O-ALLYL-2,2,2-TRICHLOROACETIMIDATE
- CAS No.
- 51479-73-3
- Chemical Name:
- O-ALLYL-2,2,2-TRICHLOROACETIMIDATE
- Synonyms
- ALLYL 2,2,2-TRICHLOROACETIMIDATE;Allyl Trichloroacetimidate;O-ALLYL-2,2,2-TRICHLOROACETIMIDATE;Allyl 2,2,2-Trichloroacetimidate >O-Allyl 2,2,2-trichloroacetimidate 96%;2,2,2-TRICHLORACETIMIDIC ACID ALLYLESTER;O-Allyl 2,2,2-trichloroacetimidate;2,2,2-TRICHLOROACETIMIDIC ACID ALLYL ESTER;Ethanimidic acid, 2,2,2-trichloro-, 2-propen-1-yl ester
- CBNumber:
- CB8100737
- Molecular Formula:
- C5H6Cl3NO
- Molecular Weight:
- 202.47
- MDL Number:
- MFCD00190710
- MOL File:
- 51479-73-3.mol
| Boiling point | 54-70 °C/7.5-11.25 mmHg |
|---|---|
| Density | 1.333 g/mL at 25 °C |
| refractive index | n20/D 1.489 |
| Flash point | 74 °C |
| storage temp. | 2-8°C |
| solubility | sol hexane, ether, dichloromethane. |
| pka | 2?+-.0.70(Predicted) |
| form | clear liquid |
| color | Colorless to Almost colorless |
| BRN | 1907084 |
| UNSPSC Code | 12352101 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS05 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H315-H318-H335-H227 | |||||||||
| Precautionary statements | P210-P264-P302+P352+P332+P313+P362+P364-P305+P351+P338+P310-P403+P235-P501-P261-P280-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-37/38-41 | |||||||||
| Safety Statements | 26-39 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 29252900 | |||||||||
| NFPA 704 |
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O-ALLYL-2,2,2-TRICHLOROACETIMIDATE price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | A2186 | Allyl 2,2,2-Trichloroacetimidate >98.0%(GC) | 51479-73-3 | 5g | $185 | 2024-03-01 | Buy |
| TRC | T896098 | 2,2,2-TrichloroacetimidicAcidAllylEster | 51479-73-3 | 50mg | $45 | 2021-12-16 | Buy |
| AK Scientific | 5073AL | 2,2,2-Trichloroacetimidicacidallylester | 51479-73-3 | 25g | $392 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | HCH0066568 | O-ALLYL 2,2,2-TRICHLOROACETIMIDATE 95.00% | 51479-73-3 | 5G | $212.1 | 2021-12-16 | Buy |
| Crysdot | CD00003706 | Allyl 2,2,2-Trichloroacetimidate 97% | 51479-73-3 | 25g | $252 | 2021-12-16 | Buy |
O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Chemical Properties,Uses,Production
Uses
Reagent used for the protection of an alcohol as its allyl ether in the presence of base sensitive functionality.
Application
O-allyl-2,2,2-trichloroacetimidate can be used to release allyl groups under mild conditions; used to prepare nitrogen-containing intermediates.
Preparation
Sodium Hydride (0.5 g, 21 mmol) is slurried in anhydrous ether (20 mL) under a nitrogen blanket. Allyl alcohol (210 mmol) is introduced in ether (30 mL) dropwise with stirring to the slurry. After 20 min, the homogeneous solution is cooled to 0 °C and Trichloroacetonitrile (20 mL, 200 mmol) is added over 15 min. The mixture is allowed to warm to 20 °C over 60 min and then concentrated to a syrup. Pentane (20 mL) containing methanol (0.8 mL, 21 mmol) is added followed by vigorous shaking, filtration, and concentration of the filtrate and pentane washings (2 × 20 mL). The product imidate is obtained as a clear liquid (90-97%). No further purification is required. Alternatively, the imidate can be prepared by using sodium methoxide as a catalyst instead of sodium hydride. Other procedures for the preparation of allyl trichloroacetimidate have been reported.
O-ALLYL-2,2,2-TRICHLOROACETIMIDATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-+86-371-66670886 | info@dakenam.com | China | 19805 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29858 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18137 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49984 | 58 |
| Aceschem Inc. | +1-817863-6948 +1-（817）863-6948 | sales@aceschem.com | United States | 19632 | 58 |
| Changzhou AniKare Pharmatech Co., Ltd. | +86-0519-8359-8696 +8618018249389 | sales@anikare.com | China | 9875 | 58 |
View Lastest Price from O-ALLYL-2,2,2-TRICHLOROACETIMIDATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2019-09-04 | O-ALLYL-2,2,2-TRICHLOROACETIMIDATE
51479-73-3
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
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- O-ALLYL-2,2,2-TRICHLOROACETIMIDATE
51479-73-3
- US $1.00 / KG
- 99%
- Career Henan Chemical Co