ChemicalBook >> CAS DataBase List >>1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene

CAS No.
97239-80-0
Chemical Name:
1,1'-Bis(diisopropylphosphino)ferrocene
Synonyms
1,1'-Bis(diisopropyL;1,1'-Bis(di-i-propylphosphino)f;cyclopentyl(diisopropyl)phosphane;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE;1,1'-Bis(di-i-propylphosphino)ferrocene;1,1'-bis-(di-Isopropylphosphino)ferrocene;1,1'-Bis(diisopropylphosphino)ferrocene>1,1'-Bis(diisopropylphosphino)ferrocene,98%
CBNumber:
CB8105732
Molecular Formula:
C22H36FeP210*
Molecular Weight:
418.31
MDL Number:
MFCD02684559
MOL File:
97239-80-0.mol
MSDS File:
SDS
Last updated:2024-10-14 18:20:50

1,1'-Bis(diisopropylphosphino)ferrocene Properties

Melting point 50-52 °C(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange-yellow
Water Solubility Insoluble in water.
InChI InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChIKey LPBBEMRSRONKMN-UHFFFAOYSA-N
SMILES P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
CAS DataBase Reference 97239-80-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P305+P351+P338-P304+P340-P405-P501A
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26
WGK Germany  3
TSCA  No
HS Code  29319090
NFPA 704
0
2 0

1,1'-Bis(diisopropylphosphino)ferrocene price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 578266 1,1′-Bis(diisopropylphosphino)ferrocene 97% 97239-80-0 500mg $114 2024-03-01 Buy
TCI Chemical B2710 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) 97239-80-0 1g $144 2024-03-01 Buy
TCI Chemical B2710 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) 97239-80-0 100mg $38 2024-03-01 Buy
Alfa Aesar H27057 1,1'-Bis(diisopropylphosphino)ferrocene, 98% 97239-80-0 1g $169 2023-06-20 Buy
Alfa Aesar H27057 1,1'-Bis(diisopropylphosphino)ferrocene, 98% 97239-80-0 5g $571 2023-06-20 Buy
Product number Packaging Price Buy
578266 500mg $114 Buy
B2710 1g $144 Buy
B2710 100mg $38 Buy
H27057 1g $169 Buy
H27057 5g $571 Buy

1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties,Uses,Production

Reaction

  1. Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
  2. Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
  3. Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
  4. Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
  5. Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
  6. Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
  7. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
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Chemical Properties

orange crystalline powder

Uses

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials

Global( 177)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Research New Materials Co., Ltd.
+8618903931531 sales018@researchvip.com China 179 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18779 58
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29884 58
Changzhou Ansciep Chemical Co., Ltd.
+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2993 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5600 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58

View Lastest Price from 1,1'-Bis(diisopropylphosphino)ferrocene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,1'-Bis(diisopropylphosphino)ferrocene pictures 2024-11-22 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1,1'-Bis(diisopropylphosphino)ferrocene pictures 2024-11-21 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
US $0.00-0.00 / Kg 1Kg 98% 100kg Henan Research New Materials Co., Ltd.
1,1'-Bis(diisopropylphosphino)ferrocene pictures 2024-10-14 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
US $0.00-0.00 / KG 1KG 98% 50KG XINXIANG RUNYU MATERIAL CO., LTD.
BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON 1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% 1,1'-Bis(diisopropylphosphino)ferrocene,98% 1,1'-Bis(di-i-propylphosphino)ferrocene,min.98% 1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]- 1,1'-Bis(di-i-propylphosphino)ferrocene,98% cyclopentyl(diisopropyl)phosphane -BIS(DIISOPROPYLPHOSPHINO)FERROCENE 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF 1,1'-Bis(di-i-propylphosphino)f 1,1'-Bis(diisopropylphosphino)ferrocene> 1,1'-Bis(diisopropyL 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE ISO 9001:2015 REACH bis(2-diisopropylphosphanylcyclopenta-1,3-dien-1-yl)iron 1,1'-bis-(di-Isopropylphosphino)ferrocene 1,1'-Bis(di-i-propylphosphino)ferrocene 97239-80-0 97239-80-8 C22H36FeP210 C22H36FeP2 2C11H18PFe Phosphine Ligands Ferrocenes Metallocenes Polydentate Phosphine Ligands Phosphorus Compounds Catalysis and Inorganic Chemistry Achiral Phosphine Aryl Phosphine Ligand Ferrocenes Metallocenes Phosphine Ligands Synthetic Organic Chemistry Catalysis and Inorganic Chemistry Phosphorus Compounds Polydentate Phosphine Ligands