis AMMONIUM HYDROGEN SULFATE ammonium hydrogensulphate Ammonium acid sulfate Ammonium bisulfate;Acid ammnonium sulfate;Ammonium acid sulfate ammonium sulfate monobasic AMMONIUMBISULFATE,CRYSTAL,REAGENT AMMONIUMBISULFATE,TECHNICAL AMMONIUM BISULFATE Acid ammnonium sulfate 7803-63-6 7809-63-6 NH4HSO4 H5NSO4 Analytical Reagents Ammonium Biochemicals and Reagents Analytical Chromatography Product Catalog BioChemical BioChemika Ultra General Use Inorganic Salts Crystallization Puriss p.a. Synthetic Reagents Inorganics