ChemicalBook >> CAS DataBase List >>1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis(di-tert-butylphosphino)ferrocene
- CAS No.
- 84680-95-5
- Chemical Name:
- 1,1'-Bis(di-tert-butylphosphino)ferrocene
- Synonyms
- DTBPF;DBtPF;98% DtBPF;DTBPF ChemBeads;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-t-butylphosphino)ferrocene;1,1'-Bis(di-tert-butylphosphiNA)ferrocene;1,1'-Bis(di-tert-butylphosphino)ferrocene
- CBNumber:
- CB3689138
- Molecular Formula:
- C26H44FeP210*
- Molecular Weight:
- 474.42
- MDL Number:
- MFCD01630818
- MOL File:
- 84680-95-5.mol
- MSDS File:
- SDS
Last updated:2025-03-12 07:03:40
| Melting point | 181-182°C (dec.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| form | crystal |
| color | orange to red |
| Water Solubility | Insoluble in water. |
| InChI | InChI=1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3; |
| InChIKey | FPLSJBJGQLJLSV-UHFFFAOYSA-N |
| SMILES | P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:9,10,11,12,13,23,24,25,26,27| |
| UNSPSC Code | 12350000 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 22-24/25-36/37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
1,1'-Bis(di-tert-butylphosphino)ferrocene price More Price(43)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 695149 | 1,1′-Bis(di-tert-butylphosphino)ferrocene | 84680-95-5 | 1g | $171 | 2024-03-01 | Buy |
| Sigma-Aldrich | 695149 | 1,1′-Bis(di-tert-butylphosphino)ferrocene | 84680-95-5 | 250mg | $93.8 | 2023-06-20 | Buy |
| TCI Chemical | B2711 | 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) | 84680-95-5 | 1g | $124 | 2024-03-01 | Buy |
| TCI Chemical | B2711 | 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) | 84680-95-5 | 100mg | $23 | 2024-03-01 | Buy |
| Alfa Aesar | L19759 | 1,1'-Bis(di-tert-butylphosphino)ferrocene, 98% | 84680-95-5 | 500mg | $65.2 | 2021-12-16 | Buy |
1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties,Uses,Production
Reaction
- Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
- Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
- Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
- Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
- Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
- Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
- Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
- Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
- Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.
Uses
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.
Uses
The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.
reaction suitability
reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Indole Forming Reactions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
Synthesis of 1,1'-Bis(di-tert-butylphosphino)ferrocene from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy- and Di-tert-butylchlorophosphane
1,1'-Bis(di-tert-butylphosphino)ferrocene Preparation Products And Raw materials
Global( 271)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Research New Materials Co., Ltd. | +8618903931531 | sales018@researchvip.com | China | 169 | 58 |
| Puyang Huicheng Electronic Materials Co., Ltd. | +86-0393-+86-0393-8910800 +8615839383373 | info@huichengchem.com | China | 529 | 58 |
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 410 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531157085 | abby@chuanghaibio.com | China | 8808 | 58 |
| Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12809 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-+86-371-66670886 | info@dakenam.com | China | 19805 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29858 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
Related articles
- 1,1'-Bis(di-tert-butylphosphino)ferrocene: Anodic Electrochemistry, Application in Catalysis and its Preparation Method
- 1,1'-Bis(di-tert-butylphosphino)ferrocene is a bulky ligand that boosts palladium-catalyzed Suzuki coupling yields and is synt....
- Aug 23，2024
View Lastest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-04-23 | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
|
US $0.00-0.00 / KG | 1KG | 99% | 20 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-04-23 | 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
|
US $0.00 / g | 500g | 98％ | 10 | Henan Research New Materials Co., Ltd. | |
 |
2025-03-21 | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mujin Biotechnology Co.,Ltd |
-
- 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
- US $0.00-0.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
- US $0.00 / g
- 98％
- Henan Research New Materials Co., Ltd.
-
- 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
- US $0.00 / KG
- 99%
- Hebei Mujin Biotechnology Co.,Ltd
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1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF
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1,1'-Bis(di-tert-butylphosphino)ferrocene 98%
DTBPF
Dehch（bis(2-ethylhexyl) cyclohexane -1,2-dicarboxylate）
1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene
1,1'-Bis(di-t-butylphosphino)ferrocene
DTBPF ChemBeads
84680-95-5
94680-95-5
C26H44FeP2
C4H92PC5H42Fe
2C13H22PFe
C26H44FeP210
2C13H23PFe
C26H42FeP2
Metallocenes
Transition Metal Compounds
Phosphine Ligands
Classes of Metal Compounds
Ferrocenes
Fe (Iron) Compounds
Achiral Phosphine
Aryl Phosphine
Classes of Metal Compounds
Fe (Iron) Compounds
Ferrocenes
Metallocenes
Phosphine Ligands
Synthetic Organic Chemistry
Transition Metal Compounds
Catalysis and Inorganic Chemistry
Phosphorus Compounds
Polydentate Phosphine Ligands