Di-tert-butylchlorophosphane
- CAS No.
- 13716-10-4
- Chemical Name:
- Di-tert-butylchlorophosphane
- Synonyms
- DI-TERT-BUTYLCHLOROPHOSPHINE;Chlorodi-tert-butylphosphine;Di-t-butyL;AURORA KA-1319;(tert-C4H9)2PCl;98% [(CH3)3C]2PCl;Phosphonous dichloride;DI-TERT-BUTYLCHLOROPHO;DI-T-BUTYLCHLOROPHOSPHINE;DI-TERT-BUTYLCHLOROPHOSPHANE
- CBNumber:
- CB2200163
- Molecular Formula:
- C8H18ClP
- Molecular Weight:
- 180.66
- MDL Number:
- MFCD00008815
- MOL File:
- 13716-10-4.mol
- MSDS File:
- SDS
Melting point | 2-3°C |
---|---|
Boiling point | 48 °C/3 mmHg (lit.) |
Density | 0.951 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 142 °F |
solubility | Miscible with terahydrofuran. |
form | Liquid |
Specific Gravity | 0.951 |
color | Clear colorless |
Sensitive | Air & Moisture Sensitive |
InChIKey | MCRSZLVSRGTMIH-UHFFFAOYSA-N |
CAS DataBase Reference | 13716-10-4(CAS DataBase Reference) |
NIST Chemistry Reference | Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-36/37/39-45-25 | |||||||||
RIDADR | UN 3265 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | No | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29310099 | |||||||||
NFPA 704 |
|
Di-tert-butylchlorophosphane price More Price(26)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 301558 | Di-tert-butylchlorophosphine 96% | 13716-10-4 | 5g | $113 | 2024-03-01 | Buy |
Sigma-Aldrich | 301558 | Di-tert-butylchlorophosphine 96% | 13716-10-4 | 25g | $441 | 2024-03-01 | Buy |
TCI Chemical | D3632 | Di-tert-butylchlorophosphine >95.0%(GC) | 13716-10-4 | 5g | $72 | 2024-03-01 | Buy |
TCI Chemical | D3632 | Di-tert-butylchlorophosphine >95.0%(GC) | 13716-10-4 | 25g | $244 | 2024-03-01 | Buy |
Alfa Aesar | B20998 | Di-tert-butylchlorophosphine, 96% | 13716-10-4 | 5g | $118 | 2024-03-01 | Buy |
Di-tert-butylchlorophosphane Chemical Properties,Uses,Production
Chemical Properties
Colorless to light yellow liqui
Uses
Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
Uses
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.
Uses
Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.
Application
Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
Precautions
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
Di-tert-butylchlorophosphane Preparation Products And Raw materials
Raw materials
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Preparation Products
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Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 436 | 58 |
Puyang Huicheng Electronic Materials Co., Ltd. | +86-0393-+86-0393-8910800 +8615839383373 | info@huichengchem.com | China | 529 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12837 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5858 | 58 |
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7433 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18648 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21639 | 55 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 9220 | 55 |
AB PharmaTech,LLC | 323-480-4688 | sales@acrospharmatech.com | United States | 989 | 55 |
View Lastest Price from Di-tert-butylchlorophosphane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-01 | Di-tert-butylchlorophosphane
13716-10-4
|
US $85.00-515.00 / g | 25g | 0.96 | 25kg | Shanghai UCHEM Inc. | ||
2024-10-25 | Di-tert-butylchlorophosphane
13716-10-4
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd | ||
2024-10-25 | Di-tert-butylchlorophosphane
13716-10-4
|
US $10.00-1.00 / kg | 1kg | 0.99 | 20 tons | Hebei Yanxi Chemical Co., Ltd. |
- Di-tert-butylchlorophosphane
13716-10-4
- US $85.00-515.00 / g
- 0.96
- Shanghai UCHEM Inc.
- Di-tert-butylchlorophosphane
13716-10-4
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- Di-tert-butylchlorophosphane
13716-10-4
- US $10.00-1.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
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